CAS 12148-71-9; (1,5-环辛二烯)(甲氧基)铱(i)二聚体; (1,5-cyclooctadiene)(methoxy)iridium(i) dimer

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规格

包装、参考价格

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C805784

MACKLIN

甲氧基(环辛二烯)铱(I)二聚体

96%

256元/100mg; 512元/250mg; 1974元/1g; 9861元/5g;

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储存：2~8 ℃,干燥,惰性气体氛围
状态：黄色到橙色粉末
物化性质：空气敏感

C2662

TCI

(1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer

565元/200MG; 1990元/1G;

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基本信息

分子式/分子量	C₁₈H₃₀Ir₂O₂ = 662.87
外观与形状(20℃)	固体
储存温度	<0℃
储存在惰性气体下	存放于惰性气体之中
应避免的情况	光,空气,湿气 (分解),加热
包装和容器	1G-带有塑料内管的玻璃瓶 (查看图片)
Reaxys-RN	14520157
PubChem物质ID	160871404
MDL编号	MFCD08459360

技术规格

Appearance	Light yellow to Amber to Dark green powder to crystal
Elemental analysis(Carbon)	31.50 to 34.00 %

物性(参考值)

熔点	179 ℃(dec.)

77-1100

Strem

Di-mu-methoxobis(1,5-cyclooctadiene)diiridium(I)

min. 98%

3930元/500mg; 11790元/2g; 47160元/10g;

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Technical Note:

1.Useful starting material for the preparation of iridium catalysts.

044967

Alfa Aesar

Methoxy(cyclooctadiene)iridium(I) dimer

Ir nominally 58%

0元/1g; 0元/5g;

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应用
Methoxy(cyclooctadiene)iridium(I) dimer is used as a catalyst in the preparation of heteroaryl fused indole ring systems and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration.

备注
Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD08459360

分子式
C₁₈H₃₀Ir₂O₂

分子量
662.88

灵敏度
Keep Cold. Moisture Sensitive. Air Sensitive. Light Sensitive.

形态
Powder

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA
否

685062

Sigma-Aldrich

(1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer

891.92元/250 MG; 3253.82元/1 G; 33157.7元/25 G;

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产品说明

应用

用作以下反应的催化剂：

制备杂芳基稠合的吲哚环体系，作为HCV NS5B聚合酶的抑制剂
硼化反应/Suzuki-Miyaura偶联反应
Metalation-Suzuki交叉偶联反应，用于合成联芳基和杂双芳基
四硼化反应
高度区域和对映选择性不对称硼氢化
通过C-H活化使芳基酮、苯甲醛和苄醇衍生物发生邻甲硅烷基化

一种强大的C-H活化催化剂，用于从芳烃制备酚

包装

250 mg in glass bottle
1, 25 g in glass bottle

基本信息

线性分子式	[Ir(OCH₃)(C₈H₁₂)]₂
分子量	662.86
MDL编号	MFCD08459360
PubChem化学物质编号	329760940
NACRES	NA.22

产品性质

reaction suitability	core: iridium reagent type: catalyst reaction type: C-H Activation
质量水平	100
mp	154-179 ℃ (D)
储存温度	−20℃
SMILES string	C[O+]1[Ir-]2[O+](C)[Ir-]12.C3CC=CCCC=C3.C4CC=CCCC=C4
InChI	1S/2C8H12.2CH3O.2Ir/c21-2-4-6-8-7-5-3-1;21-2;;/h21-2,7-8H,3-6H2;21H3;;/q;;2+1;2-1/b2*2-1-,8-7-;;;;
InChI key	BGWIAAATAAWGOI-MIXQCLKLSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

051170

Fluorochem

Bis(1,5-cyclooctadiene)dimethoxydiiridium

97+%

1056元/250mg; 2244元/1g; 9878元/5g;

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基本信息

CAS Number	12148-71-9
MDL Number	MFCD08459360
Melting Point	154-179℃

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .