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CAS: 136-85-6
分子式: C7H7N3
分子量: 133.15
沸点: 210-212 °C/12 mmHg(lit.)
熔点: 80-82 °C(lit.)
中文名称: 
5-甲基苯三唑
5-甲基-1H-苯并三唑
5-甲基苯并三氮唑
5-甲基苯并三唑
间甲苯基亚叠氮化氢
间亚叠氮基甲苯
英文名称: 
5-methyl-1H-Benzotriazole
5-methyl-1h-benzotriazol
5-methyl-1,2,3-benzotriazole
5-methylbenzotriazole
1H-Benzotriazole,5-methyl-
5-Methyl-1H-benzotriazole
m-Tolylazoimide
m-Aziminotoluene
性质描述: 黄色或浅黄色结晶体。熔点为80-82℃(83℃),沸点210-212℃(1.6kPa)。溶于醇、醚和氯仿。
生产方法: 与苯并三唑的制法相仿,可由甲苯二胺重氮化、环合而得。一种较老的方法是由间甲苯胺重氮盐与对甲苯磺酰胺反应得到。
用途: 该品作为铜和铜合金缓蚀剂,与苯并三唑(BTA)类似,实际商品还包括4-甲基苯并三唑([29878-31-7])或者为两者的混合物,简称TTA。苯并三氮唑类缓蚀剂能与亚铜离子形成不溶性的稳定络合物,吸附在金属表面上,形成一层稳定的和惰性的保护膜,厚度仅5×10-7cm,但在各种介质中很稳定,从而使铜合金得到了保护。BTA在pH值为5.5-10范围内的缓蚀作用都限好,但在低pH值介质中,TTA的缓蚀作用比BTA强。其他三氮唑化合物,例如三氮唑和萘并三氮唑等对铜及铜合金也有缓蚀作用,但不如BTA和TTA。甲基苯并三唑也用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M830854MACKLIN5-甲基苯并三氮唑98%68元/5g;   124元/25g;   378元/100g;   1406元/500g;   4803元/2.5kg;   展开
储存:2~8℃
状态:白色到浅黄色粉末或晶体
M0249TCI5-Methyl-1H-benzotriazole>99.0%(T)420元/25G;   2795元/500G;   展开

基本信息

纯度/分析方法>99.0%(T)
分子式/分子量C7H7N3 = 133.15
外观与形状(20℃)固体
储存温度0-10℃
应避免的情况加热
Reaxys-RN116658
PubChem物质ID87572334
SDBS (AIST Spectral DB)15522
MDL编号MFCD00005702

技术规格

AppearanceWhite to Light yellow to Dark green powder to crystal
Purity(Neutralization titration)min. 99.0 %
Melting point78.0 to 85.0 ℃

物性(参考值)

熔点83 ℃
沸点323 ℃
最大吸收波长276(H2O) nm
水溶性微溶
溶解性(可溶于)甲醇
溶解性(微溶于)甲苯

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。

相关法规

RTECS#DM1400000
103468J&K5-Methyl-1H-benzotriazole98%164元/10G;   446元/50G;   809元/100G;   2328元/500G;   展开

基本信息

分子式C7H7N3
分子量133.15
熔点80-82
沸点210-212
MDL编码MFCD00005702
Beilstein116658
EINECS 编号205-265-8

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
RTECSDM1400000
TSCA
07-1215Strem5-Methyl-1H-benzotriazole99%723元/25g;   2168元/100g;   9745元/500g;   展开
A10615Alfa Aesar5-Methyl-1H-benzotriazole98+%1219元/25g;   4111元/100g;   10219元/500g;   展开

应用
5-Methyl-1H-benzotriazole was used in determination of benzothiazoles and benzotriazoles in waste water samples by GC-MS. It is also used as a potential nitrification inhibitor of urea fertilizer in agricultural soils.

备注
Stable under recommended storage conditions. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00005702

EINECS
205-265-8

分子式
C7H7N3

分子量
133.15

熔点
77-84°

沸点
210-212°/12mm

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in chloroform, methanol, water (6.0 g/L at 25°C), ethanol, and toluene (slightly).

Beilstein
116658

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H335
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
DM1400000

TSCA

14949Supelco5-Methyl-1H-benzotriazoleanalytical standard971.64元/50 MG;   展开

产品说明

应用

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

包装

Bottomless glass bottle. Contents are inside inserted fused cone.

其他说明

Limited shelf life, expiry date on the label.

基本信息

经验(实验)分子式C7H7N3
分子量133.15
Beilstein116658
EC 号205-265-8
MDL编号MFCD00005702
PubChem化学物质编号329750664
NACRESNA.24

产品性质

质量水平100
等级analytical standard
测定≥98% (HPLC)
保质期limited shelf life, expiry date on the label
technique(s)HPLC: suitable
gas chromatography (GC): suitable
bp210-212 ℃/12 mmHg (lit.)
mp80-82 ℃ (lit.)
application(s)forensics and toxicology
pharmaceutical (small molecule)
格式neat
SMILES stringCc1ccc2[nH]nnc2c1
InChI1S/C7H7N3/c1-5-2-3-6-7(4-5)9-10-8-6/h2-4H,1H3,(H,8,9,10)
InChI keyLRUDIIUSNGCQKF-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319 - H335
预防措施声明P261 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
196304Sigma-Aldrich5-Methyl-1H-benzotriazole98%345.02元/10 G;   1037.36元/50 G;   展开

产品说明

一般描述

5-甲基-1H-苯并三唑是飞机除冰和防冰液的活性成分。它可以防止铜和黄铜在各种腐蚀环境中发生腐蚀。

应用

5-甲基-1H-苯并三唑用于 GC-MS 法测定废水样品中的苯并噻唑和苯并三唑。

包装

50 g in poly bottle
10 g in glass bottle

基本信息

经验(实验)分子式C7H7N3
分子量133.15
Beilstein116658
EC 号205-265-8
MDL编号MFCD00005702
PubChem化学物质编号24851750
NACRESNA.22

产品性质

质量水平200
测定98%
形式powder
bp210-212 ℃/12 mmHg (lit.)
mp80-82 ℃ (lit.)
SMILES stringCc1ccc2[nH]nnc2c1
InChI1S/C7H7N3/c1-5-2-3-6-7(4-5)9-10-8-6/h2-4H,1H3,(H,8,9,10)
InChI keyLRUDIIUSNGCQKF-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319 - H335
预防措施声明P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
005930FluorochemTolytriazole (mixture of isomers)98%220元/1g;   308元/25g;   814元/100g;   展开

基本信息

CAS Number136-85-6
MDL NumberMFCD00005702
Boiling Point210-212℃
Melting Point77-84℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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