CAS 145100-51-2; 2-(n,n-bis(trifluoromethylsulfonyl)amino)-5-chloropyridine

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N806000

MACKLIN

N-(5-氯-2-吡啶基)双(三氟甲烷磺酰亚胺)

98%

27元/1g; 43元/5g; 212元/25g; 807元/100g;

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储存：室温
状态：白色到橙色到棕褐色固体

B1865

TCI

2-[N,N-Bis(trifluoromethanesulfonyl)amino]-5-chloropyridine [Triflating Reagent]

>96.0%(GC)

895元/5G; 3825元/25G;

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基本信息

纯度/分析方法	>96.0%(GC)
分子式/分子量	C₇H₃ClF₆N₂O₄S₂ = 392.67
外观与形状(20℃)	固体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气
Reaxys-RN	5833971
PubChem物质ID	87564753
MDL编号	MFCD00191833

技术规格

Appearance	White to Light yellow powder to crystal
Purity(GC)	min. 96.0 %

安全信息

图形或危害标志
信号词	警告
危险性说明	H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P302 + P352 + P312 : 如皮肤沾染：用水充分清洗。如感觉不适，呼叫急救中心/医生。 P304 + P340 + P312 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。

193246

J&K

2-[N,N-Bis(trifluoromethanesulfonyl)amino]-5-chloropyridine

98%

265元/1G; 883元/5G;

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基本信息

分子式	C₇H₃ClF₆N₂O₄S₂
分子量	392.68
熔点	45-47
沸点	77-90
MDL编码	MFCD00191833
Beilstein	5833971
存储条件	Store at 2-8℃

安全信息

图形或危害标志	LF
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
TSCA	否

L16929

Alfa Aesar

2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine

99%

1008元/1g; 2773元/5g;

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应用
2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine provides good yields of vinyl triflates from the corresponding ketone enolates or dienolates. It is used in the total synthesis of (-)-porantheridine and the trans decahydroquinoline alkaloid (+)-219A. It is also used as a reactant for Suzuki-Miyaura cross coupling, synthesis of nicotinic acetylcholine receptor-selective ligands, enantioselective desymmetrizing palladium catalyzed carbonylation reactions, synthesis of high affinity niacin receptor GPR109A agonists and in preparation of heteroaromatics.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under dry inert gas. It is sensitive to moisture.

基本信息

MDL
MFCD00191833

EINECS
000-000-0

分子式
C₇H₃ClF₆N₂O₄S₂

分子量
392.68

熔点
44-47°

灵敏度
Keep Cold. Moisture Sensitive.

溶解性
Reacts with water.

Beilstein
5833971

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

403644

Sigma-Aldrich

N-(5-Chloro-2-pyridyl)bis(trifluoromethanesulfonimide)

96%

252.24元/1 G; 981.36元/5 G;

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产品说明

应用

反应物用于：
Suzuki-Miyaura 交叉偶联
烟碱乙酰胆碱受体选择性配体的合成
钯催化羰基化反应的对映选择性去对称化
高亲和力烟酸受体 GPR109A 激动剂的合成
杂芳烃的制备
用于由对应的酮烯醇化物或二烯醇化物生成高产率的三氟甲磺酸乙烯酯。

包装

1, 5 g in glass bottle

基本信息

经验(实验)分子式	C₇H₃ClF₆N₂O₄S₂
分子量	392.68
Beilstein	5833971
MDL编号	MFCD00191833
PubChem化学物质编号	24865208
NACRES	NA.22

产品性质

质量水平	100
测定	96%
mp	45-47 ℃ (lit.)
web metadata keyword.default	Comins reagent, triflating, enoltriflate, enoltri-flate, vinyl triflates, synthesis, trifluoromethanesulfonyl, CF3SO2, N N-Bis(trifluoromethylsulfonyl)-5-chloro-2-pyridylamine, 2-[N N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine; N-(5-Chloro-2-pyridyl)triflimide.
储存温度	2-8℃
SMILES string	FC(F)(F)S(=O)(=O)N(c1ccc(Cl)cn1)S(=O)(=O)C(F)(F)F
InChI	1S/C7H3ClF6N2O4S2/c8-4-1-2-5(15-3-4)16(21(17,18)6(9,10)11)22(19,20)7(12,13)14/h1-3H
InChI key	TUFGVZMNGTYAQD-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

009051

Fluorochem

2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine

95%

352元/5g; 1298元/25g; 4070元/100g;

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基本信息

CAS Number	145100-51-2
MDL Number	MFCD00191833
Melting Point	44-48℃

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .