CAS 12354-85-7; Dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

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货号

品牌

产品名称

规格

包装、参考价格

P817096

MACKLIN

二氯(五甲基环戊二烯基)合铑(III)二聚体

99％

959元/250mg; 3610元/1g; 8168元/5g;

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储存：室温,干燥,密封
状态：橙色到棕色到非常暗红色粉末或晶体

P1788

TCI

(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer

>96.0%(T)

1390元/200MG; 4680元/1G;

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基本信息

纯度/分析方法	>96.0%(T)
分子式/分子量	C₂₀H₃₀Cl₄Rh₂ = 618.07
外观与形状(20℃)	固体
PubChem物质ID	87560640
MDL编号	MFCD00061552

技术规格

Appearance	Light yellow to Brown powder to crystal
Purity(Argentometric Titration)	min. 96.0 %

安全信息

图形或危害标志
信号词	警告
危险性说明	H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P302 + P352 + P312 : 如皮肤沾染：用水充分清洗。如感觉不适，呼叫急救中心/医生。 P304 + P340 + P312 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。

45-0195

Strem

Dichloro(pentamethylcyclopentadienyl)rhodium(III) Dimer

99%

1230元/100mg; 4785元/500mg; 14370元/2g;

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Technical Notes:

1.Catalyst used in the functionalization of acetanilides under s olventless conditions in a ball mill.

2.Rhodium- catalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.

3.Catalyst used in the asymmetric transfer hydrogenation of imines in water.

4.Facile rhodium-catalyzed synthesis of fluorinated pyridines .

5.Rhodium-catalyzed alkylation of azobenzenes with allyl acetates .

033657

Alfa Aesar

Dichloro(pentamethylcyclopentadienyl)rhodium(III) Dimer

99%

0元/250mg; 0元/1g;

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应用
Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.

备注
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00061552

EINECS
625-704-0

分子式
C₁₀H₁₅Cl₄Rh₂

分子量
618.08

熔点
>300°

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H315-H319-H335
Toxic if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
否

338370

Sigma-Aldrich

Pentamethylcyclopentadienylrhodium(III) chloride dimer

97%

3186.86元/250 MG; 9478.9元/1 G;

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产品说明

应用

Umicore预催化剂，用于不对称和交叉偶联催化

用作以下反应的催化剂：

氧化烯化反应
仲醇的C-C键裂解
苯酚衍生物的邻位C-H烯化反应
吡啶的氧化环化反应
苯甲酰胺与醛通过sp² C-H 键的直接官能化发生氧化邻位酰化反应
酰胺化反应
还原性烷基化反应

五甲基环戊二烯基铑 (III) 氯化物二聚体可作为催化剂用于：

氧化烯化反应、
仲醇的C-C 键裂解、
苯酚衍生物的邻位 C-H 烯化反应、
吡啶的氧化环化反应、
苯甲酰胺与醛通过 sp² C-H 键
的直接官能团化反应与醛类发生氧化邻位酰化反应、
还原烷基化反应

包装

1 g in glass bottle
250 mg in glass bottle

基本信息

线性分子式	[Rh(C₅Me₅)Cl₂]₂
分子量	618.08
MDL编号	MFCD00061552
PubChem化学物质编号	24860540

产品性质

质量水平	100
测定	97%
reaction suitability	core: rhodium reagent type: catalyst reaction type: C-Mannosylation
SMILES string	Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI	1S/2C10H15.4ClH.2Rh/c21-6-7(2)9(4)10(5)8(6)3;;;;;;/h21-5H3;41H;;/q;;;;;;2+2/p-4
InChI key	QNIVKTTWBMFSBR-UHFFFAOYSA-J

安全信息

象形图
警示用语：	Warning
危险声明	H302 + H312 + H332 - H315
预防措施声明	P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
危险分类	Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Skin Irrit. 2
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

686891

Sigma-Aldrich

Chiralyst P618

Umicore

2906.43元/500 MG; 9636.75元/2 G;

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产品说明

应用

五甲基环戊二烯铑(III)氯化物可用作以下反应的催化剂：

通过2-芳氧吡啶的双C-H键功能化合成多芳基取代萘酚。
偶氮化合物的区域选择性C-N键的形成，其中叠氮化物作为氮源。
N-苯甲酰磺酰胺和异腈通过C-N键活化环合。

Umicore预催化剂，用于不对称和交叉偶联催化

用作以下反应的催化剂：

氧化烯化反应
仲醇的C-C键裂解
苯酚衍生物的邻位C-H烯化反应
吡啶的氧化环化反应
苯甲酰胺与醛通过sp² C-H 键的直接官能化发生氧化邻位酰化反应
酰胺化反应
还原性烷基化反应

包装

2 g in glass bottle
500 mg in glass bottle

法律信息

Umicore产品

详细信息请访问www.pmc.umicore.com

基本信息

线性分子式	[Rh(C₅Me₅)Cl₂]₂
分子量	618.08
MDL编号	MFCD00061552
PubChem化学物质编号	329761080
NACRES	NA.22

产品性质

质量水平	100
形式	powder
reaction suitability	core: rhodium reagent type: catalyst reaction type: C-H Activation
SMILES string	Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI	1S/2C10H15.4ClH.2Rh/c21-6-7(2)9(4)10(5)8(6)3;;;;;;/h21-5H3;41H;;/q;;;;;;2+2/p-4
InChI key	QNIVKTTWBMFSBR-UHFFFAOYSA-J

安全信息

象形图
警示用语：	Warning
危险声明	H302 + H312 + H332 - H315
预防措施声明	P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
危险分类	Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Skin Irrit. 2
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

053214

Fluorochem

Dichloro(pentamethylcyclopentadienyl) Rhodium(III) dimer

97%

3960元/250mg; 12540元/1g;

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基本信息

CAS Number	12354-85-7
MDL Number	MFCD00061552

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .