CAS 12150-46-8; 1,1'-双(二-苯基膦基)二茂铁; 1,1'-Ferrocenebis(diphenylphosphine)

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包装、参考价格

B801963

MACKLIN

1,1'-双(二苯基膦)二茂铁

97%

28元/1g; 35元/5g; 105元/25g; 385元/100g; 1699元/500g;

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储存：2~8°C
状态：黄色到橙色粉末

B992632

MACKLIN

1,1'-双(二苯基膦)二茂铁

99%

162元/25g; 532元/100g; 1988元/500g;

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储存：2-8℃
状态：浅黄色到棕色粉末到晶体

B2027

TCI

1,1'-Bis(diphenylphosphino)ferrocene

>96.0%(T)

110元/1G; 340元/5G; 1115元/25G;

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基本信息

纯度/分析方法	>96.0%(T)
分子式/分子量	C₃₄H₂₈FeP₂ = 554.39
外观与形状(20℃)	固体
PubChem物质ID	87564906
MDL编号	MFCD00001422

技术规格

Appearance	Light yellow to Brown powder to crystaline
Purity(Chelometric Titration)	min. 96.0 %

物性(参考值)

熔点	182 ℃(dec.)
水溶性	不溶

安全信息

图形或危害标志
信号词	警告
危险性说明	H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P302 + P352 + P312 : 如皮肤沾染：用水充分清洗。如感觉不适，呼叫急救中心/医生。 P304 + P340 + P312 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。

231095

J&K

1,1'-Bis(diphenylphosphino)ferrocene

98%

108元/1G; 311元/5G; 885元/25G;

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基本信息

分子式	C₃₄H₂₈FeP₂
分子量	554.39
熔点	181-182
MDL编码	MFCD00001422
EINECS 编号	430-420-3

安全信息

图形或危害标志
提示语	Danger
危险说明	H301 H312 H332
防范说明	P280 P305+P351+P338 P313
UN号码	3467
危险分类	6.1
包装等级	III
WGK	3
TSCA	否

26-0270

Strem

1,1'-Bis(diphenylphosphino)ferrocene

99%

430元/1g; 1195元/5g; 4782元/25g; 19275元/250g;

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Technical Notes:

1. Ligand for Pd-catalyzed cross- coupling.

2. Useful ligand for Pd-catalyzed carbon-nitrogen and carbon-oxygen bond forming procedures.

3.Ligand for Ni-catalyzed amination of aryl chlorides

4.Ligand for Pd-catalyzed conversion of aryl halides to aryl nitriles .

5.Ligand for Ni-catalyzed Suzuki reactions.

6.Ni-catalyzed hydroamination of 1,3-dienes.

7.Pd-catalyzed hydrocarbonation and hydroamination of 3,3-dihexylcyclopropene.

8. Pd-catalyzed y-arylation of ß,y-unsaturated ketones .

9. L igand for Ru-catalyzed reduction of nitriles to primary amines.

10. Ligand for Rh-catalyzed alkyne head-to-tail dimerization.

11.Ligand for Rh-catalyzed cross-coupling (Ref.

12.Ligand for Rh-catalyzed olefin isomerization (Ref. 22).

13Ligand for Ni or Rh-catalyzed borylation (Ref. 23, 24)

14. Ligand for regioselective Pd-catalyzed hydrophosphinylation of terminal alkynes to form branched alkenes.

C34801

Alfa Aesar

1,1'-Bis(diphenylphosphino)ferrocene

98%

2693元/5g; 8337元/25g;

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基本信息

Ref#
34801

MDL
1422

分子式
C34 H28 Fe P2

分子量
553.99

形态
Crystalline

安全信息

危险等级
6.1

包装组
III

177261

Sigma-Aldrich

Dppf

97%

124.99元/1 G; 1187.34元/10 G; 1667.67元/25 G;

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产品说明

一般描述

我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了催化效率。点击此处了解更多详情。
通过Pd-膦依序形成C-C和C-O键，制备新型官能化呋喃衍生物。

应用

Pd(II)-催化交叉偶联合成奥氮平环系统的配体。
可作为从胺和酒精绿色合成胺的钌催化借氢反应的配体。

借氢反应法钌催化胺和磺酰胺N-烷基化

包装

1, 10, 25 g in glass bottle

基本信息

经验(实验)分子式	C₃₄H₂₈FeP₂
分子量	554.38
MDL编号	MFCD00001422
PubChem化学物质编号	24850625
NACRES	NA.22

产品性质

质量水平	200
测定	97%
形式	powder
reaction suitability	reagent type: catalyst reaction type: Cross Couplings reagent type: ligand reaction type: Buchwald-Hartwig Cross Coupling Reaction reagent type: ligand reaction type: Carbonylations reagent type: ligand reaction type: Ene Reaction reagent type: ligand reaction type: Heck Reaction reagent type: ligand reaction type: Negishi Coupling reagent type: ligand reaction type: Sonogashira Coupling reagent type: ligand reaction type: Stille Coupling reagent type: ligand reaction type: Suzuki-Miyaura Coupling reagent type: ligand reaction type: Tsuji-Trost Reaction
环保替代产品特性	Catalysis Learn more about the Principles of Green Chemistry.
mp	181-182 ℃ (dec.) (lit.)
官能团	phosphine
环保替代产品分类	Aligned
SMILES string	[Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
InChI	1S/2C17H14P.Fe/c21-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h21-14H;
InChI key	HPXNTHKXCYMIJL-UHFFFAOYSA-N

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)

460490

Amethyst

1,1'-Bis(diphenylphosphino)ferrocene

98%, 用于合成

40元/1G; 49元/5G; 95元/25G; 377元/100G; 1508元/500G;

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基本信息

分子式	C₃₄H₂₈FeP₂
分子量	554.39
熔点	181-182
MDL编码	MFCD00001422
EINECS 编号	430-420-3

安全信息

图形或危害标志
提示语	Danger
危险说明	H302 H312 H332
防范说明	P280 P305+P351+P338 P313
UN号码	3467
危险分类	6.1
包装等级	III
WGK	3
TSCA	否

044344

Fluorochem

1,1'-Bis(diphenylphosphino)ferrocene

98%

220元/1g; 220元/5g; 330元/25g; 1210元/100g;

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基本信息

CAS Number	12150-46-8
MDL Number	MFCD00001422

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .