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CAS: 124-83-4
分子式: C10H16O4
分子量: 200.23
熔点: 183-187℃
中文名称: 
(1R,3S)-(+)-樟脑酸
D-樟脑酸
英文名称: 
(1R,3S)-(+)-camphoric acid
2,2-trimethyl-3-cyclopentanedicarboxylic aci (1 theta-cis)-1
d(+)-camphoric acid
D-Camphoric acid
(+)-Camphoric acid
(1R,3S)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid
D-(+)-Camphoric acid
Cis-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid
性质描述: 该产品为白色结晶性粉末,熔点183-186℃,相对密度1.186。微溶于冷水,溶于热水,乙醇,乙醚,三氯甲烷和甘油中,不溶于氯仿。
生产方法: 由樟脑用硝酸氧化而制得。
用途: 医药化工,用于制备止盗汗,也用于制赛璐珞。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
C804851MACKLIN(+)-樟脑酸99%37元/5g;   165元/25g;   590元/100g;   2785元/500g;   展开
储存:室温
状态:白色到浅黄色粉末
C0012TCI(+)-Camphoric Acid>98.0%(GC)(T)450元/25G;   1570元/100G;   4990元/500G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C10H16O4 = 200.23
外观与形状(20℃)固体
Reaxys-RN2050202
PubChem物质ID87565223
SDBS (AIST Spectral DB)6794
Merck Index (14)1733
MDL编号MFCD00001375

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Purity(Neutralization titration)min. 98.0 %
Melting point181.0 to 188.0 ℃
Specific rotation [a]20/D+43.0 to +49.0 deg(C=5, EtOH)
Solubility in Methanolalmost transparency

物性(参考值)

熔点187 ℃
比旋光度 [α]D46° (C=5,EtOH)

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
355552J&KD-(+)-Camphoric acid99%64元/5G;   145元/25G;   474元/100G;   1627元/500G;   展开

基本信息

分子式C10H16O4
分子量200.23
熔点183-186
比旋光度([α]20D)+44° to + 48° (C=1, EtOH)
MDL编码MFCD00001375
Beilstein2050204
Merck14,1733
EINECS 编号204-715-0

安全信息

图形或危害标志
提示语Warning
危险说明H302
防范说明P262
WGK2
TSCA
B23106Alfa Aesar(1R,3S)-(+)-Camphoric acid98+%609元/25g;   1122元/100g;   5584元/500g;   展开

基本信息

MDL
MFCD00001375

EINECS
204-715-0

分子式
C10H16O4

分子量
200.23

熔点
183-188°

形态
Crystalline powder

Beilstein
2050204

Merck
14,1733

安全信息

TSCA

C10820Alfa AesarD(+)-Camphoric acid99%382元/5g;   1678元/100g;   7794元/500g;   展开

基本信息

Ref#
10820

MDL
1375

分子式
C10 H16 O4

分子量
200.23

C409Sigma-Aldrich(1R,3S)-(+)-Camphoric acid99%171.99元/5 G;   745.02元/100 G;   展开

产品说明

一般描述

樟脑酸是一种二酸,一般通过萜烯(+)-樟脑氧化制备。它可用作一些有机反应中的手性诱导剂。

应用

(1R,3S)-(+)-樟脑酸可用于制备(1R,2S,3R,5S)-2,3-二苄基-1,8,8-三甲基-3-硫杂双环[3.2.1] 辛烷高氯酸盐。它与吡啶(py)或吡啶/甲醇(MeOH)中的硝酸铀酰反应形成新型铀酰-有机组合。

包装

5, 100 g in poly bottle

基本信息

经验(实验)分子式C10H16O4
分子量200.23
Beilstein2050204
EC 号204-715-0
MDL编号MFCD00001375
PubChem化学物质编号24892576
NACRESNA.22

产品性质

质量水平200
测定99%
旋光性[α]20/D 46°, c = 1 in ethanol
mp183-186 ℃ (lit.)
SMILES stringCC1(C)[C@H](CC[C@@]1(C)C(O)=O)C(O)=O
InChI1S/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)/t6-,10+/m1/s1
InChI keyLSPHULWDVZXLIL-LDWIPMOCSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
危险分类Acute Tox. 4 Oral
储存分类代码13 - Non Combustible Solids
WGKWGK 2
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
225471FluorochemD-(+)-Camphoric acid95%220元/10g;   396元/25g;   968元/100g;   展开

基本信息

CAS Number124-83-4
MDL NumberMFCD00001375
Melting Point183 - 186 ℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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