| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| P821813 | MACKLIN | 氢氧化钯 | 99.9% | 459元/200mg; 1305元/1g; 4950元/5g; | 咨询 |
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| P815788 | MACKLIN | 氢氧化钯 | 10% Pd(OH)2 | 739元/5g; 2999元/25g; 9269元/100g; | 咨询 |
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| P815787 | MACKLIN | 氢氧化钯 | 20% Pd(OH)2 | 325元/1g; 1350元/5g; 5990元/25g; | 咨询 |
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| P1528 | TCI | Palladium Hydroxide (contains Pd, PdO) on Carbon (wetted with ca. 50% Water) | | 3580元/10G; 16500元/50G; | 咨询 |
基本信息 | 分子式/分子量 | Pd(OH)2 = 140.43 | | 外观与形状(20℃) | 固体 | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 空气 | | Reaxys-RN | 11342936 | | PubChem物质ID | 87558562 | | Merck Index (14) | 7060 | | MDL编号 | MFCD00064599 |
技术规格 | Appearance | Black powder to crystal | | Drying loss | 45.0 to 60.0 % |
物性(参考值) 安全信息 | 图形或危害标志 |  | | 信号词 | 警告 | | 危险性说明 | H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
| | 防范说明 | P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染：用水充分清洗。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激：求医/就诊。
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| 317552 | J&K | Palladium hydroxide on carbon | 20% 钯, 含水约50% | 1425元/10G; 5254元/50G; | 咨询 |
基本信息 | 分子式 | Pd(OH)2 | | 分子量 | 140.43 | | MDL编码 | MFCD00064599 | | Merck | 14,7060 | | EINECS 编号 | 235-219-2 |
安全信息 |
| 039496 | Alfa Aesar | Palladium hydroxide | 99% | 1868元/0.25g; 5831元/1g; 0元/5g; | 咨询 |
应用
Acts as a catalyst for arylation reactions. It is employed in hydrogenolysis of benzyl-nitrogen bonds. 备注
Stable under recommended storage conditions. 基本信息 MDL
MFCD00064599 EINECS
235-219-2 分子式
Pd(OH)2 分子量
140.42 灵敏度
Ambient temperatures. 形态
Powder 溶解性
Insoluble in water. 安全信息 TSCA
是 |
| 045576 | Alfa Aesar | Palladium hydroxide | Pd 5% on carbon powder, Type A403002-5, nominally 50% water | 1075元/2g; 5286元/10g; | 咨询 |
基本信息 MDL
MFCD00064599 EINECS
235-219-2 安全信息 TSCA
是 |
| 042578 | Alfa Aesar | Palladium hydroxide | Pd 20% on carbon, nominally 50% water, Pearlman's Catalyst | 977元/2g; 0元/10g; 0元/50g; | 咨询 |
应用
Hydrogenolysis of benzyl-nitrogen bondsPalladium hydroxide, Pd 20% on carbon, nominally 50% water is used as a catalyst for hydrogenolysis of benzyl groups and epoxides. It is used to reduce nitro compounds to amines. It acts as a dehydrogenation reagent as well as a useful reagent for debenzylation. 备注
Sold on a dry weight basis. Unit weight excludes water weightIncompatible with oxidizing agents, acids, alcohol and sulfur compounds. 基本信息 MDL
MFCD00064599 EINECS
235-219-2 灵敏度
Ambient temperatures. 溶解性
Insoluble in water. 安全信息 TSCA
是 |
| C19962 | Alfa Aesar | Palladium hydroxide on carbon | powder, unreduced, 20% Pd, moisture ca 60% | 10815元/10g; 47686元/50g; | 咨询 |
基本信息 Ref#
19962 MDL
64599 分子式
Pd H2 O2 分子量
140.43 形态
Powder |
| 212911 | Sigma-Aldrich | Palladium hydroxide on carbon | extent of labeling: 20 wt. % loading (dry basis), matrix carbon, wet support | 541.22元/1 G; 5139.39元/10 G; 12825.6元/50 G; 85504元/500 G; | 咨询 |
产品说明 包装 1, 10, 50, 500 g in glass bottle 应用 Pd/C 和 Pd(OH)2/C 的加成反应可提高 N- 或 O-脱苄基反应的效率。
在分子内和分子间过程中高效催化芳基碘和芳基溴的直接芳基化反应。
对苄基-氮键的氢解反应特别有效，并且已证明即使对于其他碳负载钯催化剂失效的情况也同样有效。 基本信息 | 经验(实验)分子式 | H2O2Pd | | 分子量 | 140.43 | | EC 号 | 235-219-2 | | MDL编号 | MFCD00064599 | | PubChem化学物质编号 | 24852754 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 形式 | powder | | 包含 | ≤50% water | | reaction suitability | core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst | | 标记范围 | 20 wt. % loading (dry basis) | | 基质 | carbon, wet support | | SMILES string | O[Pd]O | | InChI | 1S/2H2O.Pd/h2*1H2;/q;;+2/p-2 | | InChI key | NXJCBFBQEVOTOW-UHFFFAOYSA-L |
安全信息 | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
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| 330094 | Sigma-Aldrich | Palladium hydroxide on carbon | extent of labeling: 20 wt. % loading (dry basis), matrix carbon, wet support | 4295.77元/10 G; 15236.7元/50 G; | 咨询 |
产品说明 包装 10, 50 g in glass bottle 应用 苄基和环氧化物氢解催化剂；用于将硝基化合物还原为胺并作为脱氢试剂。
脱苄基反应的有效试剂。 基本信息 | 经验(实验)分子式 | H2O2Pd | | 分子量 | 140.43 | | EC 号 | 235-219-2 | | MDL编号 | MFCD00064599 | | PubChem化学物质编号 | 24859831 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 包含 | ~50% water | | reaction suitability | core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst | | 标记范围 | 20 wt. % loading (dry basis) | | 重量 | Unit weight excludes weight of water | | 基质 | carbon, wet support | | SMILES string | O[Pd]O | | InChI | 1S/2H2O.Pd/h2*1H2;/q;;+2/p-2 | | InChI key | NXJCBFBQEVOTOW-UHFFFAOYSA-L |
安全信息 | 储存分类代码 | 13 - Non Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
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| 941062 | Amethyst | Palladium hydroxide on carbon, 20% Pd, wetted with ca. 50% H2O,reagent grade | 20% 钯, 含水约50%,试剂级 | 350元/1G; 1300元/5G; 6150元/25G; 23150元/100G; | 咨询 |
基本信息 | 分子式 | Pd(OH)2 | | 分子量 | 140.43 | | MDL编码 | MFCD00064599 | | Merck | 14,7060 | | EINECS 编号 | 235-219-2 |
安全信息 |
| 033057 | Fluorochem | Palladium hydroxide on carbon 5% | 95+% | 1430元/5g; 6050元/25g; | 咨询 |
基本信息 | CAS Number | 12135-22-7 | | MDL Number | MFCD00064599 | | Melting Point | >450℃ | | Density | 3.44 |
安全信息 | 图形或危害标志 |  | | 危险性说明 | H302: Harmful if swallowed.
H315: Causes skin irritation.
H318: Causes serious eye damage.
H335: May cause respiratory irritation.
H317: May cause an allergic skin reaction
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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| 075132 | Fluorochem | Palladium hydroxide on carbon, 20 wt.% 50% water | 95% | 528元/1g; 1210元/5g; 4730元/25g; | 咨询 |
基本信息 | CAS Number | 12135-22-7 | | MDL Number | MFCD00064599 | | Melting Point | >450℃ | | Density | 3.44 |
安全信息 | 图形或危害标志 |  | | 危险性说明 | H272: May intensify fire; oxidiser.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P210: Keep away from – No smoking.
P220: Keep/Store away from clothing//combustible materials.
P221: Take any precaution to avoid mixing with combustibles/
P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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