Technical Note:

1. Catalyst for the Pauson-Khand like conversion of enynes to cyclope ntenones.

References:

1. J. Am. Chem. Soc., 1996, 1 18, 9450.

2. Encyclopedia of Reagents for Organic Synthesis, 1995, Vol. 3, 1632.

应用
It is used as an pharmaceutical intermediate.

备注
Air, moisture and light sensitive. Store in a cool dry place. Keep away from oxidizing agents.

基本信息

MDL
MFCD00143762

分子式
C₁₂H₁₀O₂Ti

分子量
234.09

熔点
90° dec.

沸点
60°/0.001mm subl.

灵敏度
Moisture Sensitive. Air Sensitive. Ambient temperatures.

形态
Crystalline

溶解性
Insoluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H228-H300-H331
Flammable solid.Fatal if swallowed.Toxic if inhaled.

Precautionary Statements
P210-P261-P280-P301+P310a-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.Wear protective gloves/protective clothing/eye protection/face protection.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
II

危险类别
11-20-25
Highly flammable.Harmful by inhalation.Toxic if swallowed.

安全等级
7/9-20-33-36-43-45-60
Keep container tightly closed and in a well-ventilated place.When using do not eat or drink.Take precautionary measures against static discharges.Wear suitable protective clothing.In case of fire, use ... (indicate in the space the precise type of fire fighting equipment. If water increases risk, odd 'Never use water')In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
否