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CAS: 140-11-4
分子式: C9H10O2
分子量: 150.18
沸点: 206 °C(lit.)
熔点: −51 °C(lit.)
中文名称: 
苄基乙酸酯
乙酸苄酯
乙酸苯基甲基酯
乙酸苯甲酯
醋酸苄酯
英文名称: 
Benzyl acetate
Acetic acid, phenylmethyl ester
acetic acid benzyl ester
acetic acid phenylmethyl ester
acetic acid, benzyl ester
acetoxymethylbenzene
alpha-acetoxytoluene
benzyl ethanoate
benzylester kyseliny octove
nci-c06508
phenylmethyl acetate
Acetic acid,phenylmethyl ester
Benzylacetat
展开更多英文名
性质描述: 无色油状液体,具有茉莉花型特殊芳香。熔点-51.5℃,沸点215.5℃,相对密度1.0550,折射率1.5232,闪点102℃,汽化热401.5J/g,比热容1.025J/(g·℃)。与乙醇、乙醚等多数溶剂混溶,几乎不溶于水。
生产方法: 1.以苄醇与醋酸为原料,在硫酸催化下直接酯化生成乙酸苄酯,再经中和、水洗、分馏得成品。2.以氯苄与醋酸钠为原料,在催化剂吡啶和二甲基苯胺存在下进行反应生成醋酸苄酯。再经水洗、蒸馏得成品。
用途: 1.香料方面的用途。乙酸苄酯是茉莉花等浸膏的主要组分,是香馨、伊兰等花香香精调配中不可缺少的香料,因价廉,多用于皂用和其他工业用香精。常在茉莉、白兰、玉簪、月下香和水仙等香精中大量使用,也可少量用于生梨、苹果、香蕉、桑椹子等型食用香精中。2.溶剂方面的用途 乙酸苄酯在水中溶解0.23%(重量),不溶于甘油。但能与醇、醚、酮及酯肪烃,芳香烃等混溶。对油脂、硝化纤维素、乙酸纤维素等都有良好的溶解能力,还能溶解松香、甘油三松香酸酯、香豆酮树脂等。因此被用作虫胶漆、醇酸树脂、硝酸纤维素、乙酸纤维素、染料、油脂、印刷油墨等的溶剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B802625MACKLIN乙酸苄酯分析标准品,≥99.7%(GC)550元/5ml;   展开
储存:室温
状态:无色到浅黄色澄清液体
折射率:n20/D 1.502(lit.)
B802623MACKLIN乙酸苄酯99%39元/250g;   116元/1kg;   414元/5kg;   展开
储存:室温
状态:无色液体
折射率:n20/D 1.502(lit.)
A0022TCIBenzyl Acetate>99.0%(GC)130元/25G;   280元/500G;   展开

基本信息

纯度/分析方法>99.0%(GC)
分子式/分子量C9H10O2 = 150.18
外观与形状(20℃)液体
Reaxys-RN1908121
PubChem物质ID87561725
SDBS (AIST Spectral DB)810
Merck Index (14)1123
MDL编号MFCD00008712

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 99.0 %

物性(参考值)

熔点-51 ℃
沸点214 ℃
闪点102 ℃
比重1.06
折射率1.50
水溶性不溶
溶解性(可与之混溶)乙醚,醇
溶解性(可溶于)苯,氯仿,丙酮

安全信息

图形或危害标志
信号词危险
危险性说明H303 : 吞咽可能有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H370 : 会损害器官。
H372 : 长期或反复接触会对器官造成损害。
H373 : 长期或反复接触可能损害器官。
H336 : 可能造成昏昏欲睡或眩晕。
H401 : 对水生生物有毒。
H412 : 对水生生物有害并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P308+P311 : 如接触到或有疑虑:呼叫急救中心/医生。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

相关法规

RTECS#AF5075000
418699J&KBenzyl Acetate99%248元/500ML;   展开

基本信息

分子式C9H10O2
分子量150.17
熔点-51
沸点206
闪点95
密度1.054
折光率(n20D)1.5020
MDL编码MFCD00008712
Beilstein1908121
Merck14,1123
EINECS 编号205-399-7

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
H411
防范说明P261
P273
P305+P351+P338
UN号码3082
危险分类9
包装等级III
WGK1
RTECSAF5075000
TSCA
B23472Alfa AesarBenzyl Acetate99%590元/500g;   1334元/2500g;   展开

应用
Benzyl acetate can be used as a high boiling point solvent in coatings, like ink coating, binding agent and paint remover. It is used in soap and other chemical essences and has the effect of promote in floral and fantasy essences in jasmine, white orchid, fragrant plantain lily, gekkakou, narcissus and other essences. It is a plasticizer for ionophore membranes.

