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CAS: 131-56-6
分子式: C13H10O3
分子量: 214.22
沸点: 194℃(1 t
熔点: 144-147℃
中文名称: 
2,4-二羟基二苯甲酮
(2,4-二羟基苯基)苯基酮
2,4-二羟基苯酮
2,4-二羟基苯甲酮
2,4-二羟二苯甲酮
紫外线吸收剂UV-0
英文名称: 
DHB
2,4-Dihydroxy-benzophenone
(2,4-dihydroxyphenyl)phenyl-methanone
Methanone,(2,4-dihydroxyphenyl)phenyl-
(2,4-Dihydroxyphenyl)Phenylmethanone
4-Benzoylresorcinol
Ultraviolet Absorber UV-0
2,4-DHBP
2,4-Dihydroxybenzophenone
(2,4-dihydroxyphenyl) phenyl-Methanone
2,4-dihydroxy-benzophenon
2,4-dihydroxybenzofenon
advastab 48
benzoresorcinol
2,4-dihydroxydiphenyl ketone
dastib 263
eastman inhibitor dhpb
hhb
inhibitor dhbp
(2,4-dihydroxyphenyl)phenyl-methanon
quinsorb 010
resbenzophenone
syntase 100
uf 1
usaf do-28
usaf nd-54
uv 12
uvinul 400
uvistat 12
展开更多英文名
性质描述: 淡黄色针状结晶或白色粉末。熔点142.6-144.6℃.25℃的溶解度(克/100毫升溶剂):丙酮>50,苯1,乙醇>50水<0.5,正庚烷<0.5。
生产方法: 有四种主要方法。1.以间苯二酚和苯甲酰氯为原料。2.以间苯二酚和三氯甲苯为原料。3.以苯甲酸和间苯二酚为原料4.苯酐与间苯二酚缩合制得2-(2',4'-二羟基苯甲酰)苯甲酸,再经脱羟反应而得2,4-二羟基二苯甲酮。
用途: 用作紫外线吸收剂,由本品衍生的2-羟基-4-甲氧基二苯甲酮(UV-9)、2-羟基-4-正辛氧基二苯甲酮(UV-531)等二苯甲酮类,以及其他单羟基、双羟基、三羟基、四羟基的此类化合物是应用最广的吸收型光稳定剂。能吸收290-400纳米的紫外光,并且与多数合成树脂有良好的相容性,被广泛应用于高分子材料中。2,4-二羟基二苯甲酮适用于聚氯乙烯、聚苯乙烯、环氧树脂、纤维素树脂、不饱和聚酯、涂料和合成橡胶等。最大吸收波长范围280-340纳米,一般用量0.1-1%。但本品的光稳定效果并不突出。本品对大白鼠口服LD50灰8600毫克/公斤,小白鼠为2336毫克/公斤。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D807357MACKLIN2,4-二羟基二苯甲酮99%30元/25g;   47元/100g;   213元/500g;   1047元/2.5kg;   展开
储存:室温
状态:淡黄色粉末或晶体
D0573TCI2,4-Dihydroxybenzophenone>98.0%(GC)(T)130元/25G;   790元/500G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C13H10O3 = 214.22
外观与形状(20℃)固体
Reaxys-RN1311566
PubChem物质ID87567226
SDBS (AIST Spectral DB)7167
Merck Index (14)1106
MDL编号MFCD00002277

技术规格

AppearanceLight yellow to Yellow powder to crystal
Purity(GC)min. 98.0 %
Purity(Neutralization titration)min. 98.0 %
Melting point143.0 to 147.0 ℃

物性(参考值)

熔点144 ℃
水溶性不溶
溶解性(易溶于)醇,乙醚
溶解度(极微溶)

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#DJ0700000
589776J&K2,4-Dihydroxybenzophenone99%60元/25G;   195元/100G;   636元/500G;   展开

基本信息

分子式C13H10O3
分子量214.22
熔点144-147
MDL编码MFCD00002277
Beilstein1311566
Merck14,1106
EINECS 编号205-029-4

安全信息

图形或危害标志
提示语Warning
危险说明H319
防范说明P305+P351+P338
WGK2
RTECSDJ0700000
TSCA
A13749Alfa Aesar2,4-Dihydroxybenzophenone99%384元/100g;   1637元/500g;   6674元/2500g;   展开

