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CAS: 126-33-0
分子式: C4H8O2S
分子量: 120.17
沸点: 285℃
熔点: 27.4-27.8℃
中文名称: 
环丁砜(四氢噻酚砜)
环丁砜
1,1-二氧四氢噻吩
四亚甲基砜
四氢噻吩砜
二氧化噻吩烷
英文名称: 
tetrahydrothiophene-S,S-dioxide
tetrahydro-thiophene-1,1-dioxide
thiophene,tetrahydro-,1,1-dioxide
thiolane 1,1-dioxide
Tetrahydrothiophen-1,1-dioxide
Tetrahydro-thiophene 1,1-dioxide
Tetramethylene sulfone
Sulfolane
Thiophene, tetrahydro-, 1,1-dioxide
1,1-dioxidetetrahydrothiofuran
1,1-dioxidetetrahydrothiophene
1,1-dioxothiolan
2,3,4,5-tetrahydrothiophene-1,1-dioxide
bondelane a
bondolane a
cyclic tetramethylene sulfone
cyclotetramethylene sulfone
dihydrobutadiene sulphone
dioxothiolan
sulfalone
sulfolan
sulpholane
sulphoxaline
tetrahydrothiofen-1,1-dioxid
tetrahydrothiophene 1,1-dioxide
tetrahydrothiophene 1-dioxide
tetrahydrothiophene dioxide
thiacyclopentane dioxide
thiocyclopentane-1,1-dioxide
thiolane-1,1-dioxide
thiophan sulfone
thiophane dioxide
5-sulfoisophthalic acid,lithium salt sulfolane
Tetrahydrothiophene-1,1-dioxide
Tetramethy-lene aulphone
Thiophane sulfone
展开更多英文名
性质描述: 无色无味固体,在27-28℃时,熔化成无色透明液体。凝固点(99.8%浓度)26℃,沸点287℃,153-154℃(2.4kPa),相对密度1.261(30/4℃),折射率1.481。闪点(开杯)176.7℃,粘度10.34mPa·s(30℃)。可与水,混合二甲苯、甲硫醇、乙硫醇混溶,也可溶于芳烃和醇类,对石蜡烃和烯烃溶解度很小。具有很好的化学和热稳定性。
生产方法: 以丁二烯,二氧化硫为原料,在对苯二酚的甲醇溶剂存在下,于耐压反应器内加热(100-110℃)合成为环丁烯砜甲醇溶液,分馏后,精环丁烯砜在含镍催化剂存在下加氢转化为环丁砜,再经气液分离,分馏后得成品。原料消耗定额:丁二烯(>99%)654kg/t、二氧化硫(>97%)909kg/t、铝镍催化剂(Ni45-50%)71kg/t、液体氢氧化钠110kg/t。
用途: 溶解力强、选择性好的极性溶剂,大部分有机化合物与聚合物能溶于环丁砜,或与它混溶。主要用作芳烃抽提的萃取剂,聚合物纺丝或浇膜溶剂,天然气及合成气、炼厂气的净化、合成气的净化脱硫,以及作为橡胶、塑料的溶济等。此外,还可用于纺织印染工业作为印染助剂,可使色彩鲜明、光亮。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
S750081MACKLIN环丁砜99.9%179元/100ml;   628元/500ml;   展开
储存:室温
折射率:n20/D 1.484(lit.)
S817951MACKLIN环丁砜试剂级, 98%59元/250ml;   141元/1L;   518元/5L;   展开
储存:室温
状态:白色固体,液体或半固态
折射率:n20/D 1.484(lit.)
S817950MACKLIN环丁砜>99.0%(GC)37元/100g;   95元/500g;   392元/2.5kg;   1026元/10kg;   1133元/12X500g;   展开
储存:室温
状态:白色到黄色固体,无色到黄色液体
折射率:n20/D 1.484(lit.)
S817952MACKLIN环丁砜Standard for GC,≥99.5%(GC)52元/5ml;   展开
储存:室温
状态:白色到黄色固体;无色到黄色液体
折射率:n20/D 1.484(lit.)
T0115TCITetrahydrothiophene 1,1-Dioxide>99.0%(GC)170元/25G;   460元/500G;   展开

基本信息

纯度/分析方法>99.0%(GC)
分子式/分子量C4H8O2S = 120.17
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN107765
PubChem物质ID87576123
SDBS (AIST Spectral DB)749
Merck Index (14)8955
MDL编号MFCD00005484

技术规格

AppearanceWhite or Colorless to Light yellow powder to lump to clear liquid
Purity(GC)min. 99.0 %

物性(参考值)

熔点25 ℃
沸点285 ℃
水溶性完全混溶
溶解性(可与之混溶)甲苯,醇,丙酮

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H320 : 造成眼刺激。
H361 : 怀疑对生育能力或胎儿造成伤害。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P405 : 存放处须加锁。

相关法规

RTECS#XN0700000
169719J&KSulfolane99%66元/25ML;   188元/250ML;   531元/1L;   展开

基本信息

分子式C4H8O2S
分子量120.17
熔点20-26
沸点285
闪点177
密度1.261
折光率(n20D)1.4840
MDL编码MFCD00005484
Beilstein107765
Merck14,8955
EINECS 编号204-783-1

安全信息

图形或危害标志
提示语Warning
危险说明H302
防范说明P260
P262
WGK1
RTECSXN0700000
TSCA
H32505Alfa AesarSulfolane80% w/w aq. soln.686元/500ml;   2300元/2500ml;   展开

应用
Sulfolane is used in the chemical industry as a solvent for extractive distillation and chemical reactions. It is used to separate aromatic hydrocarbons (benzene, toluene and xylenes), to separate n-propyl alcohol and sec-butyl alcohol. It is also used to purify natural gas streams and for fractionation of fatty acids into saturated and unsaturated components and as a reaction solvent for the preparation of aromatic sulfonic acids, pyridines, isocyanates and pharmaceuticals. It can also be involved in the halogen exchange process and polymerization process. It is used as a plasticizer and curing agent.

备注
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00005484

EINECS
204-783-1

分子式
C4H8O2S

分子量
120.17

熔点
0-5°

密度
1.212

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Fully miscible in water.

Beilstein
107765

Merck
14,8955

GHS危害和防范说明

GHS符号

Hazard Statements
H302
Harmful if swallowed.

Precautionary Statements
P262-P501a
Do not get in eyes, on skin, or on clothing.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22
Harmful if swallowed.

安全等级
25
Avoid contact with eyes.

欧盟危险品标志

RTECS
XN0700000

TSCA

A13466Alfa AesarSulfolane99%503元/250g;   1420元/1000g;   5223元/5000g;   展开

应用
Sulfolane is used as an industrial solvent utilized for the extraction of aromatic hydrocarbons from hydrocarbon mixtures and to purify natural gas. Further, it is used in refineries and the petrochemical industry.

备注
Miscible with water, acetone, tolueneIncompatible with strong oxidizing agents.

基本信息

MDL
MFCD00005484

EINECS
204-783-1

分子式
C4H8O2S

分子量
120.17

熔点
25-28°

沸点
285°

闪点
166°(330°F)

密度
1.261

折射率
1.4825

灵敏度
Hygroscopic. Ambient temperatures.

形态
Low melting solid

溶解性
Miscible with alcohol, water, acetone, toluene and dilute mineral acids. Slightly miscible with octanes, olefins and naphthenes.

Beilstein
107765

Merck
14,8955

GHS危害和防范说明

GHS符号

Hazard Statements
H302
Harmful if swallowed.

Precautionary Statements
P262-P308+P313-P330
Do not get in eyes, on skin, or on clothing.IF exposed or concerned: Get medical advice/attention.Rinse mouth.

安全信息

危险类别
22
Harmful if swallowed.

安全等级
25
Avoid contact with eyes.

欧盟危险品标志

RTECS
XN0700000

TSCA

1601769USPResidual Solvent Class 2-SulfolaneUnited States Pharmacopeia (USP) Reference Standard3390元/3 X 1.2 ML;   展开

产品说明

一般描述

This product is provided as delivered and specified by the issuing Pharmacopoeia. All information provided in support of this product, including SDS and any product information leaflets have been developed and issued under the Authority of the issuing Pharmacopoeia.
For further information and support please go to the website of the issuing Pharmacopoeia.

分析说明

These products are for test and assay use only. They are not meant for administration to humans or animals and cannot be used to diagnose, treat, or cure diseases of any kind.  ​

其他说明

USP issued SDS can be found here.
Sales restrictions may apply.

基本信息

经验(实验)分子式C4H8O2S
分子量120.17
NACRESNA.24

产品性质

等级pharmaceutical primary standard
manufacturer/tradenameUSP
application(s)pharmaceutical (small molecule)
格式neat
InChI1S/C4H8O2S/c5-7(6)3-1-2-4-7/h1-4H2
InChI keyHXJUTPCZVOIRIF-UHFFFAOYSA-N

安全信息

储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)188.6 °F
闪点(C)87.00 ℃
T22209Sigma-AldrichSulfolane99%167.67元/5 G;   332.25元/100 G;   776.49元/500 G;   3738.59元/2.5 KG;   展开

产品说明

应用

环丁砜是一种极性非质子溶剂,可用于纤维素的完全热解,而无需任何聚合或碳化副反应。环丁砜与均三甲苯结合,可用作从 L-天冬氨酸合成聚(琥珀酰亚胺)(PSI)的溶剂。它还可以用作合成氯封端的聚醚砜低聚物的溶剂,这是一种用于尼龙 6-聚醚砜(PES)-尼龙 6 嵌段共聚物合成的聚合物活化剂。

包装

5, 100, 500 g in glass bottle
2.5 kg in glass bottle

基本信息

经验(实验)分子式C4H8O2S
分子量120.17
Beilstein107765
EC 号204-783-1
MDL编号MFCD00005484
PubChem化学物质编号24900023
NACRESNA.22

产品性质

质量水平200
蒸汽密度4.2 (vs air)
蒸汽压0.01 mmHg ( 20 ℃)
测定99%
折射率n20/D 1.484 (lit.)
bp104 ℃/0.2 mmHg (lit.)
285 ℃ (lit.)
mp20-26 ℃ (lit.)
密度1.261 g/mL at 25 ℃ (lit.)
SMILES stringO=S1(=O)CCCC1
InChI1S/C4H8O2S/c5-7(6)3-1-2-4-7/h1-4H2
InChI keyHXJUTPCZVOIRIF-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Danger
危险声明H302 - H360FD
预防措施声明P202 - P264 - P270 - P280 - P301 + P312 - P308 + P313
危险分类Acute Tox. 4 Oral - Repr. 1B
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 1
闪点(F)350.6 °F - closed cup
闪点(C)177 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
8.07993Sigma-AldrichSulfolanefor synthesis255.17元/250 ML;   361.86元/1 L;   展开

产品说明

分析说明

含量(GC, area%): ≥ 99.0 %(a/a)
水(K. F.): ≤ 0.20 %
鉴定(IR):通过测试
由于其特定的熔化范围,产物可以是固体、液体、固化熔体或过冷熔体。

基本信息

经验(实验)分子式C4H8O2S
分子量120.17
MDL编号MFCD00005484
EC索引号204-783-1

产品性质

质量水平200
蒸汽压0.035 hPa ( 30 ℃)
测定≥99.0% (GC)
形式solid
效能2006 mg/kg LD50, oral (Rat)
>2000 mg/kg LD50, skin (Rat)
bp285 ℃/1013 hPa
mp26 ℃
转变温度flash point 177 ℃
溶解性soluble ≥100 g/L
密度1.26 g/cm3 at 30 ℃
储存温度2-30℃
InChI1S/C4H8O2S/c5-7(6)3-1-2-4-7/h1-4H2
InChI keyHXJUTPCZVOIRIF-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Danger
危险声明H302 - H360FD
预防措施声明P202 - P264 - P270 - P280 - P301 + P312 - P308 + P313
危险分类Acute Tox. 4 Oral - Repr. 1B
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 1
闪点(F)350.6 °F - closed cup
闪点(C)177 ℃ - closed cup
88965SupelcoSulfolaneanalytical standard621.45元/5 ML;   展开

产品说明

一般描述

Sulfolane is widely used in combination with diisopropanolamine in the sulfinol process of removal of toxic levels of hydrogen sulfide and carbonyl sulfide from raw natural gas condensate. It is also used as an industrial solvent for photographic chemicals, polymer, and petrochemical industries.
Sulfolane is an aprotic polar solvent, used in the separation of aromatic hydrocarbons from aliphatic hydrocarbons.

应用

Sulfolane may be used as an analytical reference standard for the quantification of the analyte in groundwater samples using gas chromatography-mass spectrometry technique.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

基本信息

经验(实验)分子式C4H8O2S
分子量120.17
Beilstein107765
EC 号204-783-1
MDL编号MFCD00005484
PubChem化学物质编号329769680
NACRESNA.24

产品性质

质量水平100
等级analytical standard
蒸汽密度4.2 (vs air)
蒸汽压0.01 mmHg ( 20 ℃)
测定≥99.8% (GC)
保质期limited shelf life, expiry date on the label
technique(s)HPLC: suitable
gas chromatography (GC): suitable
折射率n20/D 1.484 (lit.)
n20/D 1.485
bp104 ℃/0.2 mmHg (lit.)
285 ℃ (lit.)
mp20-26 ℃ (lit.)
密度1.261 g/mL at 25 ℃ (lit.)
application(s)environmental
格式neat
SMILES stringO=S1(=O)CCCC1
InChI1S/C4H8O2S/c5-7(6)3-1-2-4-7/h1-4H2
InChI keyHXJUTPCZVOIRIF-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Danger
危险声明H302 - H360FD
预防措施声明P202 - P264 - P270 - P280 - P301 + P312 - P308 + P313
危险分类Acute Tox. 4 Oral - Repr. 1B
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 1
闪点(F)350.6 °F - closed cup
闪点(C)177 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
UOP-M-660-10X-PAKAccuStandardUOP Method 660 Standard,10% in Water10% in Water665元/5×1mL;   展开
UOP-M-660-PAKAccuStandardUOP Method 660 Standard,1% in Water1% in Water950元/5×1mL;   展开
UOP-M-660-0.1X-PAKAccuStandardUOP Method 660 Standard,0.1% w/w in Water0.1% w/w in Water950元/5×1mL;   展开
044698FluorochemSulfolane99%220元/25g;   440元/100g;   660元/500g;   展开

基本信息

CAS Number126-33-0
MDL NumberMFCD00005484
Boiling Point285℃
Melting Point20-26℃
Density1.261

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
防范说明 P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P501: Dispose of contents/container to in accordance with local regulation .
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