基本信息

技术规格

物性(参考值)

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

Technical Notes:

1. Photocatalyst used for the chemo-, regio, and stereoselective trifluoromethylation of styrene.

2.Photoredox catalyst used in cross-coupling: Ir/Ni dual catalysts for the synthesis of benzylic ethers.

3.Iridium complex used for catalytic olefin hydroamidation enabled by proton-coupled electron transfer.

4.Catalyst used for visible light photoredox cross -coupling of acyl chlorides with potassium

alkoxymethyltrifluoroborates.

5.Iridium catalyst used in the photoredox/nickel dual catalytic cross- coupling of secondary alkyl

ß-trifluoroboratoketones and - -esters with aryl bromides.

6.Photocatalyst used in the cross - coupling of trifluoroa lkylboranes.

应用
Chlorobis(cyclooctene)iridium(I) dime is used as catalyst for Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand, Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions, Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions, Alkylation reactions, Guerbet reaction, Allylic amination reactions in a DNA-diene-iridium(I) hybrid system, Asymmetric hydroamination reactions.

备注
keep container tightly closed. Store in cool, dry conditions in well sealed containers.

基本信息

MDL
MFCD00213465

分子式
C₃₂H₅₆Cl₂Ir₂

分子量
896.00

灵敏度
Ambient temperatures.

溶解性
Soluble in organic solvents.

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

产品说明

应用

氯二(环辛烯)铱(I)二聚体可用作以下反应的催化剂：

• 作为稳定剂，与 nido- carboranyldiphosphine 发生异构化-硼氢化反应。
• 过氧化氢氧化异羟肟酸，及其随后的杂环 Diels-Alder 环加成反应。
• 通过乙烯基硅烷偶联反应将有机官能团固定在固体载体上。
• 烷基化反应。
• 格柏反应。
• 使用 DNA-二烯-铱(I)杂化体系的烯丙基胺化反应。
• 不对称的加氢胺化反应。

• 以 nido- carboranyldiphosphine 作为稳定配体的异构化-硼氢化反应
• 过氧化氢氧化异羟肟酸及其随后的杂 Diels-Alder 环加成反应
• 通过乙烯基硅烷偶联反应将有机官能团固定在固体载体上
• 烷基化反应
• 格柏反应
• DNA-二烯-铱(I)杂化体系中的烯丙基胺化反应
• 不对称的加氢胺化反应

包装

250 mg in glass bottle
1, 5 g in glass bottle

基本信息

产品性质

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves