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CAS: 14592-56-4
分子式: C4H6Cl2N2Pd
分子量: 259.43
熔点: 300 °C
中文名称: 
二乙腈基二氯化钯
反式双(乙腈)氯化钯(II)
双(乙腈)二氯钯(II)
双(乙腈)-氯化钯(II)
英文名称: 
bis(Acetonitrile)-palladium(II) chloride
bis(Acetonitrile)-palladium(II)chloride
Bis(acetonitrile)dichloropalladium(II)
Palladium(II)chloride diacetonitrile complex
Bis(acetonitrile)palladium(II)chloride
Bis(acetonitrile)palladium(II)Dichloride
dichlorobis(acetonitrile)palladium(ii)
推荐供应商
货号品牌产品名称规格包装、参考价格
B799149MACKLIN双(乙腈)氯化钯(II)99.95% metals basis329元/250mg;   988元/1g;   3615元/5g;   咨询
储存:室温
B801882MACKLIN双(乙腈)氯化钯(II)Pd 41.0%197元/200mg;   718元/1g;   3328元/5g;   咨询
储存:室温
状态:金色晶体粉末
B1676TCIBis(acetonitrile)palladium(II) Dichloride>98.0%(T)1080元/1G;   4360元/5G;   咨询

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C4H6Cl2N2Pd = 259.43
外观与形状(20℃)固体
Reaxys-RN14640205
PubChem物质ID87564577
SDBS (AIST Spectral DB)17192
MDL编号MFCD00013122

技术规格

AppearanceLight yellow to Brown powder to crystaline
Purity(Chelometric Titration)min. 98.0 %

安全信息

图形或危害标志
信号词危险
危险性说明H301 + H311 + H331 : 吞咽、皮肤接触或吸入中毒。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P311 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

运输信息

UN编号UN3439
类别6.1
包装类别 III
监管条件代码(*)
288223J&KBis(acetonitrile)dichloropalladium(II)99%355元/500MG;   643元/1G;   2470元/5G;   咨询

基本信息

分子式C4H6Cl2N2Pd
分子量259.43
MDL编码MFCD00013122
Beilstein14640205
EINECS 编号238-637-3

安全信息

图形或危害标志
提示语Danger
危险说明H301
H311
H331
防范说明P261
P280
P301+P310
P311
UN号码3077
危险分类9
包装等级III
WGK3
TSCA
46-0370StremDichlorobis(acetonitrile)palladium(II)99%1308元/1g;   5227元/5g;   咨询

Technical Notes:

1.Catalyst for the cyclization of õ-acetylenic carboxylic acids to butenolides.

2.Catalyst for the aza-Michael reaction of carbamates with enones .

3.Catalyst for the rearrangement of allylic imidates to allylic amides.

4.Catalyst for the Nazarov cyclization of a-alkoxy dienones.

5.Catalyst for the diamination of conjugated dienes.

6.Three component Michael addition, cyclization, cross-coupling reaction.

8.C-H activation of indoles.

7.Catalyst used for the direct C-H arylation of isoxazoles at the 5 position.

010002Alfa AesarBis(acetonitrile)dichloropalladium(II)Pd 40.5%0元/1g;   0元/5g;   咨询

应用
It is used as a catalyst in an ether-directed aza-Claisen rearrangement. Also used in cyclization and cross-coupling reactions. It is applied for olefin isomerization, preparation of acetals and hemiacetal esters.

备注
Should be stored in a cool, dry place in a tightly sealed container.

基本信息

MDL
MFCD00013122

EINECS
238-637-3

分子式
PdCl2(CH3CN)2

分子量
259.41

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in acetonitrile, acetone, chloroform

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H331-H315-H319-H335
Harmful if swallowed.Harmful in contact with skin.Toxic if inhaled.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
20/21/22-36/37/38
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
9-26-36/37
Keep container in a well-ventilated place.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

TSCA

C20945Alfa AesarBis(acetonitrile)palladium(II) chloride99%2271元/500mg;   10231元/5g;   咨询

基本信息

Ref#
20945

MDL
13122

分子式
C4 H6 Cl2 N2 Pd

分子量
259.4

形态
Powder

安全信息

危险等级
6.1

包装组
III

446319Sigma-AldrichBis(acetonitrile)dichloropalladium(II)99.99%406.12元/250 MG;   1175.72元/1 G;   咨询

产品说明

应用

钯催化交叉偶联反应应用指南

包装

1 g in glass bottle
250 mg in glass bottle

基本信息

线性分子式PdCl2 · (CH3CN)2
分子量259.43
EC 号238-637-3
MDL编号MFCD00013122
PubChem化学物质编号24868266
NACRESNA.22

产品性质

质量水平100
测定99.99%
reaction suitabilitycore: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
SMILES stringCC#N.CC#N.Cl[Pd]Cl
InChI1S/2C2H3N.2ClH.Pd/c2*1-2-3;;;/h2*1H3;2*1H;/q;;;;+2/p-2
InChI keyRBYGDVHOECIAFC-UHFFFAOYSA-L

安全信息

象形图GHS06
警示用语:Danger
危险声明H301 + H311 + H331
预防措施声明P280 - P301 + P310 + P330 - P302 + P352 + P312 - P304 + P340 + P311
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
225657Sigma-AldrichBis(acetonitrile)dichloropalladium(II)99%451.12元/500 MG;   3786.99元/5 G;   咨询

产品说明

一般描述

我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型,提高了催化效率。点击此处,查看更多详情。

应用

钯催化交叉偶联反应应用指南
用于TPGS-750-M中更环保的Sonagashira偶联的催化剂

朝着通过E因子而量化的绿色过渡金属催化过程前进
用于醚导向的aza-Claisen重排反应的催化剂。

包装

5 g in glass bottle
500 mg in glass bottle

基本信息

线性分子式PdCl2 · (CH3CN)2
分子量259.43
EC 号238-637-3
MDL编号MFCD00013122
PubChem化学物质编号24853511
NACRESNA.22

产品性质

质量水平200
测定99%
形式powder
reaction suitabilitycore: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
环保替代产品特性Catalysis
Learn more about the Principles of Green Chemistry.
环保替代产品分类Aligned
SMILES stringCC#N.CC#N.Cl[Pd]Cl
InChI1S/2C2H3N.2ClH.Pd/c2*1-2-3;;;/h2*1H3;2*1H;/q;;;;+2/p-2
InChI keyRBYGDVHOECIAFC-UHFFFAOYSA-L

安全信息

象形图GHS06
警示用语:Danger
危险声明H301 + H311 + H331
预防措施声明P280 - P301 + P310 + P330 - P302 + P352 + P312 - P304 + P340 + P311
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral
储存分类代码6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
046131FluorochemBis(acetonitrile)palladium(II) chloride99%968元/1g;   3520元/5g;   咨询

基本信息

CAS Number14592-56-4
MDL NumberMFCD00013122

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H331: Toxic if inhaled.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P311: Call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P361: Remove/Take off immediately all contaminated clothing.
P363: Wash contaminated clothing before reuse.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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