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CAS: 14691-89-5
分子式: C11H21N2O2
分子量: 213.29
熔点: 142-145℃
中文名称: 
4-乙酰胺基四甲基哌啶氧自由基
4-乙酰氨基-2,2,6,6-四甲基-1-哌啶氧
英文名称: 
4-(acetylamino)-2,2,6,6-tetramethyl-1-Piperidinyloxy
4-(acetylamino)-2,2,6,6-tetramethyl-1-piperidinylox
4-acetylamino-2,2,6,6-tetramethylpiperidin- 1-oxyl
1-Piperidinyloxy,4-(acetylamino)-2,2,6,6-tetramethyl-
4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl
4-Acetamido-TEMPO,free radical
4-Acetamido-2,2,6,6-tetramethyl-1-piperidinyloxy,free radical
4-Acetamido-TEMPO
推荐供应商
货号品牌产品名称规格包装、参考价格
A838664MACKLIN4-乙酰氨-2,2,6,6-四甲基哌啶-1-氧98%33元/1g;   115元/5g;   570元/25g;   1640元/100g;   咨询
储存:2-8°C
状态:微橙色到暗橙色和微红色到暗红色固体
A1348TCI4-Acetamido-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical [Catalyst for Oxidation]>98.0%(GC)850元/5G;   1950元/25G;   咨询

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C11H21N2O2 = 213.30
外观与形状(20℃)固体
Reaxys-RN11322085
PubChem物质ID87562806
MDL编号MFCD00043593

技术规格

AppearanceLight yellow to Brown powder to crystaline
Purity(GC)min. 98.0 %
Purity(Iodometric Titration)min. 96.0 %
Melting point143.0 to 147.0 ℃

物性(参考值)

熔点143 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
385832J&K4-Acetamido-TEMPO98%338元/5G;   1181元/25G;   3543元/100G;   咨询

基本信息

分子式C11H21N2O2
分子量213.30
熔点143
MDL编码MFCD00043593
EINECS 编号423-840-3

安全信息

图形或危害标志
提示语Warning
危险说明H302
防范说明P264
P280
P302+P352
P305+P351+P338
B23456Alfa Aesar4-Acetamido-TEMPOfree radical, 98+%492元/1g;   2441元/5g;   咨询

应用
4-Acetamido-TEMPO, free radical oxidizes alcohols to carbonyl compounds in the presence of TsOH.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents, heat.

基本信息

MDL
MFCD00043593

EINECS
423-840-3

分子式
C11H21N2O2

分子量
213.30

熔点
143-146°

灵敏度
Keep Cold.

形态
Crystalline powder

溶解性
Soluble in ethanol, acetone, acetonitrile, methylene chloride. Insoluble in hexane, ether.

Beilstein
3546225

GHS危害和防范说明

GHS符号

Hazard Statements
H302
Harmful if swallowed.

Precautionary Statements
P264-P270-P301+P312a-P330-P501a
Wash thoroughly after handling.Do not eat, drink or smoke when using this product.Do not eat, drink or smoke when using this product.Rinse mouth.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22
Harmful if swallowed.

安全等级
22
Do not breathe dust.

欧盟危险品标志

TSCA
是

00375Sigma-Aldrich4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxylpurum, ≥98.0% (HPLC)528.48元/1G;   2510.3元/5G;   咨询

产品说明

一般描述

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by 1H, 13C and 15N NMR spectral data.

应用

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be employed as model nitroxyl radical to study its reaction with thiophosgene. Reaction afforded 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-1-hydroxypiperidine as major products.

其他说明

将醇轻度氧化成羰基的新型氧化剂

基本信息

经验(实验)分子式C11H21N2O2
分子量213.30
Beilstein3546225
EC 号423-840-3
MDL编号MFCD00043593
PubChem化学物质编号329747053
NACRESNA.22

产品性质

质量水平200
等级purum
测定≥98.0% (HPLC)
环保替代产品得分old score: 9
new score: 8
Find out more about DOZN™ Scoring
环保替代产品特性Waste Prevention
Safer Solvents and Auxiliaries
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.
mp143-145 ℃ (lit.)
143-146 ℃
环保替代产品分类Re-engineered
储存温度2-8℃
SMILES stringCC(=O)NC1CC(C)(C)N([O])C(C)(C)C1
InChI1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)
InChI keyUXBLSWOMIHTQPH-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
预防措施声明P264 - P270 - P301 + P312 + P330 - P501
危险分类Acute Tox. 4 Oral
储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
390380Sigma-Aldrich4-Acetamido-TEMPO, free radical97%10162.8元/25 G;   咨询

产品说明

应用

在 TsOH 存在的条件下将醇氧化为羰基化合物。

包装

25 g in glass bottle

基本信息

经验(实验)分子式C11H21N2O2
分子量213.30
Beilstein3546225
EC 号423-840-3
MDL编号MFCD00043593
PubChem化学物质编号24864140
NACRESNA.22

产品性质

质量水平200
测定97%
mp143-145 ℃ (lit.)
SMILES stringCC(=O)NC1CC(C)(C)N([O])C(C)(C)C1
InChI1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)
InChI keyUXBLSWOMIHTQPH-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
危险分类Acute Tox. 4 Oral
储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
225966Fluorochem4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl95%264元/1g;   880元/5g;   3388元/25g;   9218元/100g;   咨询

基本信息

CAS Number14691-89-5
MDL NumberMFCD00043593

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
防范说明 P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P501: Dispose of contents/container to in accordance with local regulation .
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