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CAS: 129-00-0
分子式: C16H10
分子量: 202.25
沸点: 393℃
熔点: 148-151℃
中文名称: 
嵌二萘
苯并[DEF]菲
英文名称: 
Pyrene
benzo(d,e,f)phenanthrene
benzo(def)phenanthrene
beta-pyrene
coal tar pitch volatiles:pyrene
pyren
Benzo[def]phenanthrene
Pyrene1,1,1-Trichloro-2-methyl-2-propanolBenzo(d,e,f)phenanthrene
pyrene(benzo[def]phenanthrene)
pyrene 5
pyrene5
展开更多英文名
性质描述: 淡黄色单斜晶体。不溶于水,易溶于乙醚、二硫化碳、苯和甲苯。熔点150℃,闪点210℃,沸点393℃,相对密度1.271(22/4℃)。
生产方法: 芘主要存在于煤焦油沥青的蒸馏物中。将中温沥青减压蒸馏,同时向蒸馏釜通入少量直接过热蒸汽,切取芘的窄馏分,然后用溶剂油和乙醇混合溶液,或苯和溶剂油的混合溶液重结晶,即得到纯度95%的工业芘。
用途: 有机合成原料,经氧化可制取1,4,5,8-萘四甲酸,用于染料、合成树脂和工程塑料;酰化后可制还原染料艳橙GR及其他多种染料。还可制杀虫剂、增塑剂等。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
P817273MACKLIN升华纯化, 99%30元/1g;   80元/5g;   279元/25g;   708元/100g;   2460元/500g;   展开
储存:室温,易燃物区域
状态:黄色粉末,晶体和/或块状
P817272MACKLIN97%31元/5g;   64元/25g;   178元/100g;   682元/500g;   3405元/2.5kg;   展开
储存:室温,易燃物区域
状态:浅黄色到黄色绿色晶体或块状
P1104TCIPyrene>97.0%(GC)375元/25G;   820元/100G;   3245元/500G;   展开

基本信息

纯度/分析方法>97.0%(GC)
分子式/分子量C16H10 = 202.26
外观与形状(20℃)固体
Reaxys-RN1307225
PubChem物质ID87575210
SDBS (AIST Spectral DB)878
Merck Index (14)7963
MDL编号MFCD00004136

技术规格

AppearanceWhite to Orange to Green powder to crystal
Purity(GC)min. 97.0 %
Melting point148.0 to 152.0 ℃
Solubility in Toluenealmost transparency

物性(参考值)

熔点150 ℃
沸点404 ℃
最大吸收波长330(EtOH) nm
溶解性(可溶于)甲苯

安全信息

图形或危害标志
信号词危险
危险性说明H330 : 吸入致命。
H303 : 吞咽可能有害。
H410 : 对水生生物毒性极大并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P271 : 只能在室外或通风良好之处使用。
P284 : [在通风不足的情况下]戴呼吸防护装置。
P312 : 如感觉不适,呼叫急救中心/医生。
P391 : 收集溢出物。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

相关法规

RTECS#UR2450000

运输信息

UN编号UN2811
类别6.1
包装类别 II
监管条件代码(*)
P2072TCIPyrene (purified by sublimation)>98.0%(GC)385元/1G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C16H10 = 202.26
外观与形状(20℃)固体
Reaxys-RN1307225
PubChem物质ID253659905
SDBS (AIST Spectral DB)878
Merck Index (14)7963
MDL编号MFCD00004136

技术规格

AppearanceWhite to Orange to Green powder to crystal
Purity(GC)min. 98.0 %
Melting point148.0 to 152.0 ℃

物性(参考值)

熔点151 ℃
沸点404 ℃
最大吸收波长330(EtOH) nm

安全信息

图形或危害标志
信号词危险
危险性说明H330 : 吸入致命。
H303 : 吞咽可能有害。
H410 : 对水生生物毒性极大并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P271 : 只能在室外或通风良好之处使用。
P284 : [在通风不足的情况下]戴呼吸防护装置。
P312 : 如感觉不适,呼叫急救中心/医生。
P391 : 收集溢出物。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

