基本信息

技术规格

物性(参考值)

安全信息

图形或危害标志
信号词	危险
危险性说明	H318 : 造成严重眼损伤。 H225 : 高度易燃液体和蒸气。 H260 : 遇水放出可自燃的易燃气体。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P223 : 不得与水接触。 P240 : 容器和装载设备接地/等势联接。 P231 + P232 : 在惰性气体中操作。防潮。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P233 : 保持容器密闭。 P243 : 采取防止静电放电的措施。 P241 : 使用防爆的电气/通风/照明设备。 P242 : 只能使用不产生火花的工具。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P335 + P334 : 掸掉皮肤上的细小颗粒。浸入冷水中/用湿绷带包扎。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。 P402+P404 : 存放于干燥处。存放于密闭的容器中。 P403 + P235 : 存放在通风良好的地方。保持低温。

相关法规

运输信息

基本信息

安全信息

图形或危害标志
提示语	Danger
危险说明	H225 H260 H302 H312 H315 H318 H335 H351
防范说明	P210 P231+P232 P280 P370+P378 P402+P404 P403+P235
UN号码	3399
危险分类	4.3
次要危险性	3
包装等级	I
WGK	3
TSCA	是

基本信息

安全信息

图形或危害标志
提示语	Danger
危险说明	H225 H260 H302 H318
防范说明	P210 P223 P231+P232 P280 P370+P378 P422
UN号码	3398
危险分类	4.3
包装等级	II
WGK	3
TSCA	是

基本信息

安全信息

图形或危害标志
提示语	Danger
危险说明	EUH014 H225 H260 H315 H318 H335
防范说明	P210 P223 P231+P232 P261 P370+P378 P422
UN号码	3399
危险分类	4.3
次要危险性	3
包装等级	I
WGK	3

应用
Borane- dimethyl sulfide is used for hydroboration and reduction reactions. It is used in the reduction of aldehydes, ketones, epoxides and carboxylic acids to give corresponding alcohols. It is also involved in the Corey-Itsuno reduction. It acts as an intermediate in the preparation of highly pure semiconductor. It is also employed as a rocket propellant.

备注
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Store in a cool place. Incompatible with acids, water, alcohols, bromine, acid anhydrides, acid chlorides and oxidizing agents.

基本信息

MDL
MFCD00013189

EINECS
236-313-6

分子式
C₂H₉BS

分子量
75.97

熔点
-38°

沸点
ca 44° dec.

闪点
-1°(30°F)

密度
0.801

折射率
1.4570

灵敏度
Keep Cold. Moisture Sensitive. Air Sensitive. Store under Argon.

形态
Liquid

溶解性
Miscible with ethyl ether, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents.

Beilstein
3663489

GHS危害和防范说明

GHS符号

Hazard Statements
H225-H260-H300-H314-H318-H335
Highly flammable liquid and vapour.In contact with water releases flammable gases which may ignite spontaneously.Fatal if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.May cause respiratory irritation.

Precautionary Statements
P223-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from any possible contact with water, because of violent reaction and possible flash fire.Keep away from any possible contact with water, because of violent reaction and possible flash fire.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
II

危险类别
11-14/15-25-37/38-41
Highly flammable.Reacts violently with water, liberating extremely flammable gases.Toxic if swallowed.Irritating to respiratory system and skin.Risk of serious damage to eyes.

安全等级
7/8-16-20-23-26-30-33-36/37/39-43-45-60
Keep container tightly closed and dry.Keep away from sources of ignition - No smoking.When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Never add water to this product.Take precautionary measures against static discharges.Wear suitable protective clothing, gloves and eye/face protection.In case of fire, use ... (indicate in the space the precise type of fire fighting equipment. If water increases risk, odd 'Never use water')In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
PV5080000

TSCA
是

应用
Borane- dimethyl sulfide is used for hydroboration and reduction reactions. It is used in the reduction of aldehydes, ketones, epoxides and carboxylic acids to give corresponding alcohols. It is also involved in the Corey-Itsuno reduction. It acts as an intermediate in the preparation of highly pure semiconductor. It is also employed as a rocket propellant.

