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CAS: 136-95-8
分子式: C7H6N2S
分子量: 150.20
熔点: 129-134℃
中文名称: 
2-氨基苯并噻唑
2-苯并噻唑胺
英文名称: 
2-amino-benzothiazole
Benzothiazol-2-ylamine
u-Aminoben-zothiazole
2-Aminobenzothiazole
2-Benzothiazolamine
2-amino-benzothiazol
2(3h)-benzothiazolimine
2-aminobenzthiazole
2-benzothiazolylamine
2-iminobenzothiazoline
usaf ek-3941
usaf xr-27
展开更多英文名
性质描述: 叶状体结晶。熔点132℃,易溶于乙醇、乙醚和氯仿,溶于浓盐酸,极难溶于水。蒸馏时不分解。
生产方法: 由苯基硫脲与氯化硫反应得到。先将无水氯仿吸入搪玻璃锅中,于搅拌下加入苯基硫脲,慢慢升温到60-63℃,蒸出含水氯仿,冷却至40℃加入氯化硫,气相温度不高于40℃,以免物料结块。加完后4h逐步升温至61℃,在61-64℃回流反应10h。然后将其排到盛有一定水量和活性炭的蒸馏锅中,用直接蒸汽蒸馏回收氯仿到液相温度为98℃,并维持15min。回收完毕,加水稀释,加冰冷却,加液碱中和至pH值为4.1,再加活性炭后搅拌。冷却、抽滤,滤液用30%液碱中和至pH值为7.0-7.6,然后冷却到35-40℃,压滤、烘干(温度不超过80℃)即得成品。熔点128-130℃,收率74.4%。
用途: 染料中间体。用于生产阳离子紫3RL,还用合成3-甲基苯并噻唑腙用于生产阳离子紫2RL等,也是其他有机合成的原料。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
A800876MACKLIN2-氨基苯并噻唑97%38元/25g;   109元/100g;   440元/500g;   1549元/2.5kg;   展开
储存:室温
状态:白色到黄色到米黄色到棕色粉末或晶体或片状
A0277TCI2-Aminobenzothiazole>97.0%(T)(HPLC)205元/25G;   380元/100G;   1190元/500G;   展开

基本信息

纯度/分析方法>97.0%(T)(HPLC)
分子式/分子量C7H6N2S = 150.20
外观与形状(20℃)固体
Reaxys-RN116315
PubChem物质ID87561932
SDBS (AIST Spectral DB)1467
Merck Index (14)424
MDL编号MFCD00005785

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(HPLC)min. 97.0 area%
Purity(Nonaqueous Titration)min. 97.0 %
Melting point126.0 to 131.0 ℃

物性(参考值)

熔点130 ℃
水溶性微溶
溶解性(可溶于)氯仿,醇,乙醚

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。

相关法规

RTECS#DL1050000
184983J&K2-Aminobenzothiazole99%620元/500G;   展开

基本信息

分子式C7H6N2S
分子量150.20
熔点126-129
MDL编码MFCD00005785
Beilstein116315
Merck14,424
EINECS 编号205-268-4

安全信息

图形或危害标志
提示语Warning
危险说明H302
H319
防范说明P305+P351+P338
UN号码2811
危险分类6.1
包装等级III
WGK2
RTECSDL1050000
TSCA
A13521Alfa Aesar2-Aminobenzothiazole98%864元/100g;   3982元/500g;   展开

应用
2-Aminobenzothiazole was used in the synthesis of cobalt(II) picrate mixed-ligand complexes. It was used to study adsorption of biologically significant 2-aminobenzothiazole molecules on colloidal silver particles using surface-enhanced raman scattering spectroscopy

备注
Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

基本信息

MDL
MFCD00005785

EINECS
205-268-4

分子式
C7H6N2S

分子量
150.20

熔点
126-129°

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in alcohol, chloroform, diethyl ether.

Beilstein
116315

Merck
14,424

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H319
Toxic if swallowed.Causes serious eye irritation.

Precautionary Statements
P280i-P301+P310a-P305+P351+P338-P321-P405-P501a
Wear eye/face protection.Wear eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Specific treatment (see label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36
Harmful if swallowed.Irritating to eyes.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

RTECS
DL1050000

TSCA

C14881Alfa Aesar2-Aminobenzothiazole97%399元/5g;   944元/100g;   3664元/500g;   展开

基本信息

Ref#
14881

MDL
5785

分子式
C7 H6 N2 S

分子量
150.2

形态
White to pale brown powder

108812Sigma-Aldrich2-Aminobenzothiazole97%274.66元/5 G;   629.72元/100 G;   展开

产品说明

一般描述

2-氨基苯并噻唑是一种中性载体(离子载体),用于构建用于测定 Ce 3 + 离子的聚氯乙烯膜电极。2-氨基苯并噻唑与多壁碳纳米管发生化学键合,生成一种吸附剂,用于从含水样品中分离 Pb (II)。

应用

2-氨基苯并噻唑被用于苦味酸钴混合配体配合物的合成 。利用表面增强拉曼散射光谱 研究了具有生物学意义的 2-氨基苯并噻唑分子在胶体银颗粒上的吸附。

包装

100 g in poly bottle
5 g in glass bottle

生化/生理作用

2-氨基苯并噻唑具有局部麻醉作用,在人类和兽医学中有多种用途。

基本信息

经验(实验)分子式C7H6N2S
分子量150.20
Beilstein116315
EC 号205-268-4
MDL编号MFCD00005785
eCl@ss39190704
PubChem化学物质编号24846830
NACRESNA.22

产品性质

质量水平100
测定97%
mp126-129 ℃ (lit.)
溶解性H2O: very slightly soluble
alcohol: freely soluble
chloroform: freely soluble
concentrated acid: soluble
diethyl ether: freely soluble
SMILES stringNc1nc2ccccc2s1
InChI1S/C7H6N2S/c8-7-9-5-3-1-2-4-6(5)10-7/h1-4H,(H2,8,9)
InChI keyUHGULLIUJBCTEF-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H319
预防措施声明P264 - P270 - P280 - P301 + P312 - P305 + P351 + P338 - P337 + P313
危险分类Acute Tox. 4 Oral - Eye Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
8.01268Sigma-Aldrich2-Aminobenzothiazolefor synthesis380.49元/50 G;   展开

产品说明

分析说明

Assay (HClO₄): ≥ 98.0 %
Melting range (lower value): ≥ 127 °C
Melting range (upper value): ≤ 130 °C
Identity (IR): passes test

基本信息

经验(实验)分子式C7H6N2S
分子量150.20
MDL编号MFCD00005785
EC索引号205-268-4

产品性质

质量水平200
mp127-130 ℃
储存温度2-30℃
InChI1S/C7H6N2S/c8-7-9-5-3-1-2-4-6(5)10-7/h1-4H,(H2,8,9)
InChI keyUHGULLIUJBCTEF-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H319
预防措施声明P264 - P270 - P280 - P301 + P312 - P305 + P351 + P338 - P337 + P313
危险分类Acute Tox. 4 Oral - Eye Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)Not applicable
闪点(C)Not applicable
078504Fluorochem2-Aminobenzothiazole95%220元/25g;   220元/1g;   594元/100g;   2508元/500g;   展开

基本信息

CAS Number136-95-8
MDL NumberMFCD00005785
Melting Point130℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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