相关法规

RTECS#UR2450000

运输信息

UN编号UN2811
类别6.1
包装类别 II
监管条件代码(*)
212641J&KPyrene98%274元/25G;   684元/100G;   2429元/500g;   展开

基本信息

分子式C16H10
分子量202.25
熔点145-148
沸点390-395
闪点>200
密度1.21
MDL编码MFCD00004136
Beilstein1307225
Merck14,7963
EINECS 编号204-927-3

荧光性质

λex 338 nm; λem 375 nm in DMSO

分析说明

除了在 375 nm 处的发射最大值外,在 395、385、380、415 和 445 nm 处最大值较低。

安全信息

图形或危害标志
提示语Warning
危险说明H319
H410
防范说明P273
P305+P351+P338
P501
UN号码3077
危险分类9
包装等级III
WGK2
RTECSUR2450000
TSCA
L08162Alfa AesarPyrene98%462元/25g;   1143元/100g;   展开

应用
Pyrene and its derivatives are used commercially to make? dyes? and dye precursors, for example? pyranine? and naphthalene-1,4,5,8-tetracarboxylic acid. It is used as a probe to determine solvent environments and fluorescence spectroscopy.

备注
Incompatible materials are oxidizing agents. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents.

基本信息

MDL
MFCD00004136

EINECS
204-927-3

分子式
C16H10

分子量
202.26

熔点
148-152°

沸点
393°

闪点
208°(406°F)

密度
1.271

灵敏度
Ambient temperatures.

形态
Crystals

溶解性
Soluble in toluene. Insoluble in water.

Beilstein
1307225

Merck
14,7963

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H400-H410
May be harmful if swallowed.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

安全信息

危险等级
9

包装组
III

危险类别
50/53
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
36-61
Wear suitable protective clothing.Avoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
UR2450000

TSCA

C18083Alfa AesarPyrene98%597元/25g;   1368元/100g;   4635元/500g;   展开

基本信息

Ref#
18083

MDL
4136

分子式
C16 H10

分子量
202.25

闪点
210

形态
Yellow to pale brown cryst solid

安全信息

危险等级
9

包装组
III

185515Sigma-AldrichPyrene98%284.5元/1 G;   520.7元/25 G;   909.24元/100 G;   展开

基本信息

经验(实验)分子式C16H10
分子量202.25
Beilstein1307225
EC 号204-927-3
MDL编号MFCD00004136
PubChem化学物质编号24851146
NACRESNA.23

产品性质

质量水平100
测定98%
mp145-148 ℃ (lit.)
SMILES stringc1cc2ccc3cccc4ccc(c1)c2c34
InChI1S/C16H10/c1-3-11-7-9-13-5-2-6-14-10-8-12(4-1)15(11)16(13)14/h1-10H
InChI keyBBEAQIROQSPTKN-UHFFFAOYSA-N
Gene Informationhuman ... CYP1A2(1544)

安全信息

象形图GHS09
警示用语:Warning
危险声明H410
预防措施声明P273 - P391 - P501
危险分类Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)435.2 °F
闪点(C)224 ℃
个人防护装备Eyeshields, Gloves
82648Sigma-AldrichPyrenepuriss. p.a., for fluorescence, ≥99.0% (GC)582.75元/1 G;   1832.62元/10 G;   展开

产品说明

分析说明

除了在 375 nm 处的发射最大值外,在 395、385、380、415 和 445 nm 处最大值较低。

基本信息

经验(实验)分子式C16H10
分子量202.25
Beilstein1307225
EC 号204-927-3
MDL编号MFCD00004136
PubChem化学物质编号57652921
NACRESNA.32

