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CAS: 131-91-9
分子式: C10H7NO2
分子量: 173.17
熔点: 106-108 °C (dec.)(lit.)
中文名称: 
α-亚硝基-β-萘酚
钴试剂
1-亚硝基-2-萘酚
英文名称: 
1-Nitroso-2-naphthalenol
1-nitroso-2-Naphthalenol
1-nitroso-2-naphtho
1-nitroso-2-naftol
1-nitroso-2-naphthol
1-nitroso-2-naphthaleno
alpha-nitroso-beta-naftol
alpha-nitroso-beta-naphthol
c.i. 10000
nitroso-beta-naphthol
zelen moridlova 4
2-Naphthalenol,1-nitroso-
2-Hydroxy-1-nitrosonaphthalene
展开更多英文名
性质描述: 橙黄色片状或棱状结晶。熔点109.5℃。溶于醇、醚、苯、四氯化碳、碱液及乙酸,微溶于冷石油醚,不溶于水。易燃,自燃时爆炸,遇酸、碱则很快自燃。
生产方法: 由β-萘酚经亚硝化而得。将β-萘酚、水氢氧化钠搅拌使其溶解。冷却后加亚硝酸钠,过滤,滤液冷却至0℃以下,在搅拌下,温度不超过0℃,连续滴加10%的盐酸至刚果红试纸变蓝为止。搅拌0.5h后过滤,用水洗至氯离子不大于自来水中的氯离子为止,再用蒸馏水及乙醇洗一次,滤出结晶,再经精制而得成品。
用途: 该品经磺化、重氮化、硝化可得到6-硝基-2,1-羟基重氮萘-4-磺酸。也称6-硝基-1,2-重氮氧基萘-4-磺酸,是酸性媒介黑染料的中间体。该品是测定钴、钯、铜和铁的试剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
N814501MACKLIN1-亚硝基-2-萘酚96%50元/5g;   192元/25g;   566元/100g;   2605元/500g;   展开
储存:室温
状态:棕色至黑色粉末或晶体和/或块状物
N0266TCI1-Nitroso-2-naphthol>98.0%(GC)(T)420元/25G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C10H7NO2 = 173.17
外观与形状(20℃)固体
Reaxys-RN776947
PubChem物质ID87573625
SDBS (AIST Spectral DB)2647
Merck Index (14)6641
MDL编号MFCD00003884

技术规格

AppearanceOrange to Brown to Dark red powder to crystaline
Purity(GC)min. 98.0 %
Purity(Neutralization titration)min. 98.0 %
Melting point106.0 to 110.0 ℃

物性(参考值)

熔点107 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。

相关法规

RTECS#QL4725000
A10622Alfa Aesar1-Nitroso-2-naphthol98%491元/10g;   1681元/50g;   4964元/250g;   展开

应用
1-Nitroso-2-naphthol as a complexing agent for the on-line preconcentration of cobalt with FI-FAAS. 1-Nitroso-2-naphthol is the chelating ion-exchanger in the synthesis of alumina adsorbents that are of acidic, basic and neutral nature. It is used for the removal and preconcentration of Pb(II), Cu(II), Cr(III) from waste, as well as drinking water. It is also used in the preconcentration of cobalt using C(18) microcolumn with flow injection that is coupled to a flame atomic absorption spectrometry (FI-FAAS) system. 1-Nitroso-2-naphthol is used in the preparation of 1-nitroso-2-naphthol-sodium nitrite reagent.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from strong oxidizing agents, strong bases.

基本信息

MDL
MFCD00003884

EINECS
205-043-0

分子式
C10H7NO2

分子量
173.17

熔点
104-108° dec.

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Insoluble in water.

Beilstein
776947

Merck
14,6641

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H335-H400
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.Very toxic to aquatic life.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
9

包装组
III

危险类别
22-36/37/38-50
Harmful if swallowed.Irritating to eyes, respiratory system and skin.Very toxic to aquatic organisms.

安全等级
26-36/37-61
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.Avoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
QL4725000

TSCA

C15153Alfa Aesar1-Nitroso-2-naphthol98%889元/25g;   2816元/100g;   11555元/500g;   展开

基本信息

Ref#
15153

MDL
3884

分子式
C10 H7 N O2

分子量
173.17

形态
Brown powder

安全信息

危险等级
9

包装组
III

114693Sigma-Aldrich1-Nitroso-2-naphthol97%611.43元/25 G;   1876.44元/100 G;   展开

产品说明

应用

1-亚硝基-2-萘酚是氧化铝吸附剂合成中的螯合离子交换剂,具有酸性、碱性和中性性质。它用于从废物及饮用水中去除和预浓缩 Pb(II)、Cu(II)、Cr(III)。它还用于使用 C(18)微柱,联合流动注射与火焰原子吸收光谱(FI-FAAS)系统耦合对钴进行预浓缩。
1-亚硝基-2-萘酚用于制备 1-亚硝基-2-萘酚-亚硝酸钠试剂。

包装

25, 100 g in glass bottle

基本信息

线性分子式ONC10H6OH
分子量173.17
颜色索引号10005
Beilstein776947
EC 号205-043-0
MDL编号MFCD00003884
PubChem化学物质编号24847189
NACRESNA.22

产品性质

质量水平200
测定97%
mp106-108 ℃ (dec.) (lit.)
SMILES stringOc1ccc2ccccc2c1N=O
InChI1S/C10H7NO2/c12-9-6-5-7-3-1-2-4-8(7)10(9)11-13/h1-6,12H
InChI keyYXAOOTNFFAQIPZ-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319 - H335
预防措施声明P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
464545Fluorochem1-Nitrosonaphthalen-2-ol95%220元/1g;   770元/25g;   2222元/100g;   展开

基本信息

CAS Number131-91-9
MDL NumberMFCD00003884
Melting Point104-108℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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