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CAS: 133730-34-4
分子式: C8H11BO4
分子量: 181.98
熔点: 115-117℃
中文名称: 
2,4-二甲氧基苯硼酸
英文名称: 
2,4-Dimethoxyphenylboronic acid
2,4-dimethoxybenzeneboronic acid
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D807785MACKLIN2,4-二甲氧基苯硼酸96%27元/1g;   65元/5g;   323元/25g;   1290元/100g;   展开
储存:2~8°C
状态:白色到灰白色粉末
D708915MACKLIN2,4-二甲氧基苯硼酸98%40元/1g;   70元/5g;   325元/25g;   展开
储存:2~8°C
D3521TCI2,4-Dimethoxyphenylboronic Acid (contains varying amounts of Anhydride)90元/1G;   290元/5G;   展开

基本信息

分子式/分子量C8H11BO4 = 181.98
外观与形状(20℃)固体
Reaxys-RN4744213
PubChem物质ID87559362
MDL编号MFCD01074590

技术规格

AppearanceWhite to Dark green powder to crystal
Purity(Neutralization titration)97.0 to 111.0 %

物性(参考值)

熔点105 ℃
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
102001J&K2,4-Dimethoxyphenylboronic acid98%196元/1G;   472元/5G;   1011元/25G;   展开

基本信息

分子式C8H11BO4
分子量181.98
熔点125-127
MDL编码MFCD01074590
Beilstein4744213

安全信息

防范说明P262
WGK3
TSCA
B24374Alfa Aesar2,4-Dimethoxybenzeneboronic acid98%775元/1g;   2001元/5g;   8430元/25g;   展开

基本信息

MDL
MFCD01074590

分子式
C8H11BO4

分子量
181.98

熔点
115-120°

形态
Powder

Beilstein
4744213

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

483486Sigma-Aldrich2,4-Dimethoxyphenylboronic acid95%297.45元/1 G;   2271.51元/10 G;   展开

产品说明

应用

2,4-Dimethoxyphenylboronic acid can be used:

  • As a reactant in meatal-catalyzed Suzuki−Miyaura cross-coupling reaction.
  • To prepare hydroxy(trimethoxy)phenanthrene by cross-coupling with bromo(benzyloxy)methoxybenzaldehyde followed by condensation and debenzylation reaction.
  • To synthesize 2,4-dimethoxy-1-(trifluoromethyl)benzene via Cu-catalyzed trifluoromethylation reaction.

包装

1, 10 g in glass bottle

其他说明

含有不定量的酸酐

基本信息

线性分子式(CH3O)2C6H3B(OH)2
分子量181.98
MDL编号MFCD01074590
PubChem化学物质编号24871896
NACRESNA.22

产品性质

质量水平200
测定95%
mp125-127 ℃ (lit.)
SMILES stringCOc1ccc(B(O)O)c(OC)c1
InChI1S/C8H11BO4/c1-12-6-3-4-7(9(10)11)8(5-6)13-2/h3-5,10-11H,1-2H3
InChI keySQTUYFKNCCBFRR-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
010989Fluorochem2,4-Dimethoxybenzeneboronic acid95%242元/1g;   506元/5g;   792元/10g;   1496元/25g;   展开

基本信息

CAS Number133730-34-4
MDL NumberMFCD01074590

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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