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CAS: 14221-01-3
分子式: C72H60P4Pd
分子量: 1155.58
熔点: 103 - 107°C
中文名称: 
四(三苯基磷)合钯
四(三苯基膦)钯
英文名称: 
tetrakis(triphenylphosphine)palladium
tetrakis(triphenylphosphine)palladium(o)
( beta-4)-palladiu
tetrakis(triphenylphosphine)palladium(0)
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T799152MACKLIN四(三苯基膦)钯(0)99.9% metals basis323元/250mg;   1029元/1g;   2059元/5g;   展开
储存:-20°C, 避光, 惰性气体
状态:浅黄色到琥珀色到深绿色粉末到晶体
T819527MACKLIN四(三苯基膦)钯(0)99% metals basis,Pd 9.0%368元/1g;   1025元/5g;   3707元/25g;   展开
储存:2~8℃
状态:黄色到绿色到棕色到红色粉末或晶体
T1350TCITetrakis(triphenylphosphine)palladium(0)>97.0%(T)490元/1G;   2290元/5G;   9990元/25G;   展开

基本信息

纯度/分析方法>97.0%(T)
分子式/分子量C72H60P4Pd = 1155.59
外观与形状(20℃)固体
储存温度-20℃
储存在惰性气体下存放于惰性气体之中
应避免的情况空气,加热
Reaxys-RN6704828
PubChem物质ID87577117
MDL编号MFCD00010012

技术规格

AppearanceLight yellow to Amber to Dark green powder to crystaline
Purity(Chelometric Titration)97.0 to 106.0 %

物性(参考值)

熔点105 ℃
182482J&KTetrakis(triphenylphosphine)palladium(0)99%240元/1G;   950元/5G;   4500元/25G;   展开

基本信息

分子式C72H60P4Pd
分子量1155.58
MDL编码MFCD00010012
Beilstein6704828
EINECS 编号238-086-9
存储条件Freezer -20℃

安全信息

WGK3
TSCA
46-2150StremTetrakis(triphenylphosphine)palladium(0)99% (99.9+%-Pd)825元/1g;   3121元/5g;   13110元/25g;   展开

Technical Notes:

1.Catalyst for Suzuki coupling of chiral secondary organoboronic esters.

2.Palladium-catalyzed SNAr reactions for the synthesis of heteroaryl ethers.

3.Catalyst for cross-coupling of a-diazocarbonyl compounds with arylboronic acids .

4.Diastereoselective synthesis of trans-1,2-diazetidines.

5.Palladium-catalyzed alkynyl iminium ion cyclization

6.Widely used reagent in a variety of transformations including Heck arylation, enyne and diynecycloisomerization.

7.Catalysts for cross-coupling.

010548Alfa AesarTetrakis(triphenylphosphine)palladium(0)99.8% (metals basis), Pd 9% min332元/0.5g;   968元/2g;   3905元/10g;   展开

应用
Widely used as a catalyst for palladium-catalyzed coupling reactions including Suzuki coupling, Sonogashira coupling, Heck reaction, Negishi coupling and Stille coupling. Used in isomerization, carbonylation, oxidation, and C-C bond formation reactions.

备注
Heat sensitive. Store below 4ƒ °C in tighlty closed containers, protected from light and air. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00010012

EINECS
238-086-9

分子式
Pd[P(C6H5)3]4

分子量
1155.57

熔点
100-105°

灵敏度
Store at -20°C. Air Sensitive. Store under Argon.

形态
Crystalline

溶解性
Insoluble in water. Soluble in benzene, ethanol and chloroform

Beilstein
6704828

GHS危害和防范说明

Hazard Statements
H413
May cause long lasting harmful effects to aquatic life.

安全信息

危险类别
53
May cause long-term adverse effects in the aquatic environment.

安全等级
60-61
This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

TSCA

L00953Alfa AesarTetrakis(triphenylphosphine)palladium(0)99%657元/1g;   展开

基本信息

MDL
MFCD00010012

EINECS
238-086-9

分子式
C72H60P4Pd

分子量
1155.58

熔点
100-105°

灵敏度
Store at -20°C. Air Sensitive. Store under Argon.

形态
Powder

GHS危害和防范说明

Hazard Statements
H413
May cause long lasting harmful effects to aquatic life.

