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CAS: 124-42-5
分子式: C2H7ClN2
分子量: 94.54
熔点: 165-170℃
中文名称: 
盐酸乙脒
乙脒盐酸盐
英文名称: 
ethylamidine hydrochloride
Acetamidinium chloride
Ethanimidamide,monohydrochloride
ethanimidamide, monohydrochloride
acetamidine hydrochloride
Ethanimidamide hydrochloride
Ethaneamidine hydrochloride
Ethyl amidine hydrochloride
性质描述: 白色长棱柱状结晶。熔点177-178℃。易溶于水,不溶于丙酮、乙醚。极易吸潮。有异臭味。
生产方法: 由乙腈、盐酸和甲醇经加成、氨化而得。使甲醇在湍球塔内循环,压力小于26.6kPa,冷却下通入干燥的氯化氢,制成浓度为45%的氯化氢甲醇溶液。然后投入反应罐,搅拌冷却至10-5℃,滴加乙腈,并于15-20℃保温6h,得亚胺基甲乙醚盐酸盐。放入预先配制好的13%氨甲醇溶液中,在0-40℃氨解,保持pH值7-8,搅拌2-3h,降温至30℃以下,离心分离滤出氯化铵。滤液回收甲醇,冷却过滤得成品。重量投料比:乙腈:氯化氢甲醇溶液(45%):氨:甲醇=1:3:1.05:4.3。收率82%-85%。
用途: 盐酸乙脒是医药中间体,用作生产维生素B1。
推荐供应商
货号品牌产品名称规格包装、参考价格
A800552MACKLIN乙脒盐酸盐97%33元/25g;   58元/100g;   158元/500g;   582元/2.5kg;   咨询
储存:室温
状态:白色晶体
A0008TCIAcetamidine Hydrochloride>95.0%(T)205元/25G;   1290元/500G;   咨询

基本信息

纯度/分析方法>95.0%(T)
分子式/分子量C2H6N2·HCl = 94.54
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN3591762
PubChem物质ID87561714
SDBS (AIST Spectral DB)3657
Merck Index (14)44
MDL编号MFCD00013016

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Nonaqueous Titration)min. 95.0 %(after deducting NH4Cl)
Purity(Argentometric Titration)min. 95.0 %(after deducting NH4Cl)
Melting point166.0 to 176.0 ℃
Ammonium chloridemax. 5.0 %

物性(参考值)

熔点168 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
490229J&KAcetamidine Hydrochloride97%103元/25G;   342元/100G;   1216元/500G;   咨询

基本信息

分子式C2H6N2·HCl
分子量94.54
熔点165-170
MDL编码MFCD00013016
Beilstein3591762
EINECS 编号204-700-9

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
防范说明P280
P302+P352
P305+P351+P338
WGK3
TSCA
A16091Alfa AesarAcetamidine Hydrochloride97%372元/25g;   752元/100g;   4032元/500g;   咨询

应用
Acetamidine hydrochloride was used in the preparation of decarboxyectoine. It was also used in the synthesis of ethyl 4-(4-hydroxyphenyl)methylidene-2-methyl-5-oxo-1-imidazolacetate.

备注
It is hygroscopic. Store away from oxidizing agents.

基本信息

MDL
MFCD00013016

EINECS
204-700-9

分子式
C2H6N2?HCl

分子量
94.54

熔点
168-175°

灵敏度
Hygroscopic. Ambient temperatures.

形态
Crystalline solid

溶解性
Soluble in water.

Beilstein
3591762

Merck
14,44

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

C17021Alfa AesarAcetamidine Hydrochloride98+%616元/100g;   438元/10g;   2075元/500g;   咨询

基本信息

Ref#
17021

MDL
13016

分子式
C2 H6 N2 . Cl H

分子量
94.54

159158Sigma-AldrichAcetamidine Hydrochloride95%819.17元/100 G;   2177.45元/500 G;   咨询

产品说明

一般描述

乙脒盐酸盐是一种脒盐,已经研究了它向2,4,6-三甲基 -对称-三嗪的转化。

应用

乙脒盐酸盐被用于制备脱羧基嘌呤。 它还被用于合成4-(4-羟基苯基)亚甲基-2-甲基-5-氧代-1-咪唑乙酸乙酯。

包装

100, 500 g in poly bottle

基本信息

线性分子式CH3C(=NH)NH2 · HCl
分子量94.54
Beilstein3591762
EC 号204-700-9
MDL编号MFCD00013016
PubChem化学物质编号24849795
NACRESNA.22

产品性质

质量水平100
测定95%
mp165-170 ℃ (lit.)
SMILES stringCl[H].CC(N)=N
InChI1S/C2H6N2.ClH/c1-2(3)4;/h1H3,(H3,3,4);1H
InChI keyWCQOBLXWLRDEQA-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319
预防措施声明P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
危险分类Eye Irrit. 2 - Skin Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
021800FluorochemAcetamidine Hydrochloride95%220元/25g;   1782元/500g;   2618元/1kg;   咨询

基本信息

CAS Number124-42-5
MDL NumberMFCD00013016
Melting Point165-170℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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