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CAS: 1271-19-8
分子式: C10H10Cl2Ti
分子量: 248.96
熔点: 289-291℃
中文名称: 
二氯双(η5-2,4-环戊二烯-1-基)钛
双(环戊二烯)二氯化钛
二氯二茂钛
双(环戊二烯基)二氯化钛
英文名称: 
dichlorobis(η5-2,4-cyclopentadien-1-yl)-Titanium
dichloro-di-pi-cyclopentadienyl-titaniu
bis(cyclopentadienyl)dichlorotitanium
bis(cyclopentadienyl)titanium dichloride
bis(eta(5)-cyclopentadienyl)titanium dichloride
bis(eta(sup 5)-cyclopentadienyl)titanium dichloride
bis(pi-cyclopentadienyl)titanium dichloride
biscyclopentadienyltitanium dichloride
biscyclopentadienyltitanium(iv) dichloride
dichlorobis(1,3-cyclopentadiene)titanium
dichlorobis(cyclopentadienyl)titanium
dichlorobis(eta(5)-cyclopentadienyl)titanium
dichlorobis(eta(sup 5)-2,4-cyclopentadien-1-yltitanium)
dichlorobis(eta(sup 5)-cyclopentadienyl)titanium
dichlorobis(eta5-2,4-cyclopentadien-1-yl)titanium
dichlorobis(pi-cyclopentadienyl)titanium
dichlorobiscyclopentadienyl titanium
dichlorodi-pi-cyclopentadienyltitanium
dichlorodicyclopentadienyltitanium
dichlorotitanocene
dicyclopentadienyldichlorotitanium
dicyclopentadienyltitanium dichloride
nci-c04502
titanium ferrocene
dichlorobis( eta5-2,4-cyclopentadien-1-yl)-titaniu
dichlorobis(eta(5)-2,4-cyclopentadien-1-yl)-titaniu
dichlorobis(eta(sup 5)-2,4-cyclopentadien-1-yl-titaniu
titanium, dichlorobis(eta5-2,4-cyclopentadien-1-yl)- (9ci)
dichlorodi-pi-cyclopentadienyl-titaniu
titanocenedichloride
titanocene dichloride
Titanium,dichlorobis(η5-2,4-cyclopentadien-1-yl)-
bis(η-cyclopentadienyl)-titanium chloride
bis(η-cyclopentadienyl)titanium chloride
Dichlorobis(π-cyclopentadienyl)titanium
Titanium,dichlorobis[η5-2,4-cyclopentadien-1-yl]-
Bis(cyclopentadienyl)titanium(IV)dichloride
Di(cyclopentadienyl)titanium(IV)dichloride
Dichlorobis(cyclopentodienyl)titanium
展开更多英文名
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T819116MACKLIN二氯二茂钛97%30元/5g;   81元/25g;   321元/100g;   1400元/500g;   展开
储存:室温,干燥
状态:淡棕色至深棕色至深红色和棕红色至非常深棕红色 粉末或晶体
T741839MACKLIN二氯二茂钛≥99%165元/25g;   464元/100g;   1600元/500g;   展开
储存:室温,干燥
状态:淡棕色至深棕色至深红色和棕红色至非常深棕红色 粉末或晶体
T0616TCITitanocene Dichloride>98.0%(T)295元/5G;   765元/25G;   展开

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C10H10Cl2Ti = 248.96
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
PubChem物质ID87576509
SDBS (AIST Spectral DB)11233
Merck Index (14)9482
MDL编号MFCD00003723

技术规格

AppearanceOrange to Brown to Dark red powder to crystal
Purity(Argentometric Titration)min. 98.0 %
Solubility in THFvery faint turbidity

物性(参考值)

溶解性(可溶于)甲苯,醇,氯仿
溶解度(极微溶)苯,乙醚

安全信息

图形或危害标志
信号词警告
危险性说明H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。

相关法规

RTECS#XR2050000
568146J&KBis(cyclopentadienyl)titanium Dichloride99%637元/25G;   1979元/100G;   7070元/500G;   展开

基本信息

分子式C10H10Cl2Ti
分子量248.96
熔点260-280
密度1.6
MDL编码MFCD00003723
Merck14,9482
EINECS 编号215-035-9

安全信息

图形或危害标志
提示语Warning
危险说明H315
H335
防范说明P261
WGK3
RTECSXR2050000
TSCA
22-0200StremBis(cyclopentadienyl)titanium Dichloride99+%945元/25g;   3060元/100g;   展开

Technical Notes:

1.Precatalyst for reduction of esters and a, ß-unsaturated ketones.

2. Catalyzes reductive deoxygenation of alcohols and hydroxylamines. Catalyst for the radical cyclization of epoxides .

3.Reagent for the conversion of enynes to bicyclic cyclo pentenones. 5. Catalyzes silylation of alkenes and alkynes.

