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CAS: 138526-69-9
分子式: C6H2BrF3
分子量: 210.98
沸点: 47-49 °C60 mm Hg(lit.)
中文名称: 
5-溴-1,2,3-三氟苯
3,4,5-三氟溴苯
英文名称: 
5-Bromo-1,2,3-trifluorobenzene
1-Bromo-3,4,5-trifluorobenzene
性质描述: 无色透明液体。
用途: 医药中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格
B803532MACKLIN5-溴-1,2,3-三氟苯99%28元/1g;   30元/5g;   39元/25g;   140元/100g;   698元/500g;   2600元/2.5kg;   咨询
储存:室温,易燃物区域
状态:无色液体
折射率:n20/D 1.482(lit.)
B1765TCI1-Bromo-3,4,5-trifluorobenzene>98.0%(GC)80元/5G;   290元/25G;   咨询

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C6H2BrF3 = 210.98
外观与形状(20℃)液体
Reaxys-RN7249191
PubChem物质ID87564660
SDBS (AIST Spectral DB)19682
MDL编号MFCD00070738

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 98.0 %

物性(参考值)

沸点43 ℃/15 mmHg
闪点45 ℃
比重1.78
折射率1.48

安全信息

图形或危害标志
信号词危险
危险性说明H315 : 造成皮肤刺激。
H318 : 造成严重眼损伤。
H351 : 怀疑致癌。
H411 : 对水生生物有毒并具有长期持续影响。
H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P201 : 使用前取得专用说明。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P391 : 收集溢出物。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
P405 : 存放处须加锁。

运输信息

UN编号UN1993
类别3
包装类别 III
监管条件代码(*)
540946J&K1-Bromo-3,4,5-trifluorobenzene99%114元/25G;   382元/100G;   咨询

基本信息

分子式C6H2BrF3
分子量210.98
熔点-20
沸点47-49
闪点45
密度1.767
折光率(n20D)1.4810 - 1.4830
MDL编码MFCD00070738
Beilstein7249191
EINECS 编号418-480-9

安全信息

图形或危害标志
提示语Danger
危险说明H226
H315
H318
H351
H411
防范说明P273
P280
P305+P351+P338
UN号码1993
危险分类3
包装等级III
WGK2
TSCA否
B20607Alfa Aesar5-Bromo-1,2,3-trifluorobenzene98%752元/1g;   2578元/5g;   咨询

基本信息

MDL
MFCD00070738

EINECS
418-480-9

分子式
C6H2BrF3

分子量
210.98

熔点
<-20°

沸点
140°

闪点
45°(113°F)

密度
1.767

折射率
1.4820

形态
Liquid

Beilstein
7249191

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H315-H318-H351-H411
Flammable liquid and vapour.Causes skin irritation.Causes serious eye damage.Suspected of causing cancer.Toxic to aquatic life with long lasting effects.

Precautionary Statements
P210-P201-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Obtain special instructions before use.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
10-38-40-41-51/53
Flammable.Irritating to skin.Limited evidence of a carcinogenic effect.Risk of serious damage to eyes.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
23-26-36/37/39-61
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.Avoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

TSCA
否

330841Sigma-Aldrich5-Bromo-1,2,3-trifluorobenzene99%241.58元/5 G;   咨询

产品说明

应用

5-Bromo-1,2,3-trifluorobenzene was used in flow preparation of 4,4,5,5-tetramethyl-2-(3,4,5-trifluorophenyl)-1,3,2-dioxaborolane.

包装

5 g in ampule

基本信息

线性分子式BrC6H2F3
分子量210.98
EC 号418-480-9
MDL编号MFCD00070738
PubChem化学物质编号24859920
NACRESNA.22

产品性质

质量水平200
测定99%
折射率n20/D 1.482 (lit.)
bp47-49 ℃/60 mmHg (lit.)
密度1.767 g/mL at 25 ℃ (lit.)
SMILES stringFc1cc(Br)cc(F)c1F
InChI1S/C6H2BrF3/c7-3-1-4(8)6(10)5(9)2-3/h1-2H
InChI keyHKJCELUUIFFSIN-UHFFFAOYSA-N

安全信息

象形图GHS02GHS05GHS08GHS09
警示用语:Danger
危险声明H226 - H315 - H318 - H351 - H411
预防措施声明P210 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313
危险分类Aquatic Chronic 2 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2
储存分类代码3 - Flammable liquids
WGKWGK 2
闪点(F)113.0 °F - closed cup
闪点(C)45 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
001801Fluorochem1-Bromo-3,4,5-trifluorobenzene99%264元/5g;   330元/25g;   836元/100g;   咨询

基本信息

CAS Number138526-69-9
MDL NumberMFCD00070738
Boiling Point142.48℃
Density1.782

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H315: Causes skin irritation.
H318: Causes serious eye damage.
H335: May cause respiratory irritation.
H351: Suspected of causing cancer ..
H411: Toxic to aquatic life with long lasting effects.
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P281: Use personal protective equipment as required.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P391: Collect spillage.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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