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CAS: 122-00-9
分子式: C9H10O
分子量: 134.18
沸点: 226℃
熔点: 22-24℃
中文名称: 
4'-甲基苯乙酮
甲基对甲苯基甲酮
1-(4-甲基苯基)乙醇
对乙酰甲苯
对甲基苯乙酮
英文名称: 
4-methyl acetophenone
1-p-tolyl-ethanone
1-(4-methyl-phenyl)-ethanone
4-hlethylacetophenon
Ethanone,1-(4-methylphenyl)-
1-(4-Methylpheyl)ethanone
1-(4-methylphenyl)-Ethanone
4'-methyl-acetophenon
1-(4-methylphenyl)ethanone
1-methyl-4-acetylbenzene
4'-methylacetophenone
1-(4-methylphenyl)-ethanon
melilotal
methyl p-tolyl ketone
p-acetyltoluene
p-methylacetophenone
4-methylacetophenone
4-Acetyltoluene
展开更多英文名
性质描述: 无色针状结晶体或近似无色液体。熔点28℃。沸点225℃(98.1kPa),112.5℃(1.47kPa),相对密度1.0051(20/4℃),折光率1.5335,闪点92℃。易溶于乙醇、乙醚、苯、氯仿和丙二醇,几乎不溶于水。
生产方法: 由甲苯与乙酐在无水三氯化铝存在下,经乙酰化反应制得。将干燥的甲苯和粉状无水三氯化铝加入反应锅内,搅拌下滴加乙酐,温度逐渐升至90℃,反应放出大量氯化氢气体。反应至不再产生氯化氢气体,冷至室温,将其倒入碎冰和浓盐酸的混合物中,搅拌至铝盐全部溶解为止。分出甲苯层,水洗,用10%氢氧化钠溶液洗涤至碱性,再用水洗。经无水硫酸镁干燥后,减压蒸馏,收集93-94℃(0.93kPa)馏分,得对甲基苯乙酮,收率为86%。经改进的方法是将等摩尔的三氯化铝与乙酰氯(或乙酐)在加热情况下静置使之结合,再向其中滴入溶于二硫体碳的甲苯。按乙酰氯计算,重量得率为110%。
用途: 该品具有类似山查子花的芳香,并有象紫苜蓿、蜂蜜、草莓和香味,花果香味尖锐而带甜。可用于配制金合欢型皂用紫丁香型香精等,亦可作果实食品香精。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M813265MACKLIN4'-甲基苯乙酮98%36元/25g;   69元/100g;   188元/500g;   665元/2.5kg;   2565元/10kg;   展开
储存:室温,易燃物区域
状态:无色到浅黄色液体
折射率:n20/D 1.533(lit.)
M0135TCI4'-Methylacetophenone>95.0%(GC)130元/25ML;   650元/500ML;   展开

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C9H10O = 134.18
外观与形状(20℃)液体
Reaxys-RN606053
PubChem物质ID87572239
SDBS (AIST Spectral DB)1498
MDL编号MFCD00008751

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 95.0 %

物性(参考值)

沸点226 ℃
闪点92 ℃
比重1.01
折射率1.53

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H227 : 可燃液体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P403 + P235 : 存放在通风良好的地方。保持低温。

相关法规

RTECS#AM9463000
301804J&K4'-Methylacetophenone98%115元/50G;   387元/250G;   展开

基本信息

分子式C9H10O
分子量134.18
熔点22-24
沸点226
闪点82
密度1.005
折光率(n20D)1.5330
MDL编码MFCD00008751
Beilstein606053
EINECS 编号204-514-8

安全信息

图形或危害标志
提示语Warning
危险说明H302
防范说明P260
P262
WGK1
RTECSAM9463000
TSCA
A14469Alfa Aesar4'-Methylacetophenone96%554元/50g;   1023元/250g;   2913元/1000g;   展开

应用
4'-Methylacetophenone is used as a flavoring agent. It reacts with morpholine to get 4-(p-tolyl-thioacetyl)-morpholine in the presence of sulfur as a reagent. Further, it is used as an intermediate in the manufacture of active pharmaceutical ingredients, perfumes and cosmetics.

备注
Incompatible with strong oxidizing agents, strong bases and strong reducing agents.

基本信息

MDL
MFCD00008751

EINECS
204-514-8

分子式
C9H10O

分子量
134.18

熔点
-19°

沸点
224-226°

闪点
92°(197°F)

密度
1.010

折射率
1.5340

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Miscible with water.

Beilstein
606053

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H302
Combustible liquid.Harmful if swallowed.

Precautionary Statements
P210e-P280a-P264-P301+P312a-P403+P235-P501a
Wear protective gloves and eye/face protection.Wash thoroughly after handling.Wash thoroughly after handling.Store in a well-ventilated place. Keep cool.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22
Harmful if swallowed.

安全等级
36
Wear suitable protective clothing.

欧盟危险品标志

RTECS
AM9463000

TSCA

C12618Alfa Aesar4'-Methylacetophenone95%581元/5g;   856元/250g;   2275元/1kg;   展开

基本信息

Ref#
12618

MDL
8751

分子式
C9 H10 O

分子量
134.18

闪点
92

密度
1005

M26615Sigma-Aldrich4′-Methylacetophenone95%325.59元/100 G;   574.75元/500 G;   展开

基本信息

线性分子式CH3C6H4COCH3
分子量134.18
Beilstein606053
EC 号204-514-8
MDL编号MFCD00008751
PubChem化学物质编号24896755
NACRESNA.22

产品性质

测定95%
折射率n20/D 1.533 (lit.)
bp226 ℃ (lit.)
mp22-24 ℃ (lit.)
密度1.004 g/mL at 20 ℃
1.005 g/mL at 25 ℃ (lit.)
SMILES stringCC(=O)c1ccc(C)cc1
InChI1S/C9H10O/c1-7-3-5-9(6-4-7)8(2)10/h3-6H,1-2H3
InChI keyGNKZMNRKLCTJAY-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315
预防措施声明P301 + P312 + P330
危险分类Acute Tox. 4 Oral - Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)179.6 °F - closed cup
闪点(C)82 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
W267708Sigma-Aldrich4′-Methylacetophenone≥95%, FCC, FG637.25元/;   704.2元/1 KG;   展开

产品说明

一般描述

4′-Methylacetophenone occurs naturally in mango, tomato and orange.

包装

10 kg in composite drum
1 kg in glass bottle
25 kg in poly drum
5 kg in steel drum

基本信息

线性分子式CH3C6H4COCH3
分子量134.18
FEMA编号2677
Beilstein606053
EC 号204-514-8
欧洲委员会编号156
MDL编号MFCD00008751
PubChem化学物质编号24901243
Flavis编号7.022
NACRESNA.21

产品性质

质量水平400
生物来源synthetic
等级FG
Halal
Kosher
agencymeets purity specifications of JECFA
reg. complianceEU Regulation 1334/2008 & 178/2002
FCC
FDA 21 CFR 117
FDA 21 CFR 172.515
测定≥95%
折射率n20/D 1.533 (lit.)
bp226 ℃ (lit.)
mp22-24 ℃ (lit.)
密度1.004 g/mL at 20 ℃
1.005 g/mL at 25 ℃ (lit.)
文件see Safety & Documentation for available documents
性状检查hawthorne; floral
application(s)flavors and fragrances
食品过敏原no known allergens
SMILES stringCC(=O)c1ccc(C)cc1
InChI1S/C9H10O/c1-7-3-5-9(6-4-7)8(2)10/h3-6H,1-2H3
InChI keyGNKZMNRKLCTJAY-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315
预防措施声明P264 - P270 - P280 - P301 + P312 - P302 + P352 - P332 + P313
危险分类Acute Tox. 4 Oral - Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)179.6 °F - closed cup
闪点(C)82 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
8.21243Sigma-Aldrich4′-Methylacetophenonefor synthesis391.57元/250 ML;   769.46元/1 L;   展开

产品说明

分析说明

Assay (GC, area%): ≥ 95.0 % (a/a)
Density (d 20 °C/ 4 °C): 1.004 - 1.005
Identity (IR): passes test
Due to its specific melting range the product may be solid, liquid, a solidified melt or a supercooled melt.

基本信息

经验(实验)分子式C9H10O
分子量134.18
MDL编号MFCD00008751
EC索引号204-514-8

产品性质

质量水平200
蒸汽压0.52 hPa ( 25 ℃)
测定≥95.0% (GC)
效能1400 mg/kg LD50, oral (Rat)
>2000 mg/kg LD50, skin (Rabbit)
expl. lim.1.00 % (v/v)
转变温度flash point 93 ℃
密度1.00 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/C9H10O/c1-7-3-5-9(6-4-7)8(2)10/h3-6H,1-2H3
InChI keyGNKZMNRKLCTJAY-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315
预防措施声明P264 - P270 - P280 - P301 + P312 - P302 + P352 - P332 + P313
危险分类Acute Tox. 4 Oral - Skin Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)179.6 °F - closed cup
闪点(C)82 ℃ - closed cup
075950Fluorochem4'-Methylacetophenone97%484元/250g;   1584元/1kg;   7172元/5kg;   展开

基本信息

CAS Number122-00-9
MDL NumberMFCD00008751
Boiling Point224-226℃
Melting Point22-24℃
Density1.01

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H227: Combustible liquid
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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