CAS 1258327-07-9; (11as)-3,7-双[3,5-双(三氟甲基)苯基]-10,11,12,13-四氢-5-羟基-5-氧化物二茚并[7,1-de:1',7'-fg][1,3,2]二氧磷杂八环; (11as)-3,7-bis[3,5-bis(trifluoromethyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin

CAS:

1258327-07-9

分子式:

C₃₃H₁₉F₁₂O₄P

分子量:

738.5

熔点:

>300°C

中文名称:

(11as)-3,7-双[3,5-双(三氟甲基)苯基]-10,11,12,13-四氢-5-羟基-5-氧化物二茚并[7,1-de:1',7'-fg][1,3,2]二氧磷杂八环

英文名称:

(11as)-3,7-bis[3,5-bis(trifluoromethyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin

推荐供应商

货号	品牌	产品名称	规格	包装、参考价格
S854258	MACKLIN	(11aS)-3,7-Bis[3,5-bis(trifluoromethyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin	≥98%,99%e.e.	453元/5mg; 1269元/25mg; 3688元/100mg;	咨询
储存：室温,干燥状态：白色粉末
15-0528	Strem	(11aS)-3,7-Bis[3,5-bis(trifluoromethyl)phenyl]-10,11,12,13-tetrahydro-5-hydroxy-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin	min. 98%	3690元/25mg; 12540元/100mg;	咨询
Technical Notes: 1. Org anocatalytic asymmetric multicomponent reactions of aromatic aldehydes and anilines with ß -ketoesters: facile and atom- economicalaccoss tochiral tetrahvdroovridinos 2.Pd(O)- catalyzed tandem deprotection/cyclization of tetrahydro -ß carbolines on allenes: application to the synthesis of indolo2, 3-aquinolizidines . 3.Enantios elective synthesis of benzazepinoindoles bearing trifluoromethylated quaternary stereocenters, catalyzed by chiral spirocyclic phos phoric acids. References: 1. Chem Commun., 2013, 49, 1401. 2.Org. Lett., 2014, 16, 1924. 3.Chem Commun., 2014, 50, 7538.