| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| B802404 | MACKLIN | 双(三苯基膦)氯化镍(Ⅱ) | 98% | 30元/5g; 42元/25g; 139元/100g; 668元/500g; | 咨询 |
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| B1571 | TCI | Bis(triphenylphosphine)nickel(II) Dichloride | >96.0%(T) | 340元/10G; 1390元/100G; | 咨询 |
基本信息 | 纯度/分析方法 | >96.0%(T) | | 分子式/分子量 | C36H30Cl2NiP2 = 654.18 | | 外观与形状(20℃) | 固体 | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 空气 | | Reaxys-RN | 14619310 | | PubChem物质ID | 87564474 | | SDBS (AIST Spectral DB) | 23196 | | MDL编号 | MFCD00009592 |
技术规格 | Appearance | Dark green to Dark blue to Black powder to crystal | | Purity(Chelometric Titration) | min. 96.0 % | | Purity(Iodometric Titration) | min. 96.0 % |
物性(参考值) 安全信息 | 图形或危害标志 |   | | 信号词 | 危险 | | 危险性说明 | H302 : 吞咽有害。
H372 : 长期或反复接触会对器官造成损害。
H317 : 可能造成皮肤过敏反应。
H334 : 吸入可能导致过敏或哮喘病症状或呼吸困难。
H350 : 可能致癌。
| | 防范说明 | P501 : 将内装物/容器送到批准的废物处理厂处理。
P272 : 受沾染的工作服不得带出工作场地。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P284 : [在通风不足的情况下]戴呼吸防护装置。
P302 + P352 : 如皮肤沾染：用水充分清洗。
P308 + P313 : 如接触到或有疑虑：求医/就诊。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P304 + P340 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。
P333 + P313 : 如发生皮肤刺激或皮疹：求医/就诊。
P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。
P405 : 存放处须加锁。
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相关法规 |
| 534325 | J&K | Dichlorobis(triphenylphosphine)nickel(II) | 98% | 123元/5G; 523元/25G; 1723元/100G; | 咨询 |
基本信息 | 分子式 | C36H30P2·NiCl2 | | 分子量 | 654.17 | | 熔点 | 250 | | MDL编码 | MFCD00009592 | | Beilstein | 14619310 | | EINECS 编号 | 238-154-8 |
安全信息 | 图形或危害标志 |   | | 提示语 | Danger | | 危险说明 | H314
H317
H350 | | 防范说明 | P201
P280
P308+P313 | | UN号码 | 2923 | | 危险分类 | 8 | | 次要危险性 | 6.1 | | 包装等级 | II | | WGK | 3 | | RTECS | QR6170000 |
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| 28-0095 | Strem | Bis(triphenylphosphine)nickel(II) chloride | 99% | 360元/5g; 1185元/25g; | 咨询 |
Technical Notes: 1. Catalyst for hydrosilylation of styrene with diphenysilane . 2.Catalyst for carboxylation of various aryl chlorides and other derivatives . 3.Catalyst for C-P cross-coupling reactions of diphenylphosphine oxide with aryl chloride. 4. Catalyst for N- Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides, tosylates, and sulfamates. 5.Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage . References: 1. Org. Lett., 2012, 14, 914. 2. J. Am. Chem. Soc., 2012, 134, 9106. 3. Org. Biomol. Chem., 2012,10, 9627. 4. J. Org. Chem., 2014, 79, 7132. 5. Chem. Eur. J., 2016, 22, 10420. |
| 013930 | Alfa Aesar | Dichlorobis(triphenylphosphine)nickel(II) | 98% | 662元/10g; 2720元/50g; | 咨询 |
应用
Dichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization. 备注
Store at -20?°C. It is sensitive to moisture, air and heat. Handle and store under inert gas. Hygroscopic in nature. 基本信息 MDL
MFCD00009592 EINECS
238-154-8 分子式
NiCl2[P(C6H5)3]2 分子量
654.18 熔点
ca 225° dec. 灵敏度
Moisture Sensitive. Store under Nitrogen. Ambient temperatures. 形态
Crystalline powder 溶解性
Insoluble in water. GHS危害和防范说明 GHS符号
Hazard Statements
H302-H317-H350
Harmful if swallowed.May cause an allergic skin reaction.May cause cancer. Precautionary Statements
P201-P261-P280-P301+P312a-P405-P501a
Obtain special instructions before use.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.Wear protective gloves/protective clothing/eye protection/face protection.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险等级
8 包装组
III 危险类别
49-22-43
May cause cancer by inhalation.Harmful if swallowed.May cause sensitization by skin contact. 安全等级
53-20-24-37-45-60
Avoid exposure - obtain special instructions before use.When using do not eat or drink.Avoid contact with skin.Avoid contact with skin.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste RTECS
QR6170000 TSCA
是 |
| C21750 | Alfa Aesar | Bis(triphenylphosphine)nickel(II)chloride | 98% | 816元/10g; 3030元/50g; | 咨询 |
基本信息 Ref#
21750 MDL
9592 分子式
C36 H30 Cl2 Ni P2 分子量
654.2 形态
Crystalline powder 安全信息 危险等级
8 包装组
III |
| 237116 | Sigma-Aldrich | Bis(triphenylphosphine)nickel(II) Dichloride | synthesis grade | 474元/10 G; 2069.19元/50 G; | 咨询 |
产品说明 应用 芳基甲磺酸盐和烯丙基碳酸盐与有机硼酸锂的偶联反应催化剂。 包装 10, 50 g in glass bottle 基本信息 | 线性分子式 | [(C6H5)3P]2NiCl2 | | 分子量 | 654.17 | | EC 号 | 238-154-8 | | MDL编号 | MFCD00009592 | | PubChem化学物质编号 | 24854218 | | NACRES | NA.22 |
产品性质 | 等级 | synthesis grade | | 质量水平 | 100 | | reaction suitability | core: nickel
reagent type: catalyst | | mp | 250 ℃ (dec.) (lit.) | | SMILES string | Cl[Ni]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6 | | InChI | 1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2 | | InChI key | ZBRJXVVKPBZPAN-UHFFFAOYSA-L |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H317 - H350 - H412 | | 预防措施声明 | P201 - P273 - P280 - P302 + P352 - P308 + P313 | | 危险分类 | Aquatic Chronic 3 - Carc. 1B - Skin Sens. 1 | | 储存分类代码 | 6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges |
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| 529621 | Sigma-Aldrich | Bis(triphenylphosphine)nickel(II) Dichloride | 99.99% trace metals basis | 587.51元/10 G; | 咨询 |
产品说明 应用 Ni(PPh3)2Cl2 可被用于利用氯二苯基膦进行镍辅助的联芳基O,N三氟甲磺酸磷化。 包装 10 g in glass bottle 基本信息 | 线性分子式 | [(C6H5)3P]2NiCl2 | | 分子量 | 654.17 | | EC 号 | 238-154-8 | | MDL编号 | MFCD00009592 | | PubChem化学物质编号 | 24877695 | | NACRES | NA.23 |
产品性质 | 质量水平 | 100 | | 测定 | 99.99% trace metals basis | | 形式 | powder or crystals | | reaction suitability | core: nickel | | mp | 250 ℃ (dec.) (lit.) | | SMILES string | Cl[Ni]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6 | | InChI | 1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2 | | InChI key | ZBRJXVVKPBZPAN-UHFFFAOYSA-L |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H317 - H350 - H412 | | 预防措施声明 | P201 - P273 - P280 - P302 + P352 - P308 + P313 | | 危险分类 | Aquatic Chronic 3 - Carc. 1B - Skin Sens. 1 | | 储存分类代码 | 6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges |
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| 950163 | Amethyst | Dichlorobis(triphenylphosphine)nickel(II) | 98%, 用于合成 | 58元/5G; 135元/25G; 419元/100G; | 咨询 |
基本信息 | 分子式 | C36H30P2·NiCl2 | | 分子量 | 654.17 | | 熔点 | 250 | | MDL编码 | MFCD00009592 | | Beilstein | 14619310 | | EINECS 编号 | 238-154-8 |
安全信息 | 图形或危害标志 | | | 提示语 | Danger | | 危险说明 | H314
H317
H350 | | 防范说明 | P201
P280
P308+P313 | | UN号码 | 2923 | | 危险分类 | 8 | | 次要危险性 | 6.1 | | 包装等级 | II | | WGK | 3 | | RTECS | QR6170000 |
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| 049727 | Fluorochem | Bis(triphenylphosphine)nickel(II) chloride | >96.0%(T) | 220元/1g; 748元/10g; 3476元/100g; | 咨询 |
基本信息 | CAS Number | 14264-16-5 | | MDL Number | MFCD00009592 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H302: Harmful if swallowed.
H317: May cause an allergic skin reaction.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H350: May cause cancer ..
H372: Causes damage to organs , respiratory system..
| | 防范说明 | P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear
P281: Use personal protective equipment as required.
P285: In case of inadequate ventilation wear respiratory protection.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P341: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P314: Get medical advice/attention if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P333 + P313: If skin irritation or rash occurs: Get medical advice/attention.
P342 + P311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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