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CAS: 12245-39-5
分子式: C13H19O2Rh
分子量: 310.19
熔点: 138-140 °C(lit.)
英文名称: 
(1,5-cyclooctadiene)(2,4-pentanedionato)-rhodiu
(1,5-cyclooctadiene)(2,4-pentanedionato)rhodium
acetylacetonate-1,5-cyclooctadiene rhodium
((1,2,5,6-eta)-1,5-cyclooctadiene)(2,4-pentanedionato-o,o')-rhodiu
(acetylacetonato)(1,5-cyclooctadiene)-rhodium(i),
(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)
Rh(acac)(COD)
推荐供应商
货号品牌产品名称规格包装、参考价格详情
A801411MACKLIN(1,5-环辛二烯)2,4-戊二酮铑(I)99%1166元/250mg;   2747元/1g;   展开
储存:2~8°C
状态:黄色或橙色粉末或晶体
45-0010StremAcetylacetonato(1,5-cyclooctadiene)rhodium(I)98%855元/100mg;   3480元/500mg;   展开

Technical Notes:

1. Precursor for asymmetric hydrogenation reactions.

2. Rh-catalyzed carbozincation of ynamides.

References:

1. J. Org. Chem., 1999, 64, 5593.

2. J. Org. Chem., 2009, 74, 7849.

H26083Alfa Aesar(1,5-Cyclooctadiene)rhodium(I) 2,4-pentanedionate0元/250mg;   0元/1g;   展开

基本信息

MDL
MFCD00075046

分子式
C13H19O2Rh

分子量
310.19

熔点
136-140°

形态
Crystalline solid

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
4.1

包装组
III

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
VI9292000

TSCA

683108Sigma-AldrichChiralyst P310Umicore, 99%2254.7元/500 MG;   8772.5元/2 G;   展开

产品说明

应用

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Catalyst/precursor for enantioselective/asymmetric hydrogenations, isomerization/hydroformylations, carbozincation reactions, and silylation of aryl electrophiles

包装

2 g in glass bottle
500 mg in glass bottle

法律信息

Product of Umicore

Additional information available at www.pmc.umicore.com

基本信息

经验(实验)分子式C13H19O2Rh
分子量310.19
MDL编号MFCD00075046
PubChem化学物质编号329760794
NACRESNA.22

产品性质

质量水平100
测定99%
形式solid
reaction suitabilitycore: rhodium
reagent type: catalyst
mp138-140 ℃ (lit.)
SMILES stringCC(=O)\C=C(\C)O[Rh].C1CC=CCCC=C1
InChI1S/C8H12.C5H8O2.Rh/c1-2-4-6-8-7-5-3-1;1-4(6)3-5(2)7;/h1-2,7-8H,3-6H2;3,6H,1-2H3;/q;;+1/p-1/b2-1-,8-7-;4-3-;
InChI keyTVGPAHONTUMCNP-DWVXZKBMSA-M

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
494176FluorochemAcetylacetonato(1,5-cyclooctadiene)rhodium(I)=99%, (33% Rhodium content min)5280元/250mg;   10582元/1g;   展开

基本信息

CAS Number12245-39-5
MDL NumberMFCD00075046
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9