| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| B806388 | MACKLIN | 1,2-双(二苯基膦)乙烷氯化镍 | 98% | 30元/1g; 35元/5g; 72元/25g; 267元/100g; | 咨询 |
储存：2~8°C 状态：黄色到橙色,橙色-红色或橙棕色到棕色固体,粉末,晶体,结晶粉末和/或块状 |
| B2225 | TCI | [1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride | >96.0%(T) | 320元/1G; 845元/5G; 2850元/25G; | 咨询 |
基本信息 | 纯度/分析方法 | >96.0%(T) | | 分子式/分子量 | C26H24Cl2NiP2 = 528.02 | | 外观与形状(20℃) | 固体 | | Reaxys-RN | 14761473 | | PubChem物质ID | 87565079 | | MDL编号 | MFCD00013313 |
技术规格 | Appearance | Orange to Amber to Dark red powder to crystal | | Purity(Chelometric Titration) | min. 96.0 % |
安全信息 | 图形或危害标志 |   | | 信号词 | 危险 | | 危险性说明 | H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H372 : 长期或反复接触会对器官造成损害。
H317 : 可能造成皮肤过敏反应。
H334 : 吸入可能导致过敏或哮喘病症状或呼吸困难。
H350 : 可能致癌。
| | 防范说明 | P501 : 将内装物/容器送到批准的废物处理厂处理。
P272 : 受沾染的工作服不得带出工作场地。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P284 : [在通风不足的情况下]戴呼吸防护装置。
P308 + P313 : 如接触到或有疑虑：求医/就诊。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P333 + P313 : 如发生皮肤刺激或皮疹：求医/就诊。
P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染：用水充分清洗。如感觉不适，呼叫急救中心/医生。
P304 + P340 + P312 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。
P405 : 存放处须加锁。
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| 102993 | J&K | [1,2-Bis(diphenylphosphino)ethane]dichloronickel(II) | 99% | 193元/1G; 572元/5G; 2283元/25G; | 咨询 |
基本信息 | 分子式 | C26H24P2·NiCl2 | | 分子量 | 528.02 | | 熔点 | 263-265 | | MDL编码 | MFCD00013313 |
安全信息 | 图形或危害标志 | | | 提示语 | Danger | | 危险说明 | H302
H312
H315
H319
H332
H334
H335
H350 | | 防范说明 | P201
P261
P280
P305+P351+P338
P308+P313 | | WGK | 3 | | TSCA | 否 |
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| 28-0030 | Strem | 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride | 99% | 514元/2g; 1171元/10g; 4860元/50g; | 咨询 |
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| 013932 | Alfa Aesar | Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) | 98% | 589元/2g; 2238元/10g; | 咨询 |
应用
Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers, catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes. 备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Moisture sensitive. 基本信息 MDL
MFCD00013313 分子式
NiCl2[(C6H5)2PCH2CH2P(C6H5)2] 分子量
528.02 熔点
263-265° 灵敏度
Ambient temperatures. 形态
Orange-red to brown powder 溶解性
Insoluble in water. GHS危害和防范说明 GHS符号
Hazard Statements
H302-H312-H332-H315-H319-H317-H351-H335
Harmful if swallowed.Harmful in contact with skin.Harmful if inhaled.Causes skin irritation.Causes serious eye irritation.May cause an allergic skin reaction.Suspected of causing cancer.May cause respiratory irritation. Precautionary Statements
P201-P261-P280-P305+P351+P338-P405-P501a
Obtain special instructions before use.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险类别
20/21/22-36/37/38-40-43
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes, respiratory system and skin.Limited evidence of a carcinogenic effect.May cause sensitization by skin contact. 安全等级
9-26-36/37-60
Keep container in a well-ventilated place.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste 欧盟危险品标志
 TSCA
否 |
| C36323 | Alfa Aesar | 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride | 99% | 773元/1g; 2701元/5g; 7639元/25g; | 咨询 |
基本信息 Ref#
36323 MDL
13313 分子式
C26 H24 Cl2 Ni P2 分子量
528.02 |
| 328219 | Sigma-Aldrich | [1,2-Bis(diphenylphosphino)ethane]dichloronickel(II) | | 160.47元/1 G; 170.35元/5 G; 704.49元/25 G; | 咨询 |
产品说明 应用 涉及的反应物： - Kumada 催化转移缩聚反应
- 碳硼基膦配体的氧化
- 镍铁二硫醇氢化物的合成
- Ullmann 反应-同偶联反应
醇氢甲酰化合成季碳的助催化剂 瓦克型分子内有氧氧化胺化烯烃的催化剂 包装 1, 5, 25 g in glass bottle 基本信息 | 线性分子式 | [(C6H5)2PCH2CH2P(C6H5)2]NiCl2 | | 分子量 | 528.02 | | MDL编号 | MFCD00013313 | | PubChem化学物质编号 | 24859721 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | reaction suitability | core: nickel
reagent type: catalyst | | mp | 263-265 ℃ (lit.) | | SMILES string | Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4 | | InChI | 1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2 | | InChI key | XXECWTBMGGXMKP-UHFFFAOYSA-L |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H302 + H312 + H332 - H315 - H319 - H334 - H335 - H350 | | 预防措施声明 | P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313 | | 危险分类 | Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges |
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| 077791 | Fluorochem | 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride | 96% | 220元/1g; 352元/5g; 1562元/25g; 5280元/100g; 23518元/500g; | 咨询 |
基本信息 | CAS Number | 14647-23-5 | | MDL Number | MFCD00013313 | | Melting Point | 263 - 265 ℃ |
安全信息 | 图形或危害标志 | | | 危险性说明 | H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335: May cause respiratory irritation.
H350: May cause cancer ..
H372: Causes damage to organs Respiratory system.
| | 防范说明 | P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear .
P281: Use personal protective equipment as required.
P285: In case of inadequate ventilation wear respiratory protection.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P304 + P341: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P333 + P313: If skin irritation or rash occurs: Get medical advice/attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342 + P311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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