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CAS: 141-86-6
分子式: C5H7N3
分子量: 109.1304
沸点: 285℃
熔点: 119-123℃
中文名称: 
2,6-二氨基吡啶
2,6-二氨基氮杂苯
2,6-吡啶二胺
英文名称: 
2,6-DAP
2,6-Pyridinediamine
2,6-diamino-pyridin
2,6-diaminopyridine
生产方法: 吡啶或2-氨基吡啶在更强烈的条件下胺化。
用途: 2,6-二氨基吡啶在国外目前主要用于生产一种止痛药——Phenazopyridine [CAS No.94-78-0],据说可缓解尿路感染等疾病引起的疼痛、灼烧及不适感。该药在美国为处方药,在加拿大属非处方药,在中国尚未生产。美国该药的商品名有:Azo-Standard、Baridium、Eridium、Geridium、Phenazodine、Pyridiate、Pyridium、Urodine、Urogesic、Viridium;加拿大该药的商品名有:Phenazo、Pyridium。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D807016MACKLIN2,6-二氨基吡啶98%29元/5g;   50元/25g;   108元/100g;   499元/500g;   2450元/2.5kg;   展开
储存:室温
状态:黄色到棕色到黑色粉末,晶体和/或块状
D916485MACKLIN2,6-二氨基吡啶Standard for GC, 99.9%196元/5g;   展开
储存:室温
状态:白色到灰红黄色到黑色晶体粉末
D916483MACKLIN2,6-二氨基吡啶99.5%86元/25g;   215元/100g;   599元/500g;   1088元/1kg;   展开
储存:室温
状态:白色-灰红黄色-黑色晶体-粉末
D1154TCI2,6-Diaminopyridine>98.0%(GC)(T)410元/25G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C5H7N3 = 109.13
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN108513
PubChem物质ID87567706
SDBS (AIST Spectral DB)4163
MDL编号MFCD00006329

技术规格

AppearanceWhite to Gray to Brown powder to crystal
Purity(GC)min. 98.0 %
Purity(Nonaqueous Titration)min. 98.0 %
Melting point120.0 to 124.0 ℃

物性(参考值)

熔点122 ℃
沸点285 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H317 : 可能造成皮肤过敏反应。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P272 : 受沾染的工作服不得带出工作场地。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P333 + P313 : 如发生皮肤刺激或皮疹:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。

相关法规

RTECS#US7570000
A12295Alfa Aesar2,6-Diaminopyridine98%520元/100g;   2163元/500g;   展开

应用
2,6-Diaminopyridine, used as a pharmaceutical intermediate and a hair dye coupler in oxidation/permanent formulations.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from strong oxidizing agents.

基本信息

MDL
MFCD00006329

EINECS
205-507-2

分子式
C5H7N3

分子量
109.13

熔点
118-121°

沸点
288°

闪点
155°(311°F)

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in water 180 g/L @ 20°C, acetone, ethanol, methanol, isopropanol, ethyl acetate.

Beilstein
108513

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H319-H335-H373
Toxic if swallowed.Causes serious eye irritation.May cause respiratory irritation.May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements
P260-P280i-P301+P310a-P305+P351+P338-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray.Wear eye/face protection.Wear eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
II

危险类别
25-36/37-48/21
Toxic if swallowed.Irritating to eyes and respiratory system.Harmful: danger of serious damage to health by prolonged exposure in contact with skin.

安全等级
22-36/37-45
Do not breathe dust.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

RTECS
US7570000

TSCA

C11238Alfa Aesar2,6-Diaminopyridine98%366元/25g;   594元/100g;   2539元/500g;   展开

基本信息

Ref#
11238

MDL
6329

分子式
C5 H7 N3

分子量
109.13

闪点
155

形态
Cream to brown cryst powder

安全信息

危险等级
6.1

包装组
II

8.03575Sigma-Aldrich2,6-Diaminopyridinefor synthesis884.94元/100 G;   展开

产品说明

分析说明

Assay (GC, area%): ≥ 97.0 % (a/a)
Melting range (lower value): ≥ 117 °C
Melting range (upper value): ≤ 121 °C
Identity (IR): passes test

基本信息

线性分子式2,6-(NH2)2C5H3N
分子量109.13
MDL编号MFCD00006329
EC索引号205-507-2

产品性质

质量水平200
测定≥97.0% (GC)
pH值(酸碱度)>7 ( in H2O)
bp159 ℃/13 hPa
mp115-118 ℃
转变温度flash point 155 ℃
储存温度2-30℃
InChI1S/C5H7N3/c6-4-2-1-3-5(7)8-4/h1-3H,(H4,6,7,8)
InChI keyVHNQIURBCCNWDN-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H301 - H315 - H319 - H335
预防措施声明P261 - P264 - P270 - P301 + P310 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)311.0 °F - closed cup
闪点(C)155 ℃ - closed cup
D24404Sigma-Aldrich2,6-Diaminopyridine98%446.56元/25 G;   664.76元/100 G;   3157.6元/500 G;   展开

基本信息

经验(实验)分子式C5H7N3
分子量109.13
Beilstein108513
EC 号205-507-2
MDL编号MFCD00006329
PubChem化学物质编号24893689
NACRESNA.22

产品性质

质量水平100
测定98%
bp285 ℃ (lit.)
mp117-122 ℃ (lit.)
SMILES stringNc1cccc(N)n1
InChI1S/C5H7N3/c6-4-2-1-3-5(7)8-4/h1-3H,(H4,6,7,8)
InChI keyVHNQIURBCCNWDN-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H301 - H315 - H319 - H335
预防措施声明P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGKWGK 3
闪点(F)311.0 °F - closed cup
闪点(C)155 ℃ - closed cup
V900606Sigma-Aldrich2,6-DiaminopyridineVetec, reagent grade, 98%276.53元/100 G;   展开

产品说明

包装

100 g in poly bottle

法律信息

Vetec is a trademark of sigma-aldrich International GmbH

基本信息

经验(实验)分子式C5H7N3
分子量109.13
Beilstein108513
EC 号205-507-2
MDL编号MFCD00006329
PubChem化学物质编号329829966

产品性质

等级reagent grade
产品线Vetec
测定98%
bp285 ℃ (lit.)
mp117-122 ℃ (lit.)
SMILES stringNc1cccc(N)n1
InChI1S/C5H7N3/c6-4-2-1-3-5(7)8-4/h1-3H,(H4,6,7,8)
InChI keyVHNQIURBCCNWDN-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H301 - H315 - H319 - H335
预防措施声明P301 + P330 + P331 + P310 - P305 + P351 + P338
危险分类Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGKWGK 3
闪点(F)311.0 °F - closed cup
闪点(C)155 ℃ - closed cup
DYE-103NAccuStandard2,6-Diaminopyridine185元/100mg;   展开
2,6-Diaminopyridine2,6-二氨基吡啶141-86-6
DYE-103SAccuStandard2,6-Diaminopyridine,100 μg/mL in Methanol100 μg/mL in Methanol185元/1mL;   展开
2,6-Diaminopyridine2,6-二氨基吡啶141-86-6100 µg/mL
077786Fluorochem2,6-Diaminopyridine>99%220元/1g;   264元/25g;   682元/100g;   1342元/250g;   4378元/1kg;   展开

基本信息

CAS Number141-86-6
MDL NumberMFCD00006329
Boiling Point285℃
Melting Point115-122℃
Density1.711

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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