| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | 详情 |
| N814659 | MACKLIN | 1-萘基硼酸 | 97% | 29元/1g; 33元/5g; 75元/25g; 300元/100g; 1299元/500g; | 展开 |
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| N0630 | TCI | 1-Naphthaleneboronic Acid (contains varying amounts of Anhydride) | | 215元/1G; 635元/5G; 2115元/25G; | 展开 |
基本信息 | 分子式/分子量 | C10H9BO2 = 171.99 | | 外观与形状(20℃) | 固体 | | Reaxys-RN | 2937504 | | PubChem物质ID | 87573946 | | MDL编号 | MFCD00019722 |
技术规格 | Appearance | White to Light yellow to Light red powder to crystal | | Purity(Neutralization titration) | 97.0 to 112.0 % |
物性(参考值) 安全信息 | 图形或危害标志 |  | | 信号词 | 警告 | | 危险性说明 | H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
| | 防范说明 | P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激：求医/就诊。
P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染：用水充分清洗。如感觉不适，呼叫急救中心/医生。
P304 + P340 + P312 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。
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| 260728 | J&K | 1-Naphthaleneboronic acid | 98% | 60元/1G; 111元/5G; 300元/25G; | 展开 |
基本信息 | 分子式 | C10H9BO2 | | 分子量 | 171.99 | | 熔点 | 208-214 | | MDL编码 | MFCD00019722 | | Beilstein | 2937504 |
安全信息 | 图形或危害标志 | | | 提示语 | Warning | | 危险说明 | H315
H319
H335 | | 防范说明 | P261
P305+P351+P338 | | WGK | 3 | | TSCA | 否 |
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| 05-1030 | Strem | 1-Naphthylboronic acid | min. 97% | 543元/1g; 2086元/5g; | 展开 |
Technical Notes: 1. Reagent used for the palladium-catalyzed aryl borylation of aryl halides. 2.Reagent used for the copper-catalyzed ß-boration of a,ß-unsaturated carbonyl compounds. 3. Reagent used for the nickel-catayzed (het)aryl borylation of aryl halides. 4. Reagent used for the palladium-catalyzed borylation of allylic alcohols References: 1. J. Am. Chem. Soc. 2012, 134, 11667. 2. Org. L ett.2011, 13, 4684. 3.J. Org. Chem. 2013, 78, 6427. 4.Angew. Chem., Int. Ed. 2012, 51, 13050. |
| B21219 | Alfa Aesar | 1-Naphthaleneboronic acid | 97% | 621元/1g; 1365元/5g; 5028元/25g; | 展开 |
应用
1-Naphthaleneboronic acid is a very useful building block for introduction of a naphthyl group through cross-coupling protocols. It is useful in the synthesis of polyaromatic hydrocarbons utilizing the Suzuki reaction. 备注
Incompatible with oxidizing agents. Store in a cool, dry condition in a well sealed container. Store at room temperature. 基本信息 MDL
MFCD00019722 分子式
C10H9BO2 分子量
171.99 熔点
204-210° 灵敏度
Ambient temperatures. 形态
Crystalline powder 溶解性
Soluble in methanol. Insoluble in water. Beilstein
2937504 GHS危害和防范说明 GHS符号
Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险类别
36/37/38
Irritating to eyes, respiratory system and skin. 安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste TSCA
否 |
| C34469 | Alfa Aesar | 1-Naphthaleneboronic acid | 97% | 545元/1g; 1235元/5g; 4181元/25g; | 展开 |
基本信息 Ref#
34469 MDL
19722 分子式
C10 H9 B O2 分子量
171.99 |
| N257 | Sigma-Aldrich | Naphthalene-1-boronic acid | ≥95.0% | 365.1元/5 G; 502.08元/25 G; | 展开 |
产品说明 应用 1-萘硼酸可用于： - 5-溴-2-(萘-1-基)苯甲酸甲酯，其是制备9-蒽-螺苯并芴主体材料的原料。
- 用于水解纤维素的双功能聚合物。
- 9-(萘-1-基)蒽 ，其是制备发射蓝光的蒽衍生分子玻璃的关键中间体。
它也可用作基于Suzuki 均偶联反应的荧光检测硼酸基糖类传感器的底物。 包装 5, 25 g in glass bottle 其他说明 含不定量的酸酐 基本信息 | 线性分子式 | C10H7B(OH)2 | | 分子量 | 171.99 | | Beilstein | 2937504 | | MDL编号 | MFCD00019722 | | PubChem化学物质编号 | 24897577 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 测定 | ≥95.0% | | 形式 | crystals | | mp | 208-214 ℃ (lit.) | | SMILES string | OB(O)c1cccc2ccccc12 | | InChI | 1S/C10H9BO2/c12-11(13)10-7-3-5-8-4-1-2-6-9(8)10/h1-7,12-13H | | InChI key | HUMMCEUVDBVXTQ-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H302 | | 预防措施声明 | P264 - P270 - P301 + P312 - P501 | | 危险分类 | Acute Tox. 4 Oral | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
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| 011006 | Fluorochem | 1-Naphthaleneboronic acid | 98% | 220元/5g; 550元/25g; 1320元/100g; | 展开 |
基本信息 | CAS Number | 13922-41-3 | | MDL Number | MFCD00019722 | | Boiling Point | 381.9 ℃ at 760 mmHg | | Melting Point | 208-214℃ |
安全信息 | 图形或危害标志 | | | 危险性说明 | H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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