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CAS: 145100-50-1
分子式: C7H4F6N2O4S2
分子量: 358.24
沸点: 80℃(0.25
熔点: 40-42℃
英文名称: 
2-(n,n-bis(trifluoromethylsulfonyl)amino)pyridine
n-(2-pyridyl)bis(trifluoromethane-sulfonimide)
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基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C7H4F6N2O4S2 = 358.23
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN5832565
PubChem物质ID87564759
MDL编号MFCD00191834

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Melting point38.0 to 42.0 ℃

物性(参考值)

熔点40 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
951173J&KN-(2-Pyridyl)bis(trifluoromethanesulfonimide)98%267元/1G;   503元/5G;   咨询

基本信息

分子式C7H4F6N2O4S2
分子量358.24
熔点40-42
沸点80-90
闪点110
MDL编码MFCD00191834
Beilstein5832565
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
L17433Alfa Aesar2-[N,N-Bis(trifluoromethylsulfonyl)amino]pyridine98%546元/1g;   2137元/5g;   咨询

应用
2-[N,N-Bis(trifluoromethylsulfonyl)amino]pyridine is a reactive agent used for conversion of lithium enolates of ketones to vinyl triflates.

备注
It is sensitive to moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents. Store under inert gas.

基本信息

MDL
MFCD00191834

分子式
C7H4F6N2O4S2

分子量
358.24

熔点
37-41°

沸点
97°/2mm

闪点
>110°(230°F)

灵敏度
Keep Cold. Moisture Sensitive.

溶解性
Hydrolyzes in water.

Beilstein
5832565

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

C38765Alfa AesarN-(2-Pyridyl)bis(trifluoromethanesulfonimide)97%3061元/5g;   13219元/25g;   咨询

基本信息

Ref#
38765

MDL
191834

分子式
C7 H4 F6 N2 O4 S2

分子量
358.24

闪点
110

安全信息

危险等级
6.1

包装组
III

403636Sigma-AldrichN-(2-Pyridyl)bis(trifluoromethanesulfonimide)96%2006.29元/5 G;   咨询

产品说明

一般描述

N-(2-Pyridyl)bis(trifluoromethanesulfonimide) (2-[N,N-Bis(trifluoromethylsulfonyl)amino]pyridine, N,N-Bis(trifluoromethylsulfonyl)-2-pyridylamine)) is a useful triflating reagent. It has been synthesized by reacting 2-aminopyridine and triflic anhydride.

应用

N-(2-Pyridyl)bis(trifluoromethanesulfonimide) may be used in the synthesis of aryl triflates and vinyl triflates.

包装

5 g in glass bottle

基本信息

经验(实验)分子式C7H4F6N2O4S2
分子量358.24
Beilstein5832565
MDL编号MFCD00191834
PubChem化学物质编号24865207
NACRESNA.22

产品性质

质量水平100
测定96%
bp80-90 ℃/0.25 mmHg (lit.)
mp40-42 ℃ (lit.)
储存温度2-8℃
SMILES stringFC(F)(F)S(=O)(=O)N(c1ccccn1)S(=O)(=O)C(F)(F)F
InChI1S/C7H4F6N2O4S2/c8-6(9,10)20(16,17)15(5-3-1-2-4-14-5)21(18,19)7(11,12)13/h1-4H
InChI keyDXLQEJHUQKKSRB-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)230.0 °F - closed cup
闪点(C)110 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
009052Fluorochem2-[N,N-Bis(trifluoromethylsulphonyl)amino]pyridine(triflating reagent)95%264元/1g;   1078元/5g;   1606元/10g;   3454元/25g;   咨询

基本信息

CAS Number145100-50-1
MDL NumberMFCD00191834
Melting Point40℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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