产品性质

质量水平200
等级for fluorescence
puriss. p.a.
测定≥99.0% (GC)
mp145-148 ℃ (lit.)
151-154 ℃
溶解性ethanol: soluble
痕量阳离子Ca: ≤50 mg/kg
Cd: ≤50 mg/kg
Co: ≤50 mg/kg
Cr: ≤50 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤50 mg/kg
Mg: ≤50 mg/kg
Mn: ≤50 mg/kg
Na: ≤50 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg
荧光λex 338 nm; λem 375 nm in DMSO
SMILES stringc1cc2ccc3cccc4ccc(c1)c2c34
InChI1S/C16H10/c1-3-11-7-9-13-5-2-6-14-10-8-12(4-1)15(11)16(13)14/h1-10H
InChI keyBBEAQIROQSPTKN-UHFFFAOYSA-N
Gene Informationhuman ... CYP1A2(1544)

安全信息

象形图GHS09
警示用语:Warning
危险声明H410
预防措施声明P273 - P391 - P501
危险分类Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)435.2 °F
闪点(C)224 ℃
个人防护装备Eyeshields, Gloves
571245Sigma-AldrichPyrenesublimed grade, 99%737.14元/1 G;   展开

基本信息

经验(实验)分子式C16H10
分子量202.25
Beilstein1307225
EC 号204-927-3
MDL编号MFCD00004136
PubChem化学物质编号24880620
NACRESNA.23

产品性质

等级sublimed grade
质量水平100
测定99%
mp145-148 ℃ (lit.)
荧光λex 338 nm; λem 375 nm in DMSO
SMILES stringc1cc2ccc3cccc4ccc(c1)c2c34
InChI1S/C16H10/c1-3-11-7-9-13-5-2-6-14-10-8-12(4-1)15(11)16(13)14/h1-10H
InChI keyBBEAQIROQSPTKN-UHFFFAOYSA-N
Gene Informationhuman ... CYP1A2(1544)

安全信息

象形图GHS09
警示用语:Warning
危险声明H410
预防措施声明P273 - P391 - P501
危险分类Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)435.2 °F
闪点(C)224 ℃
个人防护装备Eyeshields, Gloves
18868SupelcoPyrenecertified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland1785.11元/100 mg;   展开

产品说明

一般描述

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com.
Pyrene belongs to polycyclic aromatic hydrocarbon group. These are organic compounds which have two or more fused benzene rings in linear, angular and cluster arrangements. Pyrene is a four ring PAH.

应用

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

包装

Bottomless glass bottle. Contents are inside inserted fused cone.

法律信息

TraceCERT is a registered trademark of sigma-aldrich Co. LLC

基本信息

经验(实验)分子式C16H10
分子量202.25
Beilstein1307225
EC 号204-927-3
MDL编号MFCD00004136
PubChem化学物质编号329751751
NACRESNA.24

产品性质

质量水平300
等级certified reference material
TraceCERT®
产品线TraceCERT®
保质期limited shelf life, expiry date on the label
technique(s)HPLC: suitable
gas chromatography (GC): suitable
mp145-148 ℃ (lit.)
application(s)environmental
格式neat
SMILES stringc1cc2ccc3cccc4ccc(c1)c2c34
InChI1S/C16H10/c1-3-11-7-9-13-5-2-6-14-10-8-12(4-1)15(11)16(13)14/h1-10H
InChI keyBBEAQIROQSPTKN-UHFFFAOYSA-N

安全信息

象形图GHS09
警示用语:Warning
危险声明H410
预防措施声明P273 - P391 - P501
危险分类Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)435.2 °F
闪点(C)224 ℃
8.21051Sigma-AldrichPyrenefor synthesis222.3元/5 G;   394.55元/50 G;   1156.56元/250 G;   展开

产品说明

分析说明

Assay (GC, area%): ≥ 96.0 % (a/a)
Melting range (lower value): ≥ 147 °C
Melting range (upper value): ≤ 150 °C
Identity (IR): passes test

基本信息

经验(实验)分子式C16H10
分子量202.25
MDL编号MFCD00004136
EC索引号204-927-3

产品性质

质量水平200
蒸汽压<1 hPa ( 20 ℃)
测定≥96.0% (GC)
效能2700 mg/kg LD50, oral (Rat)
bp393 ℃/1013 hPa
mp145.3 ℃
转变温度flash point 224 ℃
密度1.209 g/cm3 at 20 ℃
堆积密度650 kg/m3
储存温度no temp limit
InChI1S/C16H10/c1-3-11-7-9-13-5-2-6-14-10-8-12(4-1)15(11)16(13)14/h1-10H
InChI keyBBEAQIROQSPTKN-UHFFFAOYSA-N