安全信息

危险类别
53
May cause long-term adverse effects in the aquatic environment.

安全等级
60-61
This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

TSCA

C20238Alfa AesarTetrakis(triphenylphosphine)palladium(0)99%967元/1g;   3167元/5g;   11231元/25g;   38867元/100g;   展开

基本信息

Ref#
20238

MDL
10012

分子式
C72 H60 P4 Pd

分子量
1155.58

形态
Crystalline

C44140Alfa AesarTetrakis(triphenylphosphine)palladium(0)99.9%, (trace metal basis)1221元/1g;   3504元/5g;   展开

基本信息

Ref#
44140

MDL
10012

分子式
C72 H60 P4 Pd

分子量
1155.58

形态
Crystalline

216666Sigma-AldrichTetrakis(triphenylphosphine)palladium(0)99%559.29元/1 G;   1896.91元/5 G;   7952.24元/25 G;   17503.1元/4 X 25 G;   展开

产品说明

应用

钯催化交叉偶联反应应用指南
四(三苯基膦)钯(0)可用作以下反应的催化剂:

  • 根岸偶联反应(反应式1), 铃木偶联反应(反应式2),Stille偶联反应(反应式3),以及Sonogashira偶联反应(反应式4),以及Buchwald-Hartwig氨基化反应(反应式5)
  • 碘化乙烯的羰基化反应(反应式6)
  • 芳基溴化物的还原反应(反应式7)
  • 碳-锡键形成反应(反应式8)
Triphenyl Phosphine Catalyst

包装

1, 5, 25, 4×25 g in glass bottle

基本信息

线性分子式Pd[(C6H5)3P]4
分子量1155.56
Beilstein6704828
EC 号238-086-9
MDL编号MFCD00010012
PubChem化学物质编号24852971
NACRESNA.22

产品性质

质量水平200
测定99%
形式solid
reaction suitabilitycore: palladium
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Buchwald-Hartwig Cross Coupling Reaction
储存温度2-8℃
SMILES string[Pd].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12
InChI1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;
InChI keyNFHFRUOZVGFOOS-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H317 - H413
预防措施声明P261 - P264 - P273 - P280 - P301 + P312 - P302 + P352
危险分类Acute Tox. 4 Oral - Aquatic Chronic 4 - Skin Sens. 1
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
8.14761Sigma-AldrichTetrakis(triphenylphosphine)-palladium(0)for synthesis393.48元/500 MG;   923.53元/5 G;   展开

产品说明

分析说明

Assay (ICP-OES): ≥ 97.0 %

基本信息

线性分子式Pd(P(C6H5)3)4
分子量1155.56
MDL编号MFCD00010012
EC索引号238-086-9

产品性质

质量水平200
形式powder
mp103-107 ℃
储存温度2-8℃
InChI1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;
InChI keyNFHFRUOZVGFOOS-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H317 - H413
预防措施声明P261 - P264 - P273 - P280 - P301 + P312 - P302 + P352
危险分类Acute Tox. 4 Oral - Aquatic Chronic 4 - Skin Sens. 1
储存分类代码11 - Combustible Solids
WGKWGK 3
697265Sigma-AldrichTetrakis(triphenylphosphine)palladium(0)≥99.99% trace metals basis977.54元/500 MG;   1867.37元/2 G;   展开

产品说明

应用

钯催化交叉偶联反应应用指南

包装

2 g in glass bottle
500 mg in glass bottle

基本信息

线性分子式Pd[(C6H5)3P]4
分子量1155.56
Beilstein6704828
EC 号238-086-9
MDL编号MFCD00010012
PubChem化学物质编号329761903
NACRESNA.22

产品性质

质量水平200
测定≥99.99% trace metals basis
reaction suitabilitycore: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
储存温度2-8℃
SMILES string[Pd].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12
InChI1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;
InChI keyNFHFRUOZVGFOOS-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
034279FluorochemPalladium (0) tetrakis(triphenylphosphine)98%352元/1g;   1122元/5g;   5280元/25g;   展开

基本信息

CAS Number14221-01-3
MDL NumberMFCD00010012
Melting Point95-105℃
Density1.36

安全信息

危险性说明 H413: May cause long lasting harmful effects to aquatic life.
防范说明 P273: Avoid release to the environment.
P501: Dispose of contents/container to in accordance with local regulation .
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