应用
Novel mordent and disperse azo dyes were prepared by the coupling of various diazo solutions of aromatic amines with 2, 4-dihydroxybenzophenone. The ultraviolet absorbing monomers were synthesized by reaction of 2, 4-dihydroxybenzophenone with glycidyl acrylate and glycidyl methacrylate. Two new polymerizable stabilizers, 4-benzoyl-2-(α-piperidino-2-chlorobenzyl)-3-hydroxyphenyl acrylate (BPBHA) and corresponding methacrylate (BPBHMA), were synthesized and characterized from 2,4-Dihydroxybenzophenone. a polymerizable UV-stabilizer, 2-hydroxy-4-(3-methacryloxy-2-hydroxylpropoxy) benzophenone (BPMA), was synthesized using 2, 4-dihydroxybenzophenone (UV-0) and glycidyl methacrylate (GMA).

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

基本信息

MDL
MFCD00002277

EINECS
205-029-4

分子式
C13H10O3

分子量
214.22

熔点
144-147°

沸点
194°/1mm

闪点
125°(257°F)

密度
1.320

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Insoluble in water.

Beilstein
1311566

Merck
14,1106

GHS危害和防范说明

GHS符号

Hazard Statements
H319
Causes serious eye irritation.

Precautionary Statements
P280i-P264-P305+P351+P338-P337+P313
Wear eye/face protection.Wash thoroughly after handling.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.If eye irritation persists: Get medical advice/attention.

安全信息

危险等级
9

包装组
III

危险类别
36
Irritating to eyes.

安全等级
26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
DJ0700000

TSCA

126217Sigma-Aldrich2,4-Dihydroxybenzophenone99%392.16元/100 G;   展开

基本信息

线性分子式(HO)2C6H3COC6H5
分子量214.22
Beilstein1311566
EC 号205-029-4
MDL编号MFCD00002277
PubChem化学物质编号24847708
NACRESNA.23

产品性质

质量水平200
测定99%
形式powder
mp144.5-147 ℃ (lit.)
SMILES stringOc1ccc(c(O)c1)C(=O)c2ccccc2
InChI1S/C13H10O3/c14-10-6-7-11(12(15)8-10)13(16)9-4-2-1-3-5-9/h1-8,14-15H
InChI keyZXDDPOHVAMWLBH-UHFFFAOYSA-N
Gene Informationrat ... Ar(24208)

安全信息

象形图GHS07GHS08GHS09
警示用语:Warning
危险声明H319 - H361fd - H411
预防措施声明P202 - P264 - P273 - P280 - P305 + P351 + P338 - P308 + P313
危险分类Aquatic Chronic 2 - Eye Irrit. 2 - Repr. 2
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)257.0 °F
闪点(C)125 ℃
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
8.18652Sigma-Aldrich2,4-Dihydroxybenzophenonefor synthesis394.68元/250 G;   展开

产品说明

分析说明

Assay (acidimetric): ≥ 99.0 %
Melting range (lower value): ≥ 143 °C
Melting range (upper value): ≤ 146 °C
Identity (IR): passes test

基本信息

线性分子式2,4-(OH)2-C6H3COC6H5
分子量214.22
MDL编号MFCD00002277
EC索引号205-029-4

产品性质

质量水平200
测定≥99.0% (acidimetric)
效能>5000 mg/kg LD50, oral (Rat)
pH值(酸碱度)5 (20 ℃, 10 g/L in H2O, slurry)
mp143-146 ℃
密度1.32 g/cm3 at 20 ℃
堆积密度750 kg/m3
储存温度2-30℃
InChI1S/C13H10O3/c14-10-6-7-11(12(15)8-10)13(16)9-4-2-1-3-5-9/h1-8,14-15H
InChI keyZXDDPOHVAMWLBH-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08GHS09
警示用语:Warning
危险声明H319 - H361fd - H411
预防措施声明P202 - P264 - P273 - P280 - P305 + P351 + P338 - P308 + P313
危险分类Aquatic Chronic 2 - Eye Irrit. 2 - Repr. 2
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)257.0 °F
闪点(C)125 ℃
236844Fluorochem(2,4-Dihydroxyphenyl)(phenyl)methanone95%264元/100g;   展开

基本信息

CAS Number131-56-6
MDL NumberMFCD00002277

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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