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CAS: 13826-86-3
分子式: BF4NO2
分子量: 132.81
中文名称: 
四氟硼酸硝
英文名称: 
nitronium, tetrafluoroborate(1-)
tetrafluoro-borate(1- nitryl
nitryl fluoborate
nitryl tetrafluoroborate
nitronium tetrafluoroborate
推荐供应商
货号品牌产品名称规格包装、参考价格详情
N798995MACKLIN硝酸四氟硼酸90%650元/5g;   展开
储存:-20°C
状态:白色晶体或块状物
N836143MACKLIN硝酸四氟硼酸96%38元/100mg;   175元/1g;   722元/5g;   展开
储存:2~8 °C,密封,干燥
状态:白色晶体或结晶粉末
423660J&KNitronium tetrafluoroborate96%480元/5G;   1330元/25G;   4818元/100G;   展开

基本信息

分子式BF4NO2
分子量132.81
熔点200
MDL编码MFCD00011432
EINECS 编号237-533-5
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H314
H317
H334
防范说明P260
P272
P280
P303+P361+P353
P304+P340+P310
P305+P351+P338
UN号码3260
危险分类8
包装等级II
WGK3
RTECSQX8620000
93-0740StremNitronium tetrafluoroboratemin. 97%1612元/5g;   3212元/25g;   展开
H34069Alfa AesarNitronium tetrafluoroborate0.3 to 0.5M soln. in sulfolane2373元/25ml;   6228元/200ml;   展开

基本信息

MDL
MFCD00011432

EINECS
237-533-5

分子式
BF4NO2

分子量
132.81

密度
1.268

形态
Liquid

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H314-H318-H334
May be harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Precautionary Statements
P260h-P284-P303+P361+P353-P305+P351+P338-P405-P501a
Wear respiratory protection.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
22-36/38-42
Harmful if swallowed.Irritating to eyes and skin.May cause sensitization by inhalation.

安全等级
20-22-25-26-36/37/39-45-60
When using do not eat or drink.Do not breathe dust.Avoid contact with eyes.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

036374Alfa AesarNitronium tetrafluoroborate90%803元/5g;   3050元/25g;   展开

应用
Ingold's method of competitive nitration has been used in order to determine relative reactivities of alkylbenzenes and benzene in homogeneous mononitrations with nitronium tetrafluoroborate in tetramethylene sulfone solutions. Oxidation of both exo-and endo-2-bromonorbornane with nitronium tetrafluoroborate in acetonitrile afforded N-exo-2-norbornylacetamide. Used in the synthesis and characterization of new polyhydroxyorganocarboxylated fullerene derivatives through the electrophilic addition of nitronium tetrafluoroborate onto fullerenes in the presence of arenecarboxylic acid in a nonaqueous medium.

备注
Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture, bases, heat. Store under dry inert gas.

基本信息

MDL
MFCD00011432

EINECS
237-533-5

分子式
BF4NO2

分子量
132.81

熔点
240° dec.

灵敏度
Keep Cold. Moisture Sensitive. Store under Nitrogen.

形态
Crystalline

溶解性
Decomposes in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
QX8620000

TSCA

B20167Alfa AesarNitronium tetrafluoroborate96%755元/5g;   2465元/25g;   7774元/100g;   展开

应用
Nitronium tetrafluoroborate has been shown to be a versatile nitrating agent for nitrogen compounds, giving the corresponding N-nitro derivative when reacted with secondary aliphatic amines, an acyl aliphatic amine, a carbamate ester: a diacyl amine and primary amides.

备注
Moisture sensitive. Store away from oxidizing agents, bases, water/moisture and heat. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas. Keep it refrigerated.

基本信息

MDL
MFCD00011432

EINECS
237-533-5

分子式
BF4NO2

分子量
132.81

熔点
ca 240° dec.

灵敏度
Keep Cold. Moisture Sensitive. Store under Nitrogen.

