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CAS: 13679-74-8
分子式: C7H8OS
分子量: 140.20
沸点: 65℃(1 to
熔点: 24-671℃
中文名称: 
2-乙酰基-5-甲基硫代苯
英文名称: 
1-(5-Methyl-thiophen-2-yl)-ethanone
1-(5-methyl-2-thienyl)ethan-1-one
Ethanone,1-(5-methyl-2-thienyl)-
ketone, methyl 5-methyl-2-thienyl
1-(5-methyl-2-thienyl)-ethanon
methylthienylcetone
2-acetyl-5-methylthiophene
推荐供应商
货号品牌产品名称规格包装、参考价格详情
A801127MACKLIN2-乙酰-5-甲基噻吩98%42元/5g;   169元/25g;   552元/100g;   展开
储存:室温
状态:无色到黄色和白色到浅黄色到橙色-黄色固体或半固态或液体
折射率:n20/D 1.561(lit.)
A1181TCI2-Acetyl-5-methylthiophene>96.0%(GC)460元/5G;   展开

基本信息

纯度/分析方法>96.0%(GC)
分子式/分子量C7H8OS = 140.20
外观与形状(20℃)固体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN110854
PubChem物质ID87562659
SDBS (AIST Spectral DB)11731
MDL编号MFCD00014529

技术规格

AppearanceWhite to Light yellow powder to lump
Purity(GC)min. 96.0 %

物性(参考值)

熔点24 ℃
闪点96 ℃
折射率1.56

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。

相关法规

RTECS#OB4972000
288706J&K2-Acetyl-5-methylthiophene96%297元/5G;   877元/25G;   展开

基本信息

分子式C7H8OS
分子量140.20
熔点24-28
沸点65-67
密度1.119
折光率(n20D)1.5590-1.5630
MDL编码MFCD00014529
Beilstein110854
EINECS 编号237-181-2

安全信息

图形或危害标志
提示语Warning
危险说明H302
H332
H312
防范说明P280
P302+P352
P301+P312
P304+P340
UN号码3335
危险分类9
包装等级III
RTECSOB4972000
A11282Alfa Aesar2-Acetyl-5-methylthiophene98%1651元/5g;   6368元/25g;   20440元/100g;   展开

基本信息

MDL
MFCD00014529

EINECS
237-181-2

分子式
C7H8OS

分子量
140.20

熔点
24-28°

沸点
65-67°/1mm

密度
1.119

折射率
1.5625

形态
Low melting solid

Beilstein
110854

GHS危害和防范说明

GHS符号

Hazard Statements
H302
Harmful if swallowed.

Precautionary Statements
P264-P270-P301+P312a-P330-P501a
Wash thoroughly after handling.Do not eat, drink or smoke when using this product.Do not eat, drink or smoke when using this product.Rinse mouth.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
9

包装组
III

危险类别
22
Harmful if swallowed.

安全等级
23-36-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).Wear suitable protective clothing.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
OB4972000

TSCA

S552038METHYL 5-METHYL-2-THIENYL KETONEAldrichCPR1908.94元/250MG;   展开

产品说明

其他说明

Please note that sigma-aldrich provides this product to early discovery researchers as part of a collection of rare and unique chemicals. sigma-aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH'S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT AS-IS AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

基本信息

线性分子式C7H8OS
分子量140.205
MDL编号MFCD00014529
533610Sigma-Aldrich2-Acetyl-5-methylthiophene98%3372.09元/25 G;   展开

产品说明

一般描述

2-Acetyl-5-methylthiophene is a volatile organic compound formed during the reaction between L-cysteine and dihydroxyacetone in glycerine or triglyceride solvent system. It can be prepared by reacting 2-methylthiophene with acetic anhydride. 2-Acetyl-5-methylthiophene undergoes palladium-catalyzed cross-coupling reaction with aryl bromides to form C-4 arylated product. It reacts with 1,2-bis(5-formyl-2-methylthiophen-3-yl)cyclopentene via Aldol condensation to form a chalcone with photochromic property. The standard molar enthalpies of combustion, formation and vaporization of 2-acetyl-5-methylthiophene are 4341.9 ± 1.8kJ/mol, 158.0 ± 2.1kJ/mol and 62.0 ± 2.6kJ/mol, respectively.

应用

2-Acetyl-5-methylthiophene may be used in the preparation of:

  • 2-ethyl-5-methylthiophene
  • (5-methylthiophen-2-yl)glyoxal
  • (2E)-1-(5-methylthiophen-2-yl)-3-(pyridin-3-yl)prop-2-en-1-one
  • ethyl 3-(5-methylthiophen-2-yl)-3-oxopropanoate

包装

25 g in glass bottle

基本信息

经验(实验)分子式C7H8OS
分子量140.20
EC 号237-181-2
MDL编号MFCD00014529
PubChem化学物质编号24877976
NACRESNA.22

产品性质

质量水平200
测定98%
折射率n20/D 1.561 (lit.)
bp65-67 ℃/1 mmHg (lit.)
mp24-28 ℃ (lit.)
密度1.106 g/mL at 25 ℃ (lit.)
SMILES stringCC(=O)c1ccc(C)s1
InChI1S/C7H8OS/c1-5-3-4-7(9-5)6(2)8/h3-4H,1-2H3
InChI keyYOSDTJYMDAEEAZ-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
001262Fluorochem2-Acetyl-5-methylthiophene95%220元/1g;   484元/5g;   792元/10g;   1584元/25g;   展开

基本信息

CAS Number13679-74-8
MDL NumberMFCD00014529
Boiling Point65-67℃/1mm
Density1.106

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H332: Harmful if inhaled.
防范说明 P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P501: Dispose of contents/container to local regulations.
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