备注
Store in a cool, dry conditions, in well sealed conditions. Store away from oxidizing agents.

基本信息

MDL
MFCD00008712

EINECS
205-399-7

分子式
CH3CO2CH2C6H5

分子量
150.18

熔点
-51°

沸点
205-207°

闪点
95°(203°F)

密度
1.053

折射率
1.5020

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Soluble in water 3.1 g/L.

Beilstein
1908121

Merck
14,1123

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H315-H319-H335-H411
May be harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.Toxic to aquatic life with long lasting effects.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38-51/53
Irritating to eyes, respiratory system and skin.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
23-26-37-57-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Use appropriate container to avoid environmental contamination.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
AF5075000

TSCA

C10582Alfa AesarBenzyl Acetate99+%678元/250ml;   1976元/1L;   展开

基本信息

Ref#
10582

MDL
8712

分子式
C9 H10 O2

分子量
150.18

闪点
102

密度
1055

形态
Liquid

B15805Sigma-AldrichBenzyl Acetate≥99%388.08元/100 G;   722.76元/1 KG;   展开

基本信息

线性分子式CH3COOCH2C6H5
分子量150.17
Beilstein1908121
EC 号205-399-7
MDL编号MFCD00008712
PubChem化学物质编号24891598
NACRESNA.22

产品性质

质量水平100
蒸汽压23 mmHg ( 110 ℃)
测定≥99%
形式liquid
自燃温度862 °F
折射率n20/D 1.502 (lit.)
bp206 ℃ (lit.)
mp−51 ℃ (lit.)
密度1.054 g/mL at 25 ℃ (lit.)
SMILES stringCC(=O)OCc1ccccc1
InChI1S/C9H10O2/c1-8(10)11-7-9-5-3-2-4-6-9/h2-6H,7H2,1H3
InChI keyQUKGYYKBILRGFE-UHFFFAOYSA-N

安全信息

危险声明H412
危险分类Aquatic Chronic 3
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)203.0 °F - closed cup
闪点(C)95 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
W213500Sigma-AldrichBenzyl Acetate≥99%, FCC, FG404.65元/;   566.48元/1 KG;   1742.05元/10 KG;   2488.9元/25 KG;   展开

产品说明

一般描述

乙酸苄酯是一种脂族风味酯,存在于多种植物油中,例如茉莉、风信子、栀子花和杜鹃花。

包装

10 kg in composite drum
25 kg in poly drum
1 kg in poly bottle

基本信息

线性分子式CH3COOCH2C6H5
分子量150.17
FEMA编号2135
Beilstein1908121
EC 号205-399-7
欧洲委员会编号204
MDL编号MFCD00008712
PubChem化学物质编号24900872
Flavis编号9.014
NACRESNA.21

产品性质

质量水平400
生物来源synthetic
等级FG
Halal
Kosher
agencymeets purity specifications of JECFA
reg. complianceEU Regulation 1334/2008 & 178/2002
FCC
FDA 21 CFR 117
FDA 21 CFR 172.515
蒸汽压23 mmHg ( 110 ℃)
测定≥99%
自燃温度862 °F
折射率n20/D 1.502 (lit.)
bp206 ℃ (lit.)
mp−51 ℃ (lit.)
密度1.054 g/mL at 25 ℃ (lit.)
文件see Safety & Documentation for available documents
性状检查fruity; floral; sweet
application(s)flavors and fragrances
食品过敏原no known allergens
SMILES stringCC(=O)OCc1ccccc1
InChI1S/C9H10O2/c1-8(10)11-7-9-5-3-2-4-6-9/h2-6H,7H2,1H3
InChI keyQUKGYYKBILRGFE-UHFFFAOYSA-N

安全信息

危险声明H412
危险分类Aquatic Chronic 3
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)203.0 °F - closed cup
闪点(C)95 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
50475SupelcoBenzyl Acetateanalytical standard1271.72元/5 ML;   展开

产品说明

一般描述

Benzyl acetates are generally used as flavoring agents and preservatives. They find applications in foods and beverages, drugs, cosmetics, pharmaceuticals, etc.

应用

Benzyl acetate has been used as a reference standard for the determination of the analyte in e-cigarette refill solutions as flavoring additives and in muskmelon and watermelon fruits as aromatic agents by gas chromatography-mass spectrometry (GC-MS), and in scented consumer products as odor compounds by gas chromatography-olfactometry (GC-O).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

基本信息

线性分子式CH3COOCH2C6H5
分子量150.17
Beilstein1908121
EC 号205-399-7
MDL编号MFCD00008712
PubChem化学物质编号329757602
NACRESNA.24

产品性质

质量水平100
等级analytical standard
蒸汽压23 mmHg ( 110 ℃)
测定≥99.7% (GC)
自燃温度862 °F
保质期limited shelf life, expiry date on the label
technique(s)HPLC: suitable
gas chromatography (GC): suitable
折射率n20/D 1.502 (lit.)
n20/D 1.503
bp206 ℃ (lit.)
mp−51 ℃ (lit.)
密度1.054 g/mL at 25 ℃ (lit.)
application(s)cleaning products
cosmetics
environmental
flavors and fragrances
food and beverages
personal care
格式neat
SMILES stringCC(=O)OCc1ccccc1
InChI1S/C9H10O2/c1-8(10)11-7-9-5-3-2-4-6-9/h2-6H,7H2,1H3
InChI keyQUKGYYKBILRGFE-UHFFFAOYSA-N

安全信息

危险声明H412
危险分类Aquatic Chronic 3
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)203.0 °F - closed cup
闪点(C)95 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
W213519Sigma-AldrichBenzyl Acetatenatural, ≥99%, FCC, FG433.21元/;   1157.94元/100 G;   3790.54元/1 KG;   14662.2元/5 KG;   展开

基本信息

线性分子式CH3COOCH2C6H5
分子量150.17
FEMA编号2135
Beilstein1908121
EC 号205-399-7
欧洲委员会编号204
MDL编号MFCD00008712
PubChem化学物质编号24900873
Flavis编号9.014
NACRESNA.21

产品性质

质量水平400
等级FG
Halal
Kosher
natural
agencymeets purity specifications of JECFA
reg. complianceEU Regulation 1334/2008 & 178/2002
FCC
FDA 21 CFR 117
蒸汽压23 mmHg ( 110 ℃)
测定≥99%
自燃温度862 °F
折射率n20/D 1.502 (lit.)
bp206 ℃ (lit.)
mp−51 ℃ (lit.)
密度1.054 g/mL at 25 ℃ (lit.)
文件see Safety & Documentation for available documents
性状检查fruity; floral; sweet
application(s)flavors and fragrances
食品过敏原no known allergens
SMILES stringCC(=O)OCc1ccccc1
InChI1S/C9H10O2/c1-8(10)11-7-9-5-3-2-4-6-9/h2-6H,7H2,1H3
InChI keyQUKGYYKBILRGFE-UHFFFAOYSA-N

安全信息

危险声明H412
预防措施声明P273 - P501
危险分类Aquatic Chronic 3
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)203.0 °F - closed cup
闪点(C)95 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
8.03181Sigma-AldrichBenzyl Acetatefor synthesis252.6元/100 ML;   324.02元/1 L;   展开

产品说明

分析说明

Assay (GC, area%): ≥ 99.0 % (a/a)
Density (d 20 °C/ 4 °C): 1.055 - 1.056
Identity (IR): passes test

基本信息

经验(实验)分子式C9H10O2
分子量150.17
MDL编号MFCD00008712
EC索引号205-399-7

产品性质

质量水平200
蒸汽压1 hPa ( 45 ℃)
测定≥99.0% (GC)
自燃温度460 ℃
效能2490 mg/kg LD50, oral (Rat)
expl. lim.0.9-8.4 % (v/v)
bp205-207 ℃/1013 hPa
mp-51 ℃
转变温度flash point 95 ℃
密度1.06 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/C9H10O2/c1-8(10)11-7-9-5-3-2-4-6-9/h2-6H,7H2,1H3
InChI keyQUKGYYKBILRGFE-UHFFFAOYSA-N

安全信息

危险声明H412
预防措施声明P273 - P501
危险分类Aquatic Chronic 3
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)203.0 °F - closed cup
闪点(C)95 ℃ - closed cup
494124FluorochemBenzyl Acetate= 99% (GC)572元/500g;   1892元/2.5kg;   3190元/5kg;   展开

基本信息

CAS Number140-11-4
MDL NumberMFCD00008712
Boiling Point214℃
Melting Point-51℃
Density1.06

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H370: Causes damage to organs Respiratory system.
H372: Causes damage to organs Kidney.
H373: May cause damage to organs Mucous membranes.
H412: Harmful to aquatic life with long lasting effects.
H336: May cause drowsiness or dizziness
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P307: IF exposed: .
P307 + P311: IF exposed: Call a POISON CENTER or doctor/physician.
P311: Call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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