| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| C824723 | MACKLIN | 4′-氯-2,2′:6′,2′′-三联吡啶 | 98% | 73元/250mg; 270元/1g; 1335元/5g; 6650元/25g; | 咨询 |
储存：2~8 ℃ 状态：白色到灰色到绿色或棕褐色粉末或晶体 |
| C3187 | TCI | 4'-Chloro-2,2':6',2''-terpyridine | >98.0%(GC)(T) | 485元/200MG; 1600元/1G; | 咨询 |
基本信息 | 纯度/分析方法 | >98.0%(GC)(T) | | 分子式/分子量 | C15H10ClN3 = 267.72 | | 外观与形状(20℃) | 固体 | | Reaxys-RN | 3613386 | | PubChem物质ID | 354334312 | | MDL编号 | MFCD00191930 |
技术规格 | Appearance | White to Light yellow to Light orange powder to crystal | | Purity(GC) | min. 98.0 % | | Purity(Nonaqueous Titration) | min. 98.0 % | | Melting point | 150.0 to 154.0 ℃ |
物性(参考值) | 熔点 | 152 ℃ | | 最大吸收波长 | 278(CH3CN) nm |
安全信息 | 图形或危害标志 |  | | 信号词 | 警告 | | 危险性说明 | H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
| | 防范说明 | P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染：用水充分清洗。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激：求医/就诊。
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| 153712 | J&K | 4'-Chloro-2,2':6',2''-terpyridine | 99% | 241元/250MG; 789元/1G; | 咨询 |
基本信息 | 分子式 | C15H10ClN3 | | 分子量 | 267.72 | | 熔点 | 148-152 | | MDL编码 | MFCD00191930 | | Beilstein | 3613386 |
安全信息 | 图形或危害标志 |   | | 提示语 | Danger | | 危险说明 | H301
H315
H318
H335 | | 防范说明 | P261
P280
P301+P310
P305+P351+P338 | | UN号码 | 2811 | | 危险分类 | 6.1 | | 包装等级 | III | | WGK | 3 | | TSCA | 否 |
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| L14728 | Alfa Aesar | 4'-Chloro-2,2':6',2''-terpyridine | 98% | 548元/250mg; 1432元/1g; | 咨询 |
应用
4'-Chloro-2,2':6',2''-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture double helicates, dendrimers, micelles and metallo-supramolecular polymers. It is used to synthesize the mono- and bis-terpyridines. It is actively involved in Williamson type ether reactions alpha,μ-bishydroxy-functionalized poly(propylene oxide). 备注
Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents. 基本信息 MDL
MFCD00191930 分子式
C15H10ClN3 分子量
267.72 熔点
148-152° 灵敏度
Ambient temperatures. 形态
Powder 溶解性
Slightly soluble in water. Beilstein
3613386 GHS危害和防范说明 GHS符号
Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险等级
6.1 包装组
III 危险类别
36/37/38
Irritating to eyes, respiratory system and skin. 安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. TSCA
否 |
| C31967 | Alfa Aesar | 4'-Chloro-2,2':6',2''-terpyridine | 99% | 2626元/1g; | 咨询 |
基本信息 Ref#
31967 MDL
191930 分子式
C15 H10 Cl N3 分子量
267.72 |
| 405868 | Sigma-Aldrich | 4′-Chloro-2,2′:6′,2′′-terpyridine | 99% | 1848.79元/1 G; | 咨询 |
产品说明 一般描述 4′-氯-2,2′:6′,2′-三联吡啶 (4′-Cltpy,Cltpy,Cl-terpy) 是一种三齿配体，含有一个三联吡啶 (tpy) 位点，Cl 位点在 4-位。它通过这两个位点与各种金属离子配位形成不同的配位聚合物。晶体结构研究表明，Cltpy 的三吡啶单元为反式、反式构象。分子沿 b 轴自行组装成堆叠柱，平面间距离为 3.51Å。 与 α,ω-双羟基-官能化的聚环氧丙烷发生 Williamson 型醚反应。它与 α-羟基-ω-羧基官能化的聚氧化乙烯发生 Williamson 型反应，得到单吡啶端基遥爪。 应用 4′-氯-2,2′:6′,2′′-三吡啶可用于以下制备过程：
- 单吡啶和双吡啶
- 双羟基功能化的三吡啶镉 (II) 配合物和富勒烯衍生物
- 4-官能化 2,2″:6″,2″-三吡啶，新型超分子结构的构建模块，如双螺旋化合物、树枝状聚合物、胶束和金属超分子聚合物
包装 1 g in glass bottle 基本信息 | 经验(实验)分子式 | C15H10ClN3 | | 分子量 | 267.71 | | MDL编号 | MFCD00191930 | | PubChem化学物质编号 | 24865338 | | NACRES | NA.22 |
产品性质 | 测定 | 99% | | 环保替代产品得分 | old score: 51
new score: 35
Find out more about DOZN™ Scoring | | 环保替代产品特性 | Waste Prevention
Atom Economy
Less Hazardous Chemical Syntheses
Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Learn more about the Principles of Green Chemistry. | | mp | 148-150 ℃ (lit.) | | 环保替代产品分类 | Re-engineered | | SMILES string | Clc1cc(nc(c1)-c2ccccn2)-c3ccccn3 | | InChI | 1S/C15H10ClN3/c16-11-9-14(12-5-1-3-7-17-12)19-15(10-11)13-6-2-4-8-18-13/h1-10H | | InChI key | AHEMFMCEBIJRMU-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H301 - H315 - H318 - H335 | | 预防措施声明 | P280 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 + P310 | | 危险分类 | Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Faceshields, Gloves |
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| 329568 | Fluorochem | 4'-Chloro-2,2':6',2''-terpyridine | 95% | 1166元/1g; 4708元/5g; 7568元/10g; | 咨询 |
基本信息 | CAS Number | 128143-89-5 | | MDL Number | MFCD00191930 | | Melting Point | 148-155℃ | | Density | 1.22 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H301: Toxic if swallowed.
H315: Causes skin irritation.
H318: Causes serious eye damage.
H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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