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CAS: 122536-76-9
分子式: C9H18N2O2
分子量: 186.25
沸点: 112°C/0.25mm
熔点: 50 °C
中文名称: 
(S)-3-叔丁氧羰基氨基吡咯烷
英文名称: 
(3S)-3-(tert-butoxycarbonylamino)pyrrolidine
(S)-3-(boc-amino)pyrrolidine
(S)-(+)-3-(Boc-amino)pyrrolidine
推荐供应商
货号品牌产品名称规格包装、参考价格详情
S818382MACKLIN(|S|)-3-(Boc-氨基)吡咯烷97%31元/1g;   101元/5g;   491元/25g;   1680元/100g;   展开
储存:室温
状态:白色到灰白色粉末或固体或块状
折射率:-20 ° (C=1, EtOH)
A1172TCI(3S)-(-)-3-(tert-Butoxycarbonylamino)pyrrolidine>98.0%(GC)(T)990元/5G;   3990元/25G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C9H18N2O2 = 186.26
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN5377813
PubChem物质ID87562650
MDL编号MFCD00143194

技术规格

AppearanceWhite to Light yellow to Light orange powder to crystal
Purity(GC)min. 98.0 %
Purity(Nonaqueous Titration)min. 98.0 %
Melting point76.0 to 80.0 ℃
Specific rotation [a]20/D-19.0 to -22.0 deg(C=1, EtOH)
Solubility in Methanolalmost transparency

物性(参考值)

熔点78 ℃
比旋光度 [α]D-20° (C=1,EtOH)

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
244064J&K(S)-3-(Boc-amino)pyrrolidine98%359元/1G;   1491元/5G;   展开

基本信息

分子式C9H18N2O2
分子量186.25
熔点50-54
比旋光度([α]20D)-23° to -17° (C=1, ethanol)
MDL编码MFCD00143194
Beilstein5377813

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
UN号码3259
危险分类8
包装等级III
WGK3
TSCA
H51729Alfa Aesar(S)-(-)-3-(Boc-amino)pyrrolidine98%3996元/5g;   20070元/25g;   展开

应用
(S)-(-)-3-(Boc-amino)pyrrolidine is used as pharmaceutical intermediate.

备注
Air sensitive. Incompatible with oxidizing agents and carbon dioxide.

基本信息

MDL
MFCD00143194

分子式
C9H18N2O2

分子量
186.25

熔点
50-54°

灵敏度
Air Sensitive. Ambient temperatures.

形态
Crystalline

溶解性
Soluble in water.

Beilstein
5377813

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P280-P305+P351+P338-P309-P310
Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.

安全信息

危险类别
34
Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

L19693Alfa Aesar(S)-(-)-3-(Boc-amino)pyrrolidine99%, ee 99%1563元/1g;   4212元/5g;   展开

基本信息

MDL
MFCD00143194

分子式
C9H18N2O2

分子量
186.25

熔点
50-54°

灵敏度
Keep Cold. Air Sensitive.

形态
Crystalline powder

Beilstein
5377813

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P280-P305+P351+P338-P309-P310
Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.

安全信息

危险类别
34
Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

009068Fluorochem(3S)-(-)-3-(tert-Butoxycarbonylamino)pyrrolidine98%220元/1g;   660元/5g;   2420元/25g;   展开

基本信息

CAS Number122536-76-9
MDL NumberMFCD00143194
Melting Point50-54℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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