CAS 133545-25-2; (S)-(6,6'-二甲氧基联苯-2,2'-二基)二[双(4-甲基苯基)膦]; (S)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis[bis(4-methylphenyl)phosphine]

CAS:

133545-25-2

分子式:

C₄₂H₄₀O₂P₂

分子量:

638.7133

中文名称:

(S)-(6,6'-二甲氧基联苯-2,2'-二基)二[双(4-甲基苯基)膦]

(S)-2,2'-双(二-对甲苯基膦)-6,6'-二甲氧基-1,1'-联苯

英文名称:

(S)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis[bis(4-methylphenyl)phosphine]

(S)-2,2'-bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl

(S)-p-tol-meobiphep

sl-a102-2

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货号	品牌	产品名称	规格	包装、参考价格	详情
S918825	MACKLIN	(S)-(-)-2,2'-二(二对甲苯基磷)-6,6'-二甲氧基- 1,1' -联苯	98%	469元/50mg; 733元/100mg; 1822元/250mg; 5845元/1g;	展开
储存：2-8°C，密闭，干燥
15-0157	Strem	(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl	min. 97%	1215元/100mg; 4530元/500mg; 15420元/2g; 61680元/10g;	展开
Technical Note： 1.See150042 2. Ru and Ir catalyzed dynamic kinetic res olution for the synthesis of hydroxy, amino acidderivatives 3. Ru-catalyzed asymmetric hydrogenation of ketones and alkenes. 4.lr catalyzed enantioselective hydrogenation of heteroaromatic compounds . 5. Conjugate addition using 2-heteroaryl titanates and zinc reagents. 6.Enantio- and regios elective heck-type reaction of aryl boronic acids with 2,3 dihydrofuran 7.Rhodium-catalyzed carbonyl Z-dienylation. 8.Rhodium-catalyzed asymmetric 1,4 addition of arylboronic acids to maleimides and enones . References: 1.Adv. Synth. Catal., 2004, 346, 842. 2.Org. L ett., 2006, 8, 4573. 3.Org. Process Res. Devel., 2001, 5, 438. 4.J. Am. Chem. Soc., 2003, 125, 10536. 5.Org. L ett., 2009, 11, 4200. 6.J .Org. Chem., 2007, 72 , 387 5. 7.J. Am. C hem. Soc., 2006, 128, 1 6040. 8.J. Org. Chem., 2011, 76, 6925.