CAS 13089-11-7; methyl trifluoropyruvate

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货号

品牌

产品名称

规格

包装、参考价格

M813744

MACKLIN

三氟丙酮酸甲酯

97%

65元/5g;

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储存：室温,易燃物区域
状态：无色到黄色液体
折射率：n20/D 1.332(lit.)

T1785

TCI

Methyl Trifluoropyruvate

>98.0%(GC)

170元/1G; 490元/5G;

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基本信息

纯度/分析方法	>98.0%(GC)
分子式/分子量	C₄H₃F₃O₃ = 156.06
外观与形状(20℃)	液体
储存温度	0-10℃
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气,加热
Reaxys-RN	1863490
PubChem物质ID	87577518
MDL编号	MFCD00114936

技术规格

Appearance	Light orange to Yellow to Green clear liquid
Purity(GC)	min. 98.0 %

物性(参考值)

沸点	86 ℃
闪点	26 ℃
比重	1.39
折射率	1.33

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。 H226 : 易燃液体和蒸气。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P240 : 容器和装载设备接地/等势联接。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P233 : 保持容器密闭。 P243 : 采取防止静电放电的措施。 P241 : 使用防爆的电气/通风/照明设备。 P242 : 只能使用不产生火花的工具。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P403 + P235 : 存放在通风良好的地方。保持低温。

运输信息

UN编号	UN3272
类别	3
包装类别	III
监管条件代码(*)

181471

J&K

Methyl 3,3,3-trifluoropyruvate

97%

209元/5G;

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基本信息

分子式	C₄H₃F₃O₃
分子量	156.06
沸点	86
闪点	26
密度	1.529
折光率(n20D)	1.3320
MDL编码	MFCD00114936
Beilstein	1863490

安全信息

图形或危害标志
提示语	Warning
危险说明	H226
防范说明	P262
UN号码	1993
危险分类	3
包装等级	III
WGK	3
TSCA	否

B21589

Alfa Aesar

Methyl Trifluoropyruvate

97%

213元/1g; 1260元/5g; 4653元/25g;

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基本信息

MDL
MFCD00114936

EINECS
000-000-0

分子式
C₄H₃F₃O₃

分子量
156.06

沸点
84-86°

闪点
26°(79°F)

密度
1.52

折射率
1.3320

灵敏度
Ambient temperatures.

形态
Liquid

Beilstein
1863490

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H315-H319-H335
Flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
10-36/37/38
Flammable.Irritating to eyes, respiratory system and skin.

安全等级
23-26-37
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

C37971

Alfa Aesar

Methyl 3,3,3-trifluoropyruvate

97%

1176元/5g;

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基本信息

Ref#
37971

MDL
114936

分子式
C4 H3 F3 O3

分子量
156.06

闪点
26

密度
1.39

安全信息

危险等级
3

包装组
III

510246

Sigma-Aldrich

Methyl 3,3,3-trifluoropyruvate

97%

337.72元/5 G;

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产品说明

一般描述

Methyl 3,3,3-trifluoropyruvate is an alkyl 3,3,3-trifluoropyruvate that can be synthesized using hexafluoropropene-1,2-oxide (HFPO) as a starting material. It reacts with aromatic amines, benzylic manoamines and diamines to form the corresponding hemiaminals.

应用

Methyl 3,3,3-trifluoropyruvate may be used in the synthesis of:

2-hydroxy-2-trifluoromethylbutan-4-olides
2-(trifluoromethyl)butan-4-olides
4-trifluoromethyl-(2H)-pyridazin-3-ones
methyl 3-methoxy-2-trifluoromethylacrylate

包装

5 g in glass bottle

基本信息

线性分子式	CF₃COCO₂CH₃
分子量	156.06
MDL编号	MFCD00114936
PubChem化学物质编号	24873485
NACRES	NA.22

产品性质

质量水平	100
测定	97%
折射率	n20/D 1.332 (lit.)
bp	86 ℃ (lit.)
密度	1.529 g/mL at 25 ℃ (lit.)
SMILES string	COC(=O)C(=O)C(F)(F)F
InChI	1S/C4H3F3O3/c1-10-3(9)2(8)4(5,6)7/h1H3
InChI key	XGLLQDIWQRQROJ-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H226
危险分类	Flam. Liq. 3
储存分类代码	3 - Flammable liquids
WGK	WGK 3
闪点(F)	78.8 °F - closed cup
闪点(C)	26 ℃ - closed cup
个人防护装备	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

006851

Fluorochem

Methyl Trifluoropyruvate

97%

220元/1g; 220元/5g; 704元/25g; 2376元/100g;

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基本信息

CAS Number	13089-11-7
MDL Number	MFCD00114936
Density	1.529

安全信息

图形或危害标志
危险性说明	H226: Flammable liquid and vapour. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P210: Keep away from – No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof / equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P370 + P378: In case of fire: Use for extinction. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up. P501: Dispose of contents/container to local regulations.