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CAS: 14268-66-7
分子式: C7H7NO2
分子量: 137.13
沸点: 144℃(16
熔点: 38-43℃
中文名称: 
3,4-(亚甲二氧基)苯胺
3,4-甲二氧苯胺
3,4-亚甲二氧基苯胺
胡椒胺
英文名称: 
1,3-benzodioxol-5-amine
3,4-(methylenedioxy)aniline
3,4-Methylenedioxyaniline
3,4-Methylene Dioxy Aniline
4-Amino-1,2-methylenedioxybenzene
5-Amino-1,3-benzodioxole
用途: 用作奥索利酸中间体
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M831091MACKLIN3,4-亚甲二氧基苯胺98%30元/5g;   57元/25g;   177元/100g;   765元/500g;   展开
储存:2~8℃
状态:淡到暗棕色或黑色晶体或熔融固体
M0741TCI3,4-Methylenedioxyaniline>98.0%(GC)(T)350元/25G;   1290元/100G;   4690元/500G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C7H7NO2 = 137.14
外观与形状(20℃)固体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况空气,加热
Reaxys-RN4919
PubChem物质ID87572747
SDBS (AIST Spectral DB)13450
MDL编号MFCD00005832

技术规格

AppearanceWhite to Gray to Brown powder to crystal
Purity(GC)min. 98.0 %
Purity(Nonaqueous Titration)min. 98.0 %
Melting point41.0 to 46.0 ℃

物性(参考值)

熔点44 ℃
沸点156 ℃/30 mmHg

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
A12975Alfa Aesar3,4-(Methylenedioxy)aniline98+%565元/10g;   1998元/50g;   8220元/250g;   展开

应用
3,4-(Methylenedioxy)aniline is an pharmaceutically important aniline derivative. It undergoes N-alkylation with cyclic secondary alkylamines in the presence of Shvo catalyst to yield N-arylpyrrolidines. 3,4-(Methylenedioxy)aniline was used in the synthesis of γ-glutamylanilides.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible to strong acids, acid chlorides, acid anhydrides. Air & Light Sensitive. Stable under recommended storage conditions.

基本信息

MDL
MFCD00005832

EINECS
238-161-6

分子式
C7H7NO2

分子量
137.14

熔点
40-45°

沸点
144°/16mm

闪点
142°(287°F)

灵敏度
Air Sensitive. Light Sensitive. Ambient temperatures.

形态
Crystalline solid

溶解性
Slightly soluble in water.

Beilstein
4919

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H331-H315-H319
Harmful if swallowed.Harmful in contact with skin.Toxic if inhaled.Causes skin irritation.Causes serious eye irritation.

Precautionary Statements
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
20/21/22-36/38
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

TSCA

C17147Alfa Aesar3,4-(Methylenedioxy)aniline97%735元/10g;   2147元/50g;   展开

基本信息

Ref#
17147

MDL
5832

分子式
C7 H7 N O2

分子量
137.14

闪点
142

安全信息

危险等级
6.1

包装组
III

161497Sigma-Aldrich3,4-(Methylenedioxy)aniline97%371.62元/10 G;   1765.21元/50 G;   展开

产品说明

一般描述

3,4-(亚甲基二氧基)苯胺是药学上重要的苯胺衍生物。在 Shvo 催化剂的存在下,它与环状仲烷基胺进行 N-烷基化反应,生成 N-芳基吡咯烷。

应用

3,4-(亚甲基二氧基)苯胺用于合成 γ-谷氨酰苯胺。

包装

10, 50 g in glass bottle

基本信息

经验(实验)分子式C7H7NO2
分子量137.14
Beilstein4919
EC 号238-161-6
MDL编号MFCD00005832
PubChem化学物质编号24849933
NACRESNA.22

产品性质

测定97%
bp144 ℃/16 mmHg (lit.)
mp39-41 ℃ (lit.)
SMILES stringNc1ccc2OCOc2c1
InChI1S/C7H7NO2/c8-5-1-2-6-7(3-5)10-4-9-6/h1-3H,4,8H2
InChI keyXGNXYCFREOZBOL-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
033052Fluorochem3,4-(Methylenedioxy)aniline95%396元/25g;   1364元/100g;   4334元/1kg;   展开

基本信息

CAS Number14268-66-7
MDL NumberMFCD00005832
Boiling Point144℃/16mm
Melting Point39-41℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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