CAS 13685-30-8; 氯二(4-甲氧苯基)膦; chlorobis(4-methoxyphenyl)phosphine

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货号

品牌

产品名称

规格

包装、参考价格

B849325

MACKLIN

双(4-甲氧基苯基)氯化膦

98%

586元/250mg; 1960元/1g;

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储存：2-8°C, 密封, 干燥
状态：白色粉末或晶体

H25887

Alfa Aesar

Chlorobis(4-methoxyphenyl)phosphine

96%

2046元/1g; 5932元/5g;

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应用
Chlorobis(4-methoxyphenyl)phosphine is used an pharmaceutical intermediate.

备注
Air & moisture sensitive. Store away from oxidizing agents, bases, air, water/ moisture.

基本信息

MDL
MFCD04972301

分子式
C₁₄H₁₄ClO₂P

分子量
280.69

熔点
61-64°

沸点
140°/1.5mm

灵敏度
Moisture Sensitive. Air Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Powder

溶解性
Reacts with water.

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P280-P303+P361+P353-P305+P351+P338-P310a
Wear protective gloves/protective clothing/eye protection/face protection.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA
否

710377

Sigma-Aldrich

Bis(4-methoxyphenyl)chlorophosphine

85%

1275.83元/2 G;

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产品说明

应用

Reactant for asymmetric:

Allylic substitution
Intermolecular Pauson-Khand reaction of symmetrically substituted alkynes
Hydrogenation
Intramolecular α-arylation of aldehydes

Reactant for:

Alcoholysis of phosphane-boranes
Probing hemilabile sites of Bis(phosphine) monoxide ligands

包装

2 g in glass bottle

基本信息

经验(实验)分子式	C₁₄H₁₄ClO₂P
分子量	280.69
MDL编号	MFCD04972301
PubChem化学物质编号	329762919
NACRES	NA.22

产品性质

质量水平	100
测定	85%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand
mp	62-66 ℃
官能团	phosphine
SMILES string	COc1ccc(cc1)P(Cl)c2ccc(OC)cc2
InChI	1S/C14H14ClO2P/c1-16-11-3-7-13(8-4-11)18(15)14-9-5-12(17-2)6-10-14/h3-10H,1-2H3
InChI key	YTFQUBRFOJIJOZ-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314
预防措施声明	P280 - P305 + P351 + P338 - P310
危险分类	Skin Corr. 1B
储存分类代码	8B - Non-combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

698474

Sigma-Aldrich

Bis(4-methoxyphenyl)chlorophosphine

95%

522.86元/250 MG;

咨询

产品说明

应用

Reactant for asymmetric:

Allylic substitution
Intermolecular Pauson-Khand reaction of symmetrically substituted alkynes
Hydrogenation
Intramolecular α-arylation of aldehydes

Reactant for:

Alcoholysis of phosphane-boranes
Probing hemilabile sites of Bis(phosphine) monoxide ligands

包装

250 mg in glass bottle

基本信息

经验(实验)分子式	C₁₄H₁₄ClO₂P
分子量	280.69
MDL编号	MFCD04972301
PubChem化学物质编号	329761258
NACRES	NA.22

产品性质

质量水平	100
测定	95%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand
mp	62-66 ℃
官能团	phosphine
SMILES string	COc1ccc(cc1)P(Cl)c2ccc(OC)cc2
InChI	1S/C14H14ClO2P/c1-16-11-3-7-13(8-4-11)18(15)14-9-5-12(17-2)6-10-14/h3-10H,1-2H3
InChI key	YTFQUBRFOJIJOZ-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H314
预防措施声明	P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
危险分类	Skin Corr. 1B
储存分类代码	8A - Combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges