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CAS: 126-73-8
分子式: C12H27O4P
分子量: 266.31
沸点: 289℃
熔点: -79-156℃
中文名称: 
三丁基磷酸盐
磷酸三正丁酯
TBP
磷酸三丁酯
磷酸正丁酯
英文名称: 
Tributyl phosphate
Phosphoric acid, tributyl ester
n-Butyl phosphate
butyl phosphate
tri-butyl phosphat
celluphos 4
disflamoll tb
mcs 2495
phosphate de tributyle
phosphoric acid tri-n-butyl ester
phosphoric acid tributyl ester
tri-n-butyl phosphate
tributilfosfato
tributilfosfato (italian)
tributoxyphosphine oxide
tributyle (phosphate de)
tributyle (phosphate de) (french)
tributylfosfaat
tributylfosfaat (dutch)
tributylfosfat
tributylphosphat
tributylphosphat (german)
Tributylphospate
n-tributyl phosphate
phosphoric acid,tributyl ester
tributyl
tributyl phosphate(tbp)
tributylphosphate
tris(1-butyl)phosphate
展开更多英文名
性质描述: 无色液体。熔点-80℃以下。沸点289℃(分解),180-183℃(2.93kPa),143-145℃(1.07kPa)。相对密度0.9729(25/4℃),折光率1.4226。易溶于有机溶剂,微溶于水。
生产方法: 由正丁醇与三氯氧磷反应而得。原料消耗(kg/t)丁醇 1500三氯氧磷 770
用途: 用作硝酸纤维素、乙酸纤维素、氯化橡胶和聚氯乙烯的主增塑剂,也常用作涂料、粘合剂和油墨的溶剂、消泡剂、消静电剂,稀土元素的萃取剂。大鼠LD50为3000mg/kg。
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货号品牌产品名称规格包装、参考价格详情
767258MACKLIN磷酸三丁酯标准溶液1000μg/mL in Isooctane289元/1ml;   展开
储存:2-8°C, 避光
767259MACKLIN磷酸三丁酯标准溶液1000μg/mL in Dichloromethane289元/1ml;   展开
储存:2-8°C, 避光
767260MACKLIN磷酸三丁酯标准溶液10μg/mL in Hexane260元/1ml;   展开
储存:2-8°C, 避光
767261MACKLIN磷酸三丁酯标准溶液20μg/mL in Hexane265元/1ml;   展开
储存:2-8°C, 避光
767262MACKLIN磷酸三丁酯标准溶液1000μg/mL in Hexane289元/1ml;   展开
储存:2-8°C, 避光
767263MACKLIN磷酸三丁酯标准溶液10μg/mL in Methanol260元/1ml;   展开
储存:2-8°C, 避光
767264MACKLIN磷酸三丁酯标准溶液100μg/mL in Methanol270元/1ml;   展开
储存:2-8°C, 避光
767265MACKLIN磷酸三丁酯标准溶液250μg/mL in Methanol275元/1ml;   展开
储存:2-8°C, 避光
767266MACKLIN磷酸三丁酯标准溶液1000μg/mL in Methanol289元/1ml;   展开
储存:2-8°C, 避光
T799396MACKLIN磷酸三丁酯Ph. Eur.899元/100ml;   2595元/500ml;   展开
储存:室温
状态:无色液体
T818519MACKLIN磷酸三丁酯Standard for GC,>99.5%49元/5ml;   展开
储存:室温
状态:无色液体
折射率:n20/D 1.424(lit.)
T818520MACKLIN磷酸三丁酯分析对照品, ≥99.5%(GC)123元/250mg;   展开
储存:室温, 密封
折射率:n20/D 1.424(lit.)
T818517MACKLIN磷酸三丁酯试剂级, 99%44元/100ml;   59元/250ml;   98元/500ml;   396元/2.5L;   692元/5L;   1189元/10L;   1035元/12X500ml;   展开
储存:室温
状态:无色液体
折射率:n20/D 1.424(lit.)
A16084Alfa AesarTri-n-butyl phosphate98%321元/250ml;   505元/1000ml;   2206元/5000ml;   展开

应用
Tri-n-butyl phosphate is used as a solvent for rare earth metals exaction and purification, and as a flame retardant component of aircraft hydraulic fluid. It is involved in the formation of stable hydrophobic complexes with some metals. It is also employed as a defoamer additive in cement casings for oil wells, as an anti-air entrainment additive for coatings and floor finishes and as a solvent in nuclear fuel processing. Further, it is used as a solvent in inks, synthetic resins, gums and adhesives. In addition, it is used as a plasticizer for cellulose esters like nitrocellulose and cellulose acetate.

备注
Incompatible with strong oxidizing agents, strong bases and alkali.

基本信息

MDL
MFCD00009436

EINECS
204-800-2

分子式
C12H27O4P

分子量
266.32

熔点
-80°

沸点
155-156°/10mm

闪点
152°(305°F)

密度
0.977

折射率
1.4240

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Miscible with diethyl ether, benzene, carbon disulfide and ethanol. Slightly miscible with water.

Beilstein
1710584

Merck
14,9618

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H351
Harmful if swallowed.Causes skin irritation.Suspected of causing cancer.

Precautionary Statements
P280h-P301+P310-P315
Wear protective gloves/clothing.IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.Get immediate medical advice/attention.

安全信息

危险类别
22-38-40
Harmful if swallowed.Irritating to skin.Limited evidence of a carcinogenic effect.

安全等级
36/37-46
Wear suitable protective clothing and gloves.If swallowed, seek medical advice immediately and show this container or label.

欧盟危险品标志

RTECS
TC7700000

TSCA

B404-500Alfa AesarN-BUTYL PHOSPHATE PURIFD 500ML623元/500ml;   展开

基本信息

Ref#
F52247

R10620Alfa AesarTributyl phosphate Standard solution100ppm210元/1ml;   展开

安全信息

危险等级
3

158615Sigma-AldrichTributyl phosphate97%747.72元/1 L;   1775.85元/2.5 L;   2145.6元/4 L;   展开

产品说明

一般描述

磷酸三丁酯 (TBP) 是一种有机磷化合物,广泛用作核燃料后处理的溶剂,用于从其他放射性核素中提取铀和钚。
磷酸三丁酯是一种内分泌干扰化合物。

应用

磷酸三丁酯的用途如下:

  • 溶剂中的溶剂-洗涤剂法灭活鸭乙型肝炎病毒模型中脂质包膜病毒的免疫球蛋白
  • 超临界 CO 2 萃取固体和液体中镧系元素时的配体
  • 金属络合物萃取剂

包装

1, 4 L in poly bottle

基本信息

线性分子式(CH3(CH2)3O)3PO
分子量266.31
Beilstein1710584
EC 号204-800-2
MDL编号MFCD00009436
PubChem化学物质编号24849766
NACRESNA.22

产品性质

质量水平300
蒸汽密度9.2 (vs air)
蒸汽压27 mmHg ( 178 ℃)
7.3 mmHg ( 150 ℃)
测定97%
形式liquid
自燃温度770 °F
折射率n20/D 1.424 (lit.)
bp180-183 ℃/22 mmHg (lit.)
mp−79 ℃ (lit.)
溶解性water: soluble 1ml in 165ml water
organic solvents: miscible
密度0.979 g/mL at 25 ℃ (lit.)
SMILES stringCCCCOP(=O)(OCCCC)OCCCC
InChI1S/C12H27O4P/c1-4-7-10-14-17(13,15-11-8-5-2)16-12-9-6-3/h4-12H2,1-3H3
InChI keySTCOOQWBFONSKY-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H302 - H315 - H351 - H412
预防措施声明P201 - P273 - P301 + P312 + P330 - P302 + P352 - P308 + P313
危险分类Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 2
闪点(F)294.8 °F
闪点(C)146 ℃
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
00675SupelcoTributyl phosphatefor extraction analysis, ≥99.0% (GC)2275.85元/500ML;   展开

基本信息

线性分子式(CH3(CH2)3O)3PO
分子量266.31
Beilstein1710584
EC 号204-800-2
MDL编号MFCD00009436
PubChem化学物质编号329747117
NACRESNA.21

产品性质

质量水平100
等级for extraction analysis
蒸汽密度9.2 (vs air)
蒸汽压27 mmHg ( 178 ℃)
7.3 mmHg ( 150 ℃)
测定≥99.0% (GC)
形式liquid
自燃温度770 °F
折射率n20/D 1.424 (lit.)
n20/D 1.424
bp180-183 ℃/22 mmHg (lit.)
mp−79 ℃ (lit.)
酸值<1
密度0.979 g/mL at 25 ℃ (lit.)
痕量阳离子Al: ≤10 mg/kg
Ba: ≤1 mg/kg
Bi: ≤1 mg/kg
Ca: ≤5 mg/kg
Cd: ≤0.5 mg/kg
Co: ≤0.5 mg/kg
Cr: ≤1 mg/kg
Cu: ≤0.5 mg/kg
Fe: ≤5 mg/kg
K: ≤5 mg/kg
Li: ≤1 mg/kg
Mg: ≤1 mg/kg
Mn: ≤0.5 mg/kg
Mo: ≤1 mg/kg
Na: ≤5 mg/kg
Ni: ≤0.5 mg/kg
Pb: ≤1 mg/kg
Sr: ≤1 mg/kg
Zn: ≤1 mg/kg
SMILES stringCCCCOP(=O)(OCCCC)OCCCC
InChI1S/C12H27O4P/c1-4-7-10-14-17(13,15-11-8-5-2)16-12-9-6-3/h4-12H2,1-3H3
InChI keySTCOOQWBFONSKY-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H302 - H315 - H351 - H412
预防措施声明P202 - P264 - P273 - P301 + P312 - P302 + P352 - P308 + P313
危险分类Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 2
闪点(F)293.0 °F - closed cup
闪点(C)145 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Y0000279Tri-n-butyl phosphateEuropean Pharmacopoeia (EP) Reference Standard2872.21元/ ;   展开

产品说明

一般描述

This product is provided as delivered and specified by the issuing Pharmacopoeia. All information provided in support of this product, including SDS and any product information leaflets have been developed and issued under the Authority of the Issuing Pharmacopoeia. For further information and support please go to the website of the issuing Pharmacopoeia.

包装

Unit quantity: 300 uL. Subject to change. The product is delivered as supplied by the issuing Pharmacopoeia. For the current unit quantity, please visit the EDQM reference substance catalogue.

注意

Please find SDS provided by EDQM here..

其他说明

Sales restrictions may apply.

基本信息

线性分子式(CH3(CH2)3O)3PO
分子量266.31
Beilstein1710584
MDL编号MFCD00009436
PubChem化学物质编号329830896
NACRESNA.24

产品性质

等级pharmaceutical primary standard
蒸汽密度9.2 (vs air)
蒸汽压27 mmHg ( 178 ℃)
7.3 mmHg ( 150 ℃)
自燃温度770 °F
manufacturer/tradenameEDQM
折射率n20/D 1.424 (lit.)
bp180-183 ℃/22 mmHg (lit.)
mp−79 ℃ (lit.)
密度0.979 g/mL at 25 ℃ (lit.)
application(s)cleaning products
cosmetics
food and beverages
personal care
pharmaceutical (small molecule)
格式neat
储存温度2-8℃
SMILES stringCCCCOP(=O)(OCCCC)OCCCC
InChI1S/C12H27O4P/c1-4-7-10-14-17(13,15-11-8-5-2)16-12-9-6-3/h4-12H2,1-3H3
InChI keySTCOOQWBFONSKY-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H302 - H315 - H351 - H412
预防措施声明P201 - P202 - P273 - P301 + P312 - P302 + P352 - P308 + P313
危险分类Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 2
闪点(F)293.0 °F - closed cup
闪点(C)145 ℃ - closed cup
PHR1205SupelcoTributyl phosphatePharmaceutical Secondary Standard; Certified Reference Material1359.83元/0.5 ML;   展开

产品说明

一般描述

Tributyl phosphate is an industrial chemical, commonly used as a plasticizer and a solvent for the extraction of uranium and plutonium in nuclear industry.
Certified pharmaceutical secondary standards for application in quality control provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to pharmacopeia primary standards.

应用

These Secondary Standards are qualified as Certified Reference Materials. These are suitable for use in several analytical applications including but not limited to pharma release testing, pharma method development for qualitative and quantitative analyses, food and beverage quality control testing, and other calibration requirements.

分析说明

These secondary standards offer multi-traceability to the USP, EP (PhEur) and BP primary standards, where they are available.

其他说明

This Certified Reference Material (CRM) is produced and certified in accordance with ISO 17034 and ISO/IEC 17025. All information regarding the use of this CRM can be found on the certificate of analysis.
Ion Mobility: TWCCSN2 value of 164.9 Å2 [M+H]+ and 182.2 Å2 [M+Na]+

The collision cross section (CCS) measurement was provided by Waters Corporation, using the SYNAPT XS mass spectrometer.
For a description and overview of how ion mobility enables the measurement of the CCS of an ion visit ims.waters.com.
Further information on the SYNAPT XS mass spectrometer can be found on the IMS microsite and product webpage.

TWCCS measurements are expected to be within 2% of this reference value.

P/N PHR1205 is part of the Waters Extractables & Leachables UNIFI scientific library which can be downloaded from Waters Marketplace.

附注

To see an example of a Certificate of Analysis for this material enter P500205 in the slot below. This is an example certificate only and may not be the lot that you receive.

基本信息

线性分子式(CH3(CH2)3O)3PO
分子量266.31
Beilstein1710584
EC 号204-800-2
MDL编号MFCD00009436
PubChem化学物质编号329823212
NACRESNA.24

产品性质

质量水平300
等级certified reference material
pharmaceutical secondary standard
蒸汽密度9.2 (vs air)
蒸汽压27 mmHg ( 178 ℃)
7.3 mmHg ( 150 ℃)
CofAcurrent certificate can be downloaded
自燃温度770 °F
technique(s)HPLC: suitable
gas chromatography (GC): suitable
折射率n20/D 1.424 (lit.)
bp180-183 ℃/22 mmHg (lit.)
mp−79 ℃ (lit.)
密度0.979 g/mL at 25 ℃ (lit.)
application(s)cleaning products
cosmetics
food and beverages
personal care
pharmaceutical (small molecule)
格式neat
药典可追溯性traceable to PhEur Y0000279
储存温度2-30℃
SMILES stringCCCCOP(=O)(OCCCC)OCCCC
InChI1S/C12H27O4P/c1-4-7-10-14-17(13,15-11-8-5-2)16-12-9-6-3/h4-12H2,1-3H3
InChI keySTCOOQWBFONSKY-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H302 - H315 - H351 - H412
预防措施声明P201 - P273 - P301 + P312 + P330 - P302 + P352 - P308 + P313
危险分类Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 2
闪点(F)294.8 °F
闪点(C)146 ℃
240494Sigma-AldrichTributyl phosphate≥99%342.68元/5 ML;   923.2元/100 ML;   展开

产品说明

一般描述

磷酸三丁酯的微生物降解是使用从土壤中分离得到的 肺炎克雷伯菌 S3 进行的 。利用轻小角中子散射 (SANS) 研究了 TBP 在 L64-普郎尼克类水溶液中的增溶行为 。

应用

磷酸三丁酯 (TBP) 用作消泡剂和/或增塑剂,用于燃料后处理和提取 。

包装

5, 100 mL in glass bottle

基本信息

线性分子式(CH3(CH2)3O)3PO
分子量266.31
Beilstein1710584
EC 号204-800-2
MDL编号MFCD00009436
PubChem化学物质编号329752548