References: 1.J. Org. Chem., 1994, 59, 4323. 2.Org. L ett., 201 o, 12, 44. 3.J. Am. Chem. Soc., 2010, 132, 254.
A11456Alfa AesarBis(cyclopentadienyl)titanium Dichloride97%964元/10g;   3141元/50g;   13403元/250g;   展开

应用
One-pot synthesis of α-methylene-γ-butyrolactones from benzaldehydes and bromomethylacrylates. Bis-(cyclopentadienyl)-titanium dichloride alkylaluminum complexls acts as catalysts for the polymerization of ethylene. Polyethylene prepared with these catalysts. Complexes of aluminum chloride and methylaluminum dichloride with bis-(cyclopentadienyl)-titanium dichloride as catalysts for the polymerization of ethylene.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, moisture, water, air.

基本信息

MDL
MFCD00003723

EINECS
215-035-9

分子式
C10H10Cl2Ti

分子量
249.00

熔点
ca 285° dec.

密度
1.60

灵敏度
Moisture Sensitive. Air Sensitive. Store under Argon. Ambient temperatures.

形态
Crystalline, packaged under argon

溶解性
Slightly soluble in water

Merck
14,9482

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H332-H315-H319-H341-H335
Harmful if swallowed.Harmful if inhaled.Causes skin irritation.Causes serious eye irritation.Suspected of causing genetic defects.May cause respiratory irritation.

Precautionary Statements
P201-P261-P280-P305+P351+P338-P405-P501a
Obtain special instructions before use.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
20/22-36/37/38-68
Harmful by inhalation and if swallowed.Irritating to eyes, respiratory system and skin.Possible risk of irreversible effects.

安全等级
9-26-36/37-60
Keep container in a well-ventilated place.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
XR2050000

TSCA

040386Alfa AesarBis(cyclopentadienyl)titanium Dichloride99+%344元/2g;   917元/10g;   3808元/50g;   14288元/250g;   展开

应用
This metallocene is a common reagent in organometallic and organic synthesis. Titanocene dichloride is used to prepare titanocene pentasulfide. Used as an anticancer drug.

备注
Air & Moisture Sensitive. Incompatible with strong acids, strong oxidizing agents and hot water. Keep tightly closed in a dry, well-ventilated place. Stable. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00003723

EINECS
215-035-9

分子式
C10H10Cl2Ti

分子量
249.00

熔点
ca 285° dec.

密度
1.60

灵敏度
Moisture Sensitive. Air Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Crystalline, Packaged under argon

溶解性
Reacts in moist air and in water to form HCl . Slightly hydrolysis in water.

Merck
14,9482

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H332-H315-H319-H341-H335
Harmful if swallowed.Harmful if inhaled.Causes skin irritation.Causes serious eye irritation.Suspected of causing genetic defects.May cause respiratory irritation.

Precautionary Statements
P201-P261-P280-P305+P351+P338-P405-P501a
Obtain special instructions before use.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
20/22-36/37/38-68
Harmful by inhalation and if swallowed.Irritating to eyes, respiratory system and skin.Possible risk of irreversible effects.

安全等级
9-26-36/37-60
Keep container in a well-ventilated place.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
XR2050000

TSCA

C21576Alfa AesarBis(cyclopentadienyl)titanium Dichloride97%733元/10g;   2343元/50g;   展开

基本信息

Ref#
21576

MDL
3723

分子式
C10 H10 Cl2 Ti

分子量
249

密度
1.6

安全信息

危险等级
8

包装组
II

234826Sigma-AldrichBis(cyclopentadienyl)titanium(IV) dichloride97%585.26元/10 G;   1622.01元/50 G;   展开

产品说明

包装

10, 50 g in glass bottle

应用

由苯甲醛和溴甲基丙烯酸酯一锅法合成 α-亚甲基-γ-丁内酯。

基本信息

经验(实验)分子式C10H10Cl2Ti
分子量248.96
EC 号215-035-9
MDL编号MFCD00003723
PubChem化学物质编号24854058
NACRESNA.22

产品性质

质量水平100
测定97%
reaction suitabilitycore: titanium
reagent type: catalyst
mp260-280 ℃ (dec.) (lit.)
密度1.6 g/mL at 25 ℃ (lit.)
SMILES stringCl[Ti]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI1S/2C5H5.2ClH.Ti/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChI keyXKLWATAZDMHTSH-UHFFFAOYSA-L

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
911950AmethystBis(cyclopentadienyl)titanium Dichloride97%, 用于合成68元/5G;   176元/25G;   572元/100G;   展开

基本信息

分子式C10H10Cl2Ti
分子量248.96
熔点260-280
密度1.6
MDL编码MFCD00003723
Merck14,9482
EINECS 编号215-035-9

安全信息

图形或危害标志
提示语Warning
危险说明H315
H335
防范说明P261
WGK3
RTECSXR2050000
TSCA
099333FluorochemTitanocene Dichloride97%330元/5g;   968元/25g;   展开

基本信息

CAS Number1271-19-8
MDL NumberMFCD00003723
Melting Point260-280℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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