备注
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Store in a cool place. Incompatible with acids, water, alcohols, bromine, acid anhydrides, acid chlorides and oxidizing agents.

基本信息

MDL
MFCD00013189

EINECS
236-313-6

分子式
C₂H₉BS

分子量
75.97

熔点
-38°

沸点
ca 44° dec.

闪点
-1°(31°F)

密度
0.801

折射率
1.4570

灵敏度
Moisture Sensitive. Air Sensitive. Ambient temperatures.

形态
Liquid

溶解性
Miscible with ethyl ether, tetrahydrofurane, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents.

Beilstein
3663489

GHS危害和防范说明

GHS符号

Hazard Statements
H225-H260-H301-H314-H318-H335
Highly flammable liquid and vapour.In contact with water releases flammable gases which may ignite spontaneously.Toxic if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.May cause respiratory irritation.

Precautionary Statements
P223-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from any possible contact with water, because of violent reaction and possible flash fire.Keep away from any possible contact with water, because of violent reaction and possible flash fire.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
II

危险类别
11-14/15-25-37/38-41
Highly flammable.Reacts violently with water, liberating extremely flammable gases.Toxic if swallowed.Irritating to respiratory system and skin.Risk of serious damage to eyes.

安全等级
16-23-26-36/37/39-43-45
Keep away from sources of ignition - No smoking.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of fire, use ... (indicate in the space the precise type of fire fighting equipment. If water increases risk, odd 'Never use water')In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

RTECS
PV5080000

TSCA
是

基本信息

Ref#
17706

MDL
13189

分子式
C2 H9 B S

分子量
75.95

闪点
3

密度
0.801

形态
Liquid

安全信息

危险等级
4.3

包装组
I

产品说明

一般描述

硼烷二甲硫醚络合物(BMS)是用于硼氢化反应制备有机硼烷化合物(有机合成中的关键中间体)的常用试剂​​和介导剂。BMS还用作还原剂，用于将各种官能团(例如醛、酮、环氧化物、酯和羧酸)还原为相应的醇。

应用

硼烷二甲硫醚(BH₃ Me₂S)可以用作以下反应的试剂：

• 从3-氧代戊二酸二甲酯选择性合成1,3,5-含氧化合物。
• 将臭氧化物转化为醇。
• 在CBS催化下，将二茂铁基-1,3-二酮不对称还原为1,3-二醇。
• 以C₃-对称三脚架羟基酰胺为配体，将酮对映体选择性还原为手性仲醇。
• 硼氢化还原及其他应用。
• 与树枝状聚合物载体L-吡咯烷醇一起用于茚满酮和四氢萘酮的不对称还原。

包装

25, 4×25, 100, 800 mL in Sure/Seal™
18 L in Kilo-Lab™
建议将25 mL Sure/Seal^™ 瓶作为一次性瓶使用。 反复穿刺可能会导致产品性能下降。
View returnable container options.

其他说明

10.0-10.2M 以 BH₃ 存在。可含过量甲基硫醚。

法律信息

Sure/Seal is a trademark of sigma-aldrich Co. LLC

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H225 - H260 - H301 + H311 - H318 - H360FD - H412
预防措施声明	P210 - P231 + P232 - P273 - P280 - P301 + P310 - P305 + P351 + P338
危险分类	Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Water-react. 1
补充剂危害	EUH014
储存分类代码	4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGK	WGK 1
闪点(F)	64.4 °F
闪点(C)	18 ℃
个人防护装备	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

基本信息

安全信息

图形或危害标志
提示语	Danger
危险说明	EUH014 H225 H260 H315 H318 H335
防范说明	P210 P223 P231+P232 P261 P370+P378 P422
UN号码	3399
危险分类	4.3
次要危险性	3
包装等级	III
WGK	3

基本信息

安全信息

图形或危害标志
提示语	Danger
危险说明	EUH014 H225 H260 H315 H318 H335
防范说明	P210 P223 P231+P232 P261 P370+P378 P422
UN号码	3399
危险分类	4.3
次要危险性	3
包装等级	III
WGK	3