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CAS: 1365531-89-0
分子式: C48H52O4P2
分子量: 754.8716  
中文名称: 
(R)-2,2'-双[双(3,5-二甲基苯基)膦基]-4,4',6,6'-四甲氧基联苯
英文名称: 
(R)-2,2'-bis[bis(3,5-dimethylphenyl)phosphino]-4,4',6,6'-tetramethoxybiphenyl
(R)-xylyl-garphos
(R)-(4,4',6,6'-tetramethoxybiphenyl-2,2'-diyl)bis[bis(3,5-dimethylphenyl)phosphine]
推荐供应商
货号品牌产品名称规格包装、参考价格详情
R950118MACKLIN(R)-2,2'-双[双(3,5-二甲基苯基)膦]-4,4',6,6'-四甲氧基--1,1'-联苯98%,99%ee536元/100mg;   展开
储存:室温
15-1661Strem(R)-2,2'-Bis[bis(3,5-dimethylphenyl)phosphino]-4,4',6,6'-tetramethoxy-)-1,1'-biphenylmin. 97%1020元/100mg;   4110元/500mg;   展开

Technical Note:

1.Chiral ligand used in the preparation of hydrogenation catalysts with exceptionally high activity and selectivity.

Reference:

1.US Patent Application No.61/381,493.

761389Sigma-Aldrich(R)-(4,4′,6,6′-Tetramethoxybiphenyl-2,2′-diyl)bis(bis(3,5-dimethylphenyl)phosphine)97%2983.71元/500 MG;   展开

产品说明

包装

100, 500 mg in glass bottle

法律信息

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.
Garphos is a trademark of Kanata Chemical Technologies, Inc.

基本信息

经验(实验)分子式C48H52O4P2
分子量754.87
MDL编号MFCD19443624
PubChem化学物质编号329766931
NACRESNA.22

产品性质

质量水平100
测定97%
旋光性[α]22/D +94.0°, c = 0.5% in dichloromethane
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp>300 ℃
官能团phosphine
InChI1S/C48H52O4P2/c1-29-13-30(2)18-39(17-29)53(40-19-31(3)14-32(4)20-40)45-27-37(49-9)25-43(51-11)47(45)48-44(52-12)26-38(50-10)28-46(48)54(41-21-33(5)15-34(6)22-41)42-23-35(7)16-36(8)24-42/h13-28H,1-12H3
InChI keyIDNKFBDRZBLTFQ-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
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