储存：2-8℃
状态：无色到黄色液体

Technical Notes:

1. Highly enantio-, regio- and diastereo-selective one-pot 2 +3-cycloaddition reaction via isomerization of 3- butynoates to allenoates

2. Further insight in the minor/major concept using hydrogen pressure effect in asymmetric hydrogenation

3. Cobalt precursors for high-throughput discovery of base metal asymmetric alkene hydrogenation catalysts

References:

1.Chem. Sci., 2010, 1, 739.

2. J. Mol. Cata. A Chem.. 2012, 214, 363.

3. Science, 2013, 342, 1076.

产品说明

应用

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
(+)-1,2-Bis[(2R,5R)-2,5-diethylphospholano]ethane can be used as a reactant to prepare:

• Chromium diphosphine chloride complex which is employed as a catalyst for chemoselective oligomerization reaction.
• α-Arylpyrrolidines by Suzuki-Miyaura cross-coupling and enantioselective copper-catalyzed intramolecular hydroamination reactions.

It can also be used as a catalyst in the enantioselective preparation of (perfluoroalkyl)butenyldiketones via cross Rauhut-Currier reaction of β-perfluoroalkylenones and vinyl ketones.

包装

100 mg in clear glass bottle
500 mg in amber glass bottle

法律信息

与 Kanata Chemical Technologies Inc. 联合销售，仅供研究使用。这些化合物由 E.I. du Pont de Nemours and Company 授权制造和销售，此许可不包括利用这些化合物制备在制药领域销售的产品的权利。

基本信息

经验(实验)分子式	C18H36P2
分子量	314.43
MDL编号	MFCD01073768
PubChem化学物质编号	24884985
NACRES	NA.22

产品性质

质量水平	100
折射率	n20/D 1.5249
bp	104-106 ℃/0.05 mmHg
密度	0.939 g/mL at 25 ℃
SMILES string	CC[C@@H]1CC[C@@H](CC)P1CCP2[C@H](CC)CC[C@H]2CC
InChI	1S/C18H36P2/c1-5-15-9-10-16(6-2)19(15)13-14-20-17(7-3)11-12-18(20)8-4/h15-18H,5-14H2,1-4H3/t15-,16-,17-,18-/m1/s1
InChI key	QOLRLVPABLMMKI-BRSBDYLESA-N

安全信息

储存分类代码	12 - Non Combustible Liquids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable