CAS 13939-06-5; 六羰基钼; Molybdenum carbonyl,(OC-6-11)-

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产品名称

规格

包装、参考价格

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M829667

MACKLIN

六羰基钼

98%

121元/1g; 477元/5g; 2355元/25g; 8408元/100g;

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储存：室温
状态：白色到灰白色粉末,晶体,结晶粉末

42-1350

Strem

Molybdenum carbonyl

98%

690元/5g; 1725元/25g; 5340元/100g; 24030元/500g;

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Technical Notes:

1.AL .D precursor used for Mo thin film deposition

References:

1.Chem. Vap. Deposition 2001 Z 33.

2.ACs App/. Mater. Interfaces 2019 11 173211

3.Chem. Mater. 2019. 31. 8338.

4.J. Mater. C hem.. 2011 21 705.

5.J. Electron. Mater.. 2018. 4Z. 6709.

6.Nanoscale.2014. 6. 14453.

7.L angmuir2015. 31.1196

8.App/. Surf. Sci.. 2016 365. 1 60.

9.Phys. Status Solidi RRL 2018 12 1 800023.

10. J. Vac. Sci. Technol. A. 2020. 38. 022409.

013057

Alfa Aesar

Hexacarbonylmolybdenum

98%

579元/2.5g; 2921元/25g; 11753元/100g;

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应用
Hexacarbonylmolybdenum is widely utilized in electron beam-induced deposition technique providing an appropriate source of molybdenum atoms. It finds an application as important reagent in organometallic synthesis because of replacement of carbonyl ligands by other donor ligands. Its derivative is act as a catalyst in organic synthesis, which is used in alkyne metathesis and the Pauson-Khand reaction.

备注
Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00003466

EINECS
237-713-3

分子式
C₆MoO₆

分子量
264.00

熔点
ca 150° dec.

密度
1.96

灵敏度
Ambient temperatures.

形态
Crystalline, may contain up to 1% Cr

溶解性
Slightly soluble in tetrahydrofuran, diglyme and acetonitrile.

GHS危害和防范说明

GHS符号

Hazard Statements
H300-H330
Fatal if swallowed.Fatal if inhaled.

Precautionary Statements
P280f-P304+P340-P310-P302+P352
Wear protective clothing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Immediately call a POISON CENTER or doctor/physician.IF ON SKIN: Wash with plenty of soap and water.

安全信息

危险等级
6.1

包装组
II

危险类别
26/28
Very toxic by inhalation and if swallowed.

安全等级
28-36-45
After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).Wear suitable protective clothing.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA
是

C19039

Alfa Aesar

Molybdenum hexacarbonyl

98%

2054元/10g; 5167元/50g; 29164元/250g;

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基本信息

Ref#
19039

MDL
3466

分子式
C6 O6 Mo

分子量
264

密度
1.96

安全信息

危险等级
6.1

包装组
II

577766

Sigma-Aldrich

Molybdenumhexacarbonyl

≥99.9% trace metals basis

1794.86元/5 G; 4328.88元/25 G;

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产品说明

一般描述

基材原子序数：42 钼

包装

5, 25 g in glass bottle

基本信息

线性分子式	Mo(CO)₆
分子量	264.00
EC 号	237-713-3
MDL编号	MFCD00003466
PubChem化学物质编号	24880893
NACRES	NA.23

产品性质

质量水平	100
蒸汽密度	9.1 (vs air)
测定	≥99.9% trace metals basis
形式	solid solid
纯化方式	sublimation
reaction suitability	core: molybdenum reagent type: catalyst
bp	156 ℃ (lit.)
mp	150 ℃ (dec.) (lit.)
密度	1.96 g/mL at 25 ℃ (lit.)
SMILES string	[Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI	1S/6CO.Mo/c6*1-2;
InChI key	KMKBZNSIJQWHJA-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H331
预防措施声明	P261 - P271 - P304 + P340 + P311 - P403 + P233 - P405 - P501
危险分类	Acute Tox. 3 Inhalation
储存分类代码	6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

8.00396

Sigma-Aldrich

Hexacarbonylmolybdenum

for synthesis

1220.03元/10 G; 2802.6元/25 G;

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产品说明

分析说明

Assay (Mo(CO)₆): ≥ 99.0 %
Assay (Cr(CO)₆): ≤ 1.0 %
Identity (IR): passes test

基本信息

线性分子式	Mo(CO)₆
分子量	264.00
MDL编号	MFCD00003466
EC索引号	237-713-3

产品性质

质量水平	200
蒸汽压	0.13 hPa ( 20 ℃)
形式	powder
mp	147-152 ℃ (decomposition)
密度	1.96 g/cm³ at 20 ℃
InChI	1S/6CO.Mo/c6*1-2;
InChI key	KMKBZNSIJQWHJA-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H331
预防措施声明	P261 - P271 - P304 + P340 + P311 - P403 + P233 - P405 - P501
危险分类	Acute Tox. 3 Inhalation
储存分类代码	6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

754943

Sigma-Aldrich

Molybdenumhexacarbonyl

packaged for use in deposition systems

5753.64元/25 G;

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基本信息

线性分子式	Mo(CO)₆
分子量	264.00
EC 号	237-713-3
MDL编号	MFCD00003466
PubChem化学物质编号	329766468
NACRES	NA.23

产品性质

蒸汽密度	9.1 (vs air)
测定	99.9% (trace metals analysis)
形式	solid
reaction suitability	core: molybdenum
bp	156 ℃ (lit.)
mp	150 ℃ (dec.) (lit.)
密度	1.96 g/mL at 25 ℃ (lit.)
SMILES string	[Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI	1S/6CO.Mo/c6*1-2;
InChI key	KMKBZNSIJQWHJA-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H331
预防措施声明	P261 - P271 - P304 + P340 + P311 - P403 + P233 - P405 - P501
危险分类	Acute Tox. 3 Inhalation
储存分类代码	6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

050113

Fluorochem

Molybdenum hexacarbonyl

97%

1232元/5g; 3630元/25g;

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基本信息

CAS Number	13939-06-5
MDL Number	MFCD00003466
Boiling Point	156℃
Melting Point	150℃
Density	1.96

安全信息

图形或危害标志
危险性说明	H300: Fatal if swallowed. H310: Fatal in contact with skin. H330: Fatal if inhaled.
防范说明	P260: Do not breathe . P262: Do not get in eyes, on skin, or on clothing. P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P284: Wear respiratory protection. . P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302 + P350: IF ON SKIN: Gently wash with plenty of soap and water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P310: Immediately call a POISON CENTER or doctor/physician. P320: Specific treatment is urgent (see . on this label). P321: Specific treatment (see . on this label). P322: Specific measures (see . on this label). P330: Rinse mouth. P361: Remove/Take off immediately all contaminated clothing. P363: Wash contaminated clothing before reuse. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.