安全信息

象形图GHS09
警示用语:Warning
危险声明H410
预防措施声明P273 - P391 - P501
危险分类Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)435.2 °F
闪点(C)224 ℃
48570SupelcoPyreneanalytical standard925.22元/5000 MG;   展开

产品说明

一般描述

Pyrene is a neat reference standard, which may be used for environmental analysis.
Pyrene belongs to polycyclic aromatic hydrocarbon group. These are organic compounds which have two or more fused benzene rings in linear, angular and cluster arrangements. Pyrene is a four ring PAH.

应用

Pyrene may be used as an analytical reference standard for the quantification of the analyte in environmental tobacco smoke samples using high-performance liquid chromatography technique.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

基本信息

经验(实验)分子式C16H10
分子量202.25
Beilstein1307225
EC 号204-927-3
MDL编号MFCD00004136
PubChem化学物质编号24872119

产品性质

等级analytical standard
CofAcurrent certificate can be downloaded
包装ampule of 5000 mg
technique(s)HPLC: suitable
gas chromatography (GC): suitable
mp145-148 ℃ (lit.)
application(s)environmental
格式neat
储存温度2-30℃
SMILES stringc1cc2ccc3cccc4ccc(c1)c2c34
InChI1S/C16H10/c1-3-11-7-9-13-5-2-6-14-10-8-12(4-1)15(11)16(13)14/h1-10H
InChI keyBBEAQIROQSPTKN-UHFFFAOYSA-N
Gene Informationhuman ... CYP1A2(1544)

安全信息

象形图GHS09
警示用语:Warning
危险声明H410
危险分类Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码13 - Non Combustible Solids
WGKWGK 2
闪点(F)No data available
闪点(C)No data available
个人防护装备Eyeshields, Gloves
409791AmethystPyrene98%, 试剂级40元/5G;   79元/25G;   257元/100G;   788元/500G;   展开

基本信息

分子式C16H10
分子量202.25
熔点145-148
沸点390-395
闪点>200
密度1.21
MDL编码MFCD00004136
Beilstein1307225
Merck14,7963
EINECS 编号204-927-3

安全信息

图形或危害标志
提示语Warning
危险说明H319
H410
防范说明P273
P305+P351+P338
P501
UN号码3077
危险分类9
包装等级III
WGK2
RTECSUR2450000
TSCA
APP-9-185AccuStandardPyrene,100 μg/mL in MeOH100 μg/mL in MeOH232元/1mL;   展开
Pyrene129-00-0100 µg/mL
APP-9-185-10XAccuStandardPyrene,1000 μg/mL in MeOH1000 μg/mL in MeOH386元/1mL;   展开
Pyrene129-00-0100 µg/mL
AS-E0082AccuStandardPyrene,5.0 mg/mL in MeOH5.0 mg/mL in MeOH494元/1mL;   展开
Pyrene129-00-05 mg/mL
H-123NAccuStandardPyrene201元/100mg;   展开
Pyrene129-00-0
M-8310-FL-18AccuStandardPyrene,0.5 mg/mL in Acetonitrile0.5 mg/mL in Acetonitrile309元/1mL;   展开
Pyrene129-00-0.5 mg/mL
Z-013-16AccuStandardPyrene in Dichloromethane,0.2 mg/mL in Dichloromethane0.2 mg/mL in Dichloromethane232元/1mL;   展开
Pyrene129-00-0.2 mg/mL
449367FluorochemPyrene95%220元/1g;   264元/5g;   展开

基本信息

CAS Number129-00-0
MDL NumberMFCD00004136

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H341: Suspected of causing genetic defects ..
H372: Causes damage to organs Blood.
H410: Very toxic to aquatic life with long lasting effects.
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P281: Use personal protective equipment as required.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P391: Collect spillage.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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