形态
Crystals

溶解性
Decomposes in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
QX8620000

TSCA

C17438Alfa AesarNitronium tetrafluoroborate97%947元/5g;   2116元/25g;   10031元/100g;   展开

基本信息

Ref#
17438

MDL
11432

分子式
B F4 N O2

分子量
132.81

安全信息

危险等级
8

包装组
II

C42907Alfa AesarNitronium tetrafluoroborate0.5M solution in sulfolane, AcroSeal™8676元/100ml;   展开

基本信息

Ref#
42907

安全信息

危险等级
8

包装组
III

176303Sigma-AldrichNitronium tetrafluoroborate solution0.5 M in sulfolane3054.2元/200 ML;   展开

产品说明

应用

Reactant for preparation of:

  • Anologues of SCH 39166 as potent and selective dopamine D1 receptor antagonists
  • Anticonvulsant agent SB-406725A
  • Nitro-derivatives of chlorambucil conjugated to prasterone and pregnenolone as anticancer agents
  • Nano-sized cryptomelane particles for the formation of potentiometric potassium ion sensors
  • Nitro- and aminoindole derivatives
  • Hydroxynitroalkyl esters as affectors of metabolism of sulfate-reducing bacteria
  • Fluorescence probes to monitor the generation of nitrative stress in neurodegenerative disorders

Used as:
  • Oxidizing agent in high-power Li-ion battery technology for large-scale applications as required for plug-in hybrid vehicles

包装

200 mL in poly bottle

基本信息

线性分子式NO2BF4
分子量132.81
MDL编号MFCD00011432
PubChem化学物质编号24850570
NACRESNA.22

产品性质

质量水平100
浓度0.5 M in sulfolane
密度1.268 g/mL at 25 ℃
储存温度2-8℃
SMILES stringO=[N+]=O.F[B-](F)(F)F
InChI1S/BF4.NO2/c2-1(3,4)5;2-1-3/q-1;+1
InChI keyRGVZMPONLYFINH-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07GHS08
警示用语:Danger
危险声明H302 - H314 - H317 - H334 - H360FD
预防措施声明P202 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 1B - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
366153Sigma-AldrichNitronium tetrafluoroborate≥95%1088.79元/5 G;   1975.07元/25 G;   展开

产品说明

应用

反应物用于制备:

  • SCH 39166 作为强效和选择性多巴胺 D1 受体拮抗剂的分析
  • 抗惊厥药 SB-406725A
  • 苯丁酸氮芥的硝基衍生物与普拉睾酮和孕烯醇酮偶联作为抗癌剂
  • 纳米级钾锰矿颗粒用于形成电位钾离子传感器
  • 硝基和氨基吲哚衍生物
  • 羟基硝基烷基酯对硫酸盐还原菌代谢的影响
  • 荧光探针监测神经退行性疾病中硝化应激的产生

用作:
  • 插电式混合动力汽车用大功率锂离子电池技术中的氧化剂

硝基四氟硼酸盐 (NO2BF4) 可用作反应物,用于制备:
  • SCH 39166 类似物作为强效和选择性多巴胺 D1 受体拮抗剂。
  • 抗惊厥剂 SB-406725A。
  • 苯丁酸氮芥的硝基衍生物与普拉睾酮和孕烯醇酮结合作为抗癌药物。
  • 纳米锰钾矿颗粒用于电位型钾离子传感器的形成。
  • 硝基和氨基吲哚衍生物。
  • 羟基硝基烷基酯,作为硫酸盐还原菌代谢的影响因子。
  • 荧光探针,监测神经退行性疾病中硝化应激的产生。

NO 2 BF 4 还可作为氧化剂用于大功率锂离子电池技术,用于插电式混合动力车的大规模应用。

包装

5 g in PFA/FEP bottle
25 g in poly bottle

基本信息

线性分子式NO2BF4
分子量132.81
EC 号237-533-5
MDL编号MFCD00011432
PubChem化学物质编号24862622
NACRESNA.22

产品性质

质量水平200
测定≥95%
储存温度2-8℃
SMILES stringO=[N+]=O.F[B-](F)(F)F
InChI1S/BF4.NO2/c2-1(3,4)5;2-1-3/q-1;+1
InChI keyRGVZMPONLYFINH-UHFFFAOYSA-N

安全信息

象形图GHS05GHS08
警示用语:Danger
危险声明H314 - H317 - H334
预防措施声明P260 - P272 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
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