CAS 1462397-86-9; 二氯三苯基膦[双(2-(乙硫基)乙基)胺]钌(ii); dichlorotriphenylphosphine[bis(2-(ethylthio)ethyl)amine]ruthenium(ii)

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货号

品牌

产品名称

规格

包装、参考价格

O724927

MACKLIN

(OC-6-13)-二氯[rel-2-[(R)-乙硫基-κS]-N-[2-[(S)-乙硫基-κS]乙基]乙胺-κN](三苯基膦)钌

98%

565元/100mg; 1170元/250mg; 3956元/1g;

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储存：2-8°C, 惰性气体

746339

Sigma-Aldrich

Dichlorotriphenylphosphine[bis(2-(ethylthio)ethyl)amine]ruthenium(II)

97%

532.08元/100 MG; 2249.4元/500 MG;

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产品说明

一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

应用

Catalyst for the hydrogenation of esters to alcohols.
Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.

Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters

包装

100, 500 mg in glass bottle

其他说明

"The mer-SNS complexes form isomers in solution. This is due to the different arrangements of the SEt groups relative to the SNS ligand plane. Two of the isomers have eclipsed SEt groups (arranged on one side of the SNS plane), and the third isomer has staggered SEt groups (occupying the opposite sides of the SNS plane)."

法律信息

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

基本信息

经验(实验)分子式	C₂₆H₃₄Cl₂NPRuS₂
分子量	627.63
MDL编号	MFCD26960799
PubChem化学物质编号	329765759
NACRES	NA.22

产品性质

质量水平	100
测定	97%
reaction suitability	core: ruthenium reagent type: catalyst
环保替代产品特性	Catalysis Learn more about the Principles of Green Chemistry.
mp	300-310 ℃
环保替代产品分类	Aligned
SMILES string	CCSCCN([H])CCSCC.Cl[Ru]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
InChI	1S/C18H15P.C8H19NS2.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-10-7-5-9-6-8-11-4-2;;;/h1-15H;9H,3-8H2,1-2H3;2*1H;/q;;;;+2/p-2
InChI key	ZQGMNGJIEYHKBR-UHFFFAOYSA-L

安全信息

象形图
警示用语：	Danger
危险声明	H302 + H312 - H331
预防措施声明	P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P311
危险分类	Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral
储存分类代码	6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable