| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| S769161 | MACKLIN | 三氟甲烷磺酸钪 | 99.995% trace metals basis | 688元/1g; | 咨询 |
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| S817718 | MACKLIN | 三氟甲烷磺酸钪 | 98% | 30元/250mg; 59元/1g; 129元/5g; 365元/25g; 900元/100g; | 咨询 |
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| T1663 | TCI | Scandium(III) Trifluoromethanesulfonate | >98.0%(T) | 755元/1G; 2335元/5G; | 咨询 |
基本信息 | 纯度/分析方法 | >98.0%(T) | | 分子式/分子量 | C3F9O9S3Sc = 492.15 | | 外观与形状(20℃) | 固体 | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 湿气 (吸湿) | | Reaxys-RN | 8510151 | | PubChem物质ID | 87577404 | | MDL编号 | MFCD00192433 |
技术规格 | Appearance | White to Almost white powder to crystal | | Purity(Chelometric Titration) | min. 98.0 % |
物性(参考值) 安全信息 | 图形或危害标志 |  | | 信号词 | 警告 | | 危险性说明 | H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
| | 防范说明 | P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染：用水充分清洗。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激：求医/就诊。
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| 302513 | J&K | Scandium(III) Triflate | 98% | 242元/250MG; 679元/1G; | 咨询 |
基本信息 | 分子式 | C3F9O9S3Sc | | 分子量 | 492.16 | | MDL编码 | MFCD00192433 | | Beilstein | 8510151 |
安全信息 | 图形或危害标志 | | | 提示语 | Warning | | 危险说明 | H315
H319
H335 | | 防范说明 | P261
P305+P351+P338 | | WGK | 3 |
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| 21-2000 | Strem | Scandium(III) Trifluoromethanesulfonate | min. 98% | 334元/250mg; 751元/1g; 2600元/5g; | 咨询 |
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| 040566 | Alfa Aesar | Scandium(III) Trifluoromethanesulfonate | 98% | 387元/250mg; 1288元/1g; 4492元/5g; | 咨询 |
应用
Scandium(III) trifluoromethanesulfonate is widely used as a catalyst in hydrothiolation, selective two-electron reduction of oxygen by ferrocene derivatives and vinylogous Fridel-crafts alkylation of indoles and pyrrole in water. It is involved in the Mukaiyama aldol addition and stereochemically catalyzes the radical polymerization of acrylates. It acts as a Lewis acid catalyst and used in the synthesis of bullvalone via a stabilized sulfur ylide. 备注
Incompatible with strong oxidizing agents. 基本信息 MDL
MFCD00798539 分子式
Sc(OSO2CF3)3 分子量
492.16 灵敏度
Hygroscopic. Ambient temperatures. 形态
Powder 溶解性
Soluble in water, alcohol and acetonitrile. GHS危害和防范说明 GHS符号
Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险等级
8 包装组
III 危险类别
36/37/38
Irritating to eyes, respiratory system and skin. 安全等级
26-36
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing. TSCA
否 |
| C36389 | Alfa Aesar | Scandium(III) Trifluoromethanesulfonate | 95% | 1075元/1g; 2701元/5g; | 咨询 |
基本信息 Ref#
36389 MDL
192433 分子式
C3 F9 O9 S3 Sc 分子量
492.17 形态
Powder 安全信息 危险等级
8 包装组
III |
| 483354 | Sigma-Aldrich | Scandium(III) Triflate | 99.995% trace metals basis | 808.55元/1 G; | 咨询 |
基本信息 | 线性分子式 | Sc(SO3CF3)3 | | 分子量 | 492.16 | | Beilstein | 8510151 | | MDL编号 | MFCD00192433 | | PubChem化学物质编号 | 24871885 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 测定 | 99.995% trace metals basis | | reaction suitability | core: scandium
reagent type: catalyst | | mp | >300 ℃ | | SMILES string | [Sc+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F | | InChI | 1S/3CHF3O3S.Sc/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3 | | InChI key | HZXJVDYQRYYYOR-UHFFFAOYSA-K |
安全信息 | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
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| 418218 | Sigma-Aldrich | Scandium(III) Triflate | 99% | 264.52元/250 MG; 808.55元/1 G; 2783.24元/5 G; | 咨询 |
产品说明 一般描述 三氟甲磺酸钪是一种非常活跃、高效、可回收和可重复使用的酰化催化剂。三氟甲磺酸钪是弗里德尔-克拉夫茨酰化反应、狄尔斯-阿尔德反应和其他碳-碳键形成反应的重要催化剂。 它还可以立体化学催化丙烯酸酯的自由基聚合反应。(4′S,5′S)-2,6-双[4′-(三异丙基)氧甲基-5′-苯基-1′,3′-恶唑啉-2′-yl]吡啶的三氟甲磺酸钪络合物，已被用作取代吲哚与甲基(E)-2-氧代-4-芳基-3-丁烯酸甲酯之间的不对称弗里德尔-克拉夫茨反应的催化剂。 应用 三氟甲磺酸钪作为催化剂用于：
- 芳香族和脂肪族硫醇的加氢硫醇反应。
- 二茂铁衍生物对O2的选择性双电子还原。
- 吲哚和吡咯在水中的烷基化反应。
- β腈酮的合成。
- 与三乙基硅烷结合，通过还原方式开放功能化的吡喃糖苷环。
- 通过稳定的硫叶立德合成牛酮的关键步骤。
包装 250 mg in glass bottle
1, 5 g in glass bottle 基本信息 | 线性分子式 | Sc(SO3CF3)3 | | 分子量 | 492.16 | | Beilstein | 8510151 | | MDL编号 | MFCD00192433 | | PubChem化学物质编号 | 24866212 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 测定 | 99% | | reaction suitability | core: scandium
reagent type: catalyst | | SMILES string | [Sc+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F | | InChI | 1S/3CHF3O3S.Sc/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3 | | InChI key | HZXJVDYQRYYYOR-UHFFFAOYSA-K |
安全信息 | 储存分类代码 | 13 - Non Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
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| 009343 | Fluorochem | Scandium (III) triflate | 99% | 242元/1g; 660元/5g; | 咨询 |
基本信息 | CAS Number | 144026-79-9 | | MDL Number | MFCD00192433 | | Melting Point | 300℃ |
安全信息 | 图形或危害标志 | | | 危险性说明 | H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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