CAS 12108-13-3; 三羰基[(1,2,3,4,5-η)-1-甲基-2,4-环戊二烯基]合锰; 2-methylcyclopentadienyl

CAS:

12108-13-3

分子式:

C9H7MnO3

分子量:

218.09

沸点:

232-233℃

熔点:

-1-2.2℃

中文名称:

三羰基[(1,2,3,4,5-η)-1-甲基-2,4-环戊二烯基]合锰

英文名称:

2-methylcyclopentadienyl

manganese methylcyclopentadienyl tricarbonyl

manganese,tricarbonyl methylcyclopentadienyl

methyl cyclopentadienyl manganese tricar

methylcyclopentadienylmanganese tricarbonyl

methylcyclopentadienylmanganesetricar

tricarbonyl[(1,2,3,4,5-η)-1-methyl-2,4-cyclopentadien-1-yl]-Manganese

manganese, tricarbonyl methylcyclopentadienyl

2-methylcyclopentadienyl manganese tricarbonyl

ak-33x

antiknock-33

ci-2

combustion improver -2

(methylcyclopentadienyl)tricarbonyl-manganes

tricarbonyl[(1,2,3,4,5- eta)-1-methyl-2,4-cyclopentadien-1-yl]-manganes

Manganese,tricarbonyl[(1,2,3,4,5-η)-1-methyl-2,4-cyclopentadien-1-yl]-

methylcyclopentadienyl manganese tricarbonyl

Manganese,tricarbonyl(methyl-p-cyclopentadienyl)-

methylcyklopentadientrikarbonylmanganium

Manganese,tricarbonyl(methylcyclopentadienyl)-

(Methylcyclopentadienyl)tricarbonylmanganese

mmt

p-Methylcyclopentadienylmanganese tricarbonyl

2-Methylcyclopentadienylmanganese tricarbonyl

Ethyl MMT

tricarbonyl [(1,2,3,4,5-.eta.)-1-methyl-2,4-cyclopentadiene-1-yl] manganese

Hitec 3000

tricarbonyl methylcyclopentadienyl manganese

Methylcymantrene

NSC 22316

Tricarbonyl(η5-methylcyclopentadienyl)manganese

Tricarbonyl(η5-methylcyclopentadienyl)manganese(I)

tricarbonyl(methylcyclopendadienyl)manganese

Tricarbonyl(2-methylcyclopentadienyl)manganese

tricarbonyl(methylcyclopentadienyl)manganese

Tricarbonyl(methyl-π-cyclopentadienyl)manganese

Manganese,tricarbonyl[(1,2,3,4,5-h)-1-methyl-2,4-cyclopentadien-1-yl]-

(methylcyclopentadienyl)manganese tricarbonyl

Manganese,tricarbonyl((1,2,3,4,5-η)-1-methyl-2,4-cyclopentadien-1-yl)-

展开更多英文名

性质描述:

Insoluble in water. Soluble in hydrocarbon solvents, alcohols, ether, acetone

推荐供应商

货号

品牌

产品名称

规格

包装、参考价格

T830731

MACKLIN

2-甲基环戊二烯三羰基锰

98%

53元/1g; 70元/5g; 210元/25g; 650元/100g; 1860元/500g;

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储存：室温,密封
状态：浅黄色液体
物化性质：Insoluble in water. Soluble in hydrocarbon solvents, alcohols, ether, acetone
折射率：1.5873

25-1550

Strem

Methylcyclopentadienylmanganese tricarbonyl

min. 97%

945元/5g; 3810元/25g;

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047125

Alfa Aesar

Methylcyclopentadienylmanganese tricarbonyl

97%

428元/1g; 1708元/5g; 6951元/25g; 11132元/100g;

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备注
Special handling precautions required. View MSDS prior to purchase. MSDS are available online at www.alfa.com

基本信息

MDL
MFCD00001426

EINECS
235-166-5

分子式
C₉H₇MnO₃

分子量
218.09

熔点
1.5°

沸点
233°

闪点
96°(205°F)

密度
1.388

折射率
1.5873

灵敏度
Air Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Liquid

溶解性
Insoluble in water. Soluble in hydrocarbon solvents, alcohols, ether, acetone

Merck
14,6223

GHS危害和防范说明

GHS符号

Hazard Statements
H300-H310-H330
Fatal if swallowed.Fatal in contact with skin.Fatal if inhaled.

Precautionary Statements
P301+P310a-P304+P340-P320-P330-P405-P501a
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Specific treatment is urgent (see label).Rinse mouth.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
II

危险类别
24-26/28
Toxic in contact with skin.Very toxic by inhalation and if swallowed.

安全等级
4-9-20-23-27/28-36/37/39-45-60
Keep away from living quarters.Keep container in a well-ventilated place.When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of ... (to be specified by the manufacturer).Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
OP1450000

TSCA
是

317632

Sigma-Aldrich

(Methylcyclopentadienyl)manganese(I) tricarbonyl

194.85元/1 G; 3550.3元/50 G;

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产品说明

一般描述

甲基环戊二烯基三羰基锰(MMT)通常用作汽油中的抗爆剂。它也可用作无铅汽油的添加剂。

应用

甲基环戊二烯基锰三羰基可用于掺杂 ZnSe 纳米晶体。
它也可作为反应物用于：

Aldol 加成反应
用共轭联噻吩单元制备均-和异核混合双卡宾配合物
使用成形飞秒激光脉冲的分子碎裂
金属有机气相外延(MOVPE)制备 GaAs(001)上生长的 MnAs薄膜

包装

1, 50 g in glass bottle

基本信息

线性分子式	C₅H₄CH₃Mn(CO)₃
分子量	218.09
EC 号	235-166-5
MDL编号	MFCD00001426
PubChem化学物质编号	24859093
NACRES	NA.22

产品性质

蒸汽密度	>1 (vs air)
质量水平	100
蒸汽压	0.05 mmHg ( 20 ℃)
reaction suitability	core: manganese reagent type: catalyst
折射率	n20/D 1.584 (lit.)
bp	232-233 ℃ (lit.)
mp	−1 ℃ (lit.)
密度	1.38 g/mL at 25 ℃ (lit.)
SMILES string	[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].C[C]1[CH][CH][CH][CH]1
InChI	1S/C6H7.3CO.Mn/c1-6-4-2-3-5-6;3*1-2;/h2-5H,1H3;;;;
InChI key	LYHJNAIHGFWRKM-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H301 - H310 + H330 - H315 - H372 - H410
预防措施声明	P262 - P273 - P280 - P301 + P310 + P330 - P302 + P352 + P310 - P304 + P340 + P310
危险分类	Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Irrit. 2 - STOT RE 1 Inhalation
靶器官	Lungs
储存分类代码	6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK	WGK 3
闪点(F)	204.8 °F - closed cup
闪点(C)	96 ℃ - closed cup
个人防护装备	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter