CAS 13716-10-4; 二叔丁基氯化膦; di-tert-butylchlorophosphine

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货号

品牌

产品名称

规格

包装、参考价格

D806479

MACKLIN

二叔丁基氯化膦

96%

30元/1g; 99元/5g; 450元/25g; 1699元/100g; 7700元/500g;

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储存：室温, 干燥, 惰性气体
状态：无色或黄色液体
折射率：n20/D 1.482(lit.)

D3632

TCI

Di-tert-butylchlorophosphine

>95.0%(GC)

785元/5G; 2650元/25G;

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基本信息

纯度/分析方法	>95.0%(GC)
分子式/分子量	C₈H₁₈ClP = 180.66
外观与形状(20℃)	液体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气,湿气 (分解)
Reaxys-RN	1847423
PubChem物质ID	87560114
MDL编号	MFCD00008815

技术规格

Appearance	Colorless to Almost colorless clear liquid
Purity(GC)	min. 95.0 %
Purity(Argentometric Titration)	min. 94.0 %

物性(参考值)

熔点	3 ℃
沸点	72 ℃/13 mmHg
闪点	62 ℃
比重	0.95
折射率	1.48

安全信息

图形或危害标志
信号词	危险
危险性说明	H314 : 造成严重皮肤灼伤和眼损伤。 H227 : 可燃液体。 H290 : 可能腐蚀金属。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P234 : 只能在原容器中存放。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P390 : 吸收溢出物，防止材料损坏。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。 P363 : 沾染的衣服清洗后方可重新使用。 P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。 P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。 P403 + P235 : 存放在通风良好的地方。保持低温。 P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。 P405 : 存放处须加锁。

运输信息

UN编号	UN3265
类别	8
包装类别	II
监管条件代码(*)

15-1000

Strem

Di-t-butylchlorophosphine

min. 98%

405元/1g; 1635元/5g; 2955元/25g;

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B20998

Alfa Aesar

Di-tert-butylchlorophosphine

96%

411元/1g; 1394元/5g; 4440元/25g;

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应用
Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

备注
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.

基本信息

MDL
MFCD00008815

分子式
C₈H₁₈ClP

分子量
180.66

沸点
47-49°/3mm

闪点
62°(144°F)

密度
0.951

折射率
1.4840

灵敏度
Moisture Sensitive. Air Sensitive. Store under Argon. Ambient temperatures.

形态
Liquid

溶解性
Miscible with terahydrofuran.

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H314-H318
Combustible liquid.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P280-P305+P351+P338-P309-P310
Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
20-23-26-36/37/39-45-60
When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
否

C32090

Alfa Aesar

Di-tert-butylchlorophosphine

96%

1667元/5ml; 4724元/25ml; 14990元/100ml;

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基本信息

Ref#
32090

MDL
8815

分子式
C8 H18 Cl P

分子量
180.66

闪点
61

密度
0.95

安全信息

危险等级
8

包装组
II

301558

Sigma-Aldrich

Di-tert-butylchlorophosphine

96%

845.58元/5 G; 3147.76元/25 G; 6361.67元/100 G;

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产品说明

包装

25, 100 g in Sure/Seal™
5 g in glass bottle

应用

与 Pd(OAc)₂ 配合使用的大体积配体，用于芳基硼酸和溴代芳烃及氯代芳烃之间的高效 Suzuki-Miyaura 交叉偶联反应。

基本信息

线性分子式	[(CH₃)₃C]₂PCl
分子量	180.66
MDL编号	MFCD00008815
PubChem化学物质编号	24858196

产品性质

质量水平	100
测定	96%
reaction suitability	reagent type: ligand reaction type: Suzuki-Miyaura Coupling
折射率	n20/D 1.482 (lit.)
bp	48 ℃/3 mmHg (lit.)
密度	0.951 g/mL at 25 ℃ (lit.)
官能团	phosphine
SMILES string	CC(C)(C)P(Cl)C(C)(C)C
InChI	1S/C8H18ClP/c1-7(2,3)10(9)8(4,5)6/h1-6H3
InChI key	MCRSZLVSRGTMIH-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314
预防措施声明	P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
危险分类	Skin Corr. 1B
储存分类代码	8A - Combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	143.6 °F - closed cup
闪点(C)	62 ℃ - closed cup
个人防护装备	Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

050914

Fluorochem

Di-tert-butylchlorophosphine

95%

220元/1g; 924元/5g; 3938元/25g;

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基本信息

CAS Number	13716-10-4
MDL Number	MFCD00008815
Boiling Point	48℃
Density	0.95

安全信息

图形或危害标志
危险性说明	H314: Causes severe skin burns and eye damage. H318: Causes serious eye damage.
防范说明	P260: Do not breathe . P264: Wash hands thoroughly after handling. P280: Wear . P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P321: Specific treatment (see . on this label). P363: Wash contaminated clothing before reuse. P405: Store locked up. P501: Dispose of contents/container to local regulations.