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CAS: 137348-86-8
分子式: C14H32NO2P
分子量: 277.39
沸点: 85℃(0.2
英文名称: 
Di-tert-butyl N,N-diisopropylphosphoramidite
di-tert-butyl n,n-diisopropylphosphor-amidite
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货号品牌产品名称规格包装、参考价格详情
D835341MACKLINN,N-二异丙基亚磷酰胺二叔丁酯98%36元/1g;   146元/5g;   550元/25g;   展开
储存:2~8°C,密封
状态:无色液体
D4211TCIDi-tert-butyl N,N-Diisopropylphosphoramidite>95.0%(GC)305元/1G;   1045元/5G;   展开

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C14H32NO2P = 277.39
外观与形状(20℃)液体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况空气,湿气 (分解),加热
Reaxys-RN4858847
PubChem物质ID160871438
MDL编号MFCD00153506

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 95.0 %
Purity(with Total Nitrogen)min. 98.0 %

物性(参考值)

沸点77 ℃/2.5 mmHg
比重0.89
折射率1.44

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
462652J&KDi-tert-butyl N,N-Diisopropylphosphoramidite95%276元/1G;   945元/5G;   展开

基本信息

分子式C14H32NO2P
分子量277.39
沸点85-90
闪点113
密度0.879
折光率(n20D)1.4370 - 1.4410
MDL编码MFCD00153506
Beilstein4858847
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
C42689Alfa AesarDi-tert-butyl N,N-Diisopropylphosphoramidite95%815元/1g;   2417元/5g;   展开

基本信息

Ref#
42689

MDL
153506

分子式
C14 H32 N O2 P

分子量
277.39

闪点
113

密度
0.879

419362Sigma-AldrichDi-tert-butyl N,N-diisopropylphosphoramidite95%446.08元/1 G;   1166.52元/5 G;   展开

产品说明

应用

Di-tert-butyl N,N-diisopropylphosphoramidite is a general reagent to introduce tert-butyl-protected phosphate groups. It is commonly used in phosphorylation of biomolecules. It can also be used in the synthesis of phosphoramidate-linked glycoconjugates.

包装

1, 5 g in glass bottle

基本信息

线性分子式[(CH3)2CH]2NP[OC(CH3)3]2
分子量277.38
Beilstein4858847
MDL编号MFCD00153506
PubChem化学物质编号24866105
NACRESNA.22

产品性质

质量水平200
测定95%
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
折射率n20/D 1.444 (lit.)
bp85-90 ℃/0.2 mmHg (lit.)
密度0.879 g/mL at 25 ℃ (lit.)
官能团phosphine
储存温度2-8℃
SMILES stringCC(C)N(C(C)C)P(OC(C)(C)C)OC(C)(C)C
InChI1S/C14H32NO2P/c1-11(2)15(12(3)4)18(16-13(5,6)7)17-14(8,9)10/h11-12H,1-10H3
InChI keyYGFLCNPXEPDANQ-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)235.4 °F - closed cup
闪点(C)113 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
226515FluorochemDi-tert-butyl diisopropylphosphoramidite95%396元/1g;   1320元/5g;   6160元/25g;   展开

基本信息

CAS Number137348-86-8
MDL NumberMFCD00153506
Boiling Point77℃
Density0.89

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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