产品性质

蒸汽密度9.2 (vs air)
质量水平200
蒸汽压27 mmHg ( 178 ℃)
7.3 mmHg ( 150 ℃)
测定≥99%
形式liquid
自燃温度770 °F
折射率n20/D 1.424 (lit.)
bp180-183 ℃/22 mmHg (lit.)
mp−79 ℃ (lit.)
溶解性organic solvents: miscible
water: soluble (1mL in 165mL)
密度0.979 g/mL at 25 ℃ (lit.)
SMILES stringCCCCOP(=O)(OCCCC)OCCCC
InChI1S/C12H27O4P/c1-4-7-10-14-17(13,15-11-8-5-2)16-12-9-6-3/h4-12H2,1-3H3
InChI keySTCOOQWBFONSKY-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H302 - H315 - H351 - H412
预防措施声明P201 - P273 - P301 + P312 + P330 - P302 + P352 - P308 + P313
危险分类Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 2
闪点(F)294.8 °F
闪点(C)146 ℃
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
90820Sigma-AldrichTributyl phosphatepuriss., ≥99.0% (GC)1022.04元/100 ML;   3055.49元/500 ML;   展开

基本信息

线性分子式(CH3(CH2)3O)3PO
分子量266.31
Beilstein1710584
EC 号204-800-2
MDL编号MFCD00009436
PubChem化学物质编号329769952
NACRESNA.22

产品性质

蒸汽密度9.2 (vs air)
质量水平200
蒸汽压27 mmHg ( 178 ℃)
7.3 mmHg ( 150 ℃)
等级puriss.
测定≥99.0% (GC)
形式liquid
自燃温度770 °F
折射率n20/D 1.424 (lit.)
bp180-183 ℃/22 mmHg (lit.)
mp−79 ℃ (lit.)
密度0.979 g/mL at 25 ℃ (lit.)
SMILES stringCCCCOP(=O)(OCCCC)OCCCC
InChI1S/C12H27O4P/c1-4-7-10-14-17(13,15-11-8-5-2)16-12-9-6-3/h4-12H2,1-3H3
InChI keySTCOOQWBFONSKY-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H302 - H315 - H351 - H412
预防措施声明P201 - P273 - P301 + P312 + P330 - P302 + P352 - P308 + P313
危险分类Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 2
闪点(F)294.8 °F
闪点(C)146 ℃
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
8.18604Sigma-AldrichTributyl phosphatefor synthesis350.27元/500 ML;   579.32元/1 L;   1350.99元/2.5 L;   展开

产品说明

分析说明

Assay (GC, area%): ≥ 99.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.976 - 0.978
Identity (IR): passes test

基本信息

线性分子式(CH3(CH2)3O)3PO
分子量266.31
Beilstein1710584
MDL编号MFCD00009436
EC索引号204-800-2

产品性质

蒸汽密度9.2 (vs air)
质量水平200
蒸汽压27 mmHg ( 178 ℃)
7.3 mmHg ( 150 ℃)
测定≥99.0% (GC)
形式liquid
自燃温度770 °F
效能1550 mg/kg LD50, oral (Rat)
>3100 mg/kg LD50, skin (Rabbit)
折射率n20/D 1.424 (lit.)
bp180-183 ℃/22 mmHg (lit.)
mp−79 ℃ (lit.)
转变温度flash point 146 ℃
溶解性 6 g/L
密度0.979 g/mL at 25 ℃ (lit.)
储存温度2-30℃
SMILES stringCCCCOP(=O)(OCCCC)OCCCC
InChI1S/C12H27O4P/c1-4-7-10-14-17(13,15-11-8-5-2)16-12-9-6-3/h4-12H2,1-3H3
InChI keySTCOOQWBFONSKY-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H302 - H315 - H351 - H412
预防措施声明P201 - P202 - P273 - P301 + P312 - P302 + P352 - P308 + P313
危险分类Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 2
闪点(F)294.8 °F
闪点(C)146 ℃
212178AmethystTributyl phosphate99%, 用于分析84元/500ML;   302元/2.5L;   543元/5L;   展开

基本信息

分子式C12H27O4P
分子量266.32
熔点-79
沸点180-183
闪点145
密度0.979
折光率(n20D)1.4240
MDL编码MFCD00009436
Beilstein1710584
EINECS 编号204-800-2

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H351
防范说明P281
WGK2
RTECSTC7700000
TSCA
PLAS-PL-068NAccuStandardTributylphosphate772元/50mg;   展开
Tributylphosphate磷酸三丁酯126-73-8
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9