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CAS: 12116-66-4
分子式: C10H10Cl2Hf
分子量: 379.58
熔点: 230-233℃
中文名称: 
双(环戊二烯)二氯化铪
英文名称: 
bis(η-cyclopentadienyl)-hafnium chloride
bis(η-cyclopentadienyl)hafnium chloride
dichlorodi-pi-cyclopentadienyl-hafniu
dichlorobis(eta-cyclopentadienyl)hafnium
dichlorodi-pi-cyclopentadienylhafnium
dichlorodicyclopentadienylhafnium
dicyclopentadienylhafnium dichloride
hafnium dicyclopentadiene dichloride
dichlorobis( eta5-2,4-cyclopentadien-1-yl)-hafniu
dichlorobis(eta(5)-2,4-cyclopentadien-1-yl)-hafniu
hafnocene dichloride
Bis(cyclopentadienyl)hafnium(IV)dichloride
Di(cyclopentadienyl)hafnium(IV)dichloride
Bis(cyclopentadienyl)hafnium dichloride
展开更多英文名
推荐供应商
货号品牌产品名称规格包装、参考价格
H838410MACKLIN二氯二茂铪97%36元/200mg;   96元/1g;   375元/5g;   1708元/25g;   咨询
储存:室温
状态:白色到浅黄色到浅橙色粉末到晶体
H0914TCIHafnocene Dichloride>98.0%(T)520元/1G;   1350元/5G;   5190元/25G;   咨询

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C10H10Cl2Hf = 379.58
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
PubChem物质ID87571272
SDBS (AIST Spectral DB)23507
MDL编号MFCD00001438

技术规格

AppearanceWhite to Light yellow to Light orange powder to crystal
Purity(Chelometric Titration)min. 98.0 %

物性(参考值)

熔点233 ℃
水溶性不溶

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H371 : 可能损害器官。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P308+P311 : 如接触到或有疑虑:呼叫急救中心/医生。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P405 : 存放处须加锁。

相关法规

RTECS#MG4815000
72-1000StremBis(cyclopentadienyl)hafnium Dichloridemin. 98%520元/1g;   1807元/5g;   7173元/25g;   咨询
036105Alfa AesarBis(cyclopentadienyl)hafnium Dichloride1173元/1g;   8690元/5g;   29304元/25g;   咨询

应用
Starting material to prepare many kinds of hafnocene(II or IV) derivatives; in combination with AgI salt, is an effective activator for glycosyl fluoride. Pharmaceutical intermediates and alos used in chemical research.

备注
Moisture sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under inert gas. Incompatible with Strong oxidizing agents.

基本信息

MDL
MFCD00001438

EINECS
235-177-5

分子式
C10H10Cl2Hf

分子量
379.59

熔点
230-233°

灵敏度
Moisture Sensitive. Air Sensitive. Ambient temperatures.

形态
Crystalline, Packaged under argon

溶解性
Soluble in aromatic solvents, chloroform; slightly soluble in THF, ether. Insolble in hexanes.

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
34
Causes burns.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
是

119334Sigma-AldrichBis(cyclopentadienyl)hafnium(IV) dichloride98%430.81元/1 G;   2108.72元/10 G;   咨询

基本信息

经验(实验)分子式C10H10Cl2Hf
分子量379.58
EC 号235-177-5
MDL编号MFCD00001438
PubChem化学物质编号24847393
NACRESNA.22

产品性质

质量水平200
测定98%
reaction suitabilitycore: hafnium
reagent type: catalyst
mp230-233 ℃ (lit.)
SMILES stringCl[Hf]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI1S/2C5H5.2ClH.Hf/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChI keyUHCOEQZUSAFLHQ-UHFFFAOYSA-L

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
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