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CAS: 120801-75-4
分子式: FSO2CF2CO2Si(CH3)3
分子量: 250.27
沸点: 156℃
英文名称: 
trimethylsilyl-2,2-difluoro-2-(fluorosulfonyl)acetate
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货号品牌产品名称规格包装、参考价格详情
T820212MACKLIN三甲硅烷基 2,2-二氟-2-(氟磺酰)醋酸盐90%32元/1g;   135元/5g;   662元/25g;   1850元/100g;   展开
储存:2-8℃,惰性气体氛围
状态:无色到黄色液体
折射率:n20/D 1.367(lit.)
T3022TCITrimethylsilyl Difluoro(fluorosulfonyl)acetate>96.0%(GC)780元/5G;   1805元/25G;   展开

基本信息

纯度/分析方法>96.0%(GC)
分子式/分子量C5H9F3O4SSi = 250.26
外观与形状(20℃)液体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解),加热
包装和容器 5G-带有玻璃内管的塑料瓶 (查看图片)
Reaxys-RN6400119
PubChem物质ID253660122
MDL编号MFCD02093343

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 96.0 %

物性(参考值)

沸点86 ℃/46 mmHg
闪点26 ℃
比重1.25
折射率1.37

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H226 : 易燃液体和蒸气。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P234 : 只能在原容器中存放。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

运输信息

UN编号UN2920
类别8 / 3
包装类别 II
监管条件代码(*)
397101J&KTrimethylsilyl 2,2-difluoro-2-(fluorosulfonyl)acetate90%660元/5G;   1416元/25G;   展开

基本信息

分子式C5H9F3O4SSi
分子量250.27
沸点156
闪点26
密度1.27
折光率(n20D)1.3670
MDL编码MFCD02093343
Beilstein6400119

安全信息

图形或危害标志
提示语Danger
危险说明H226
H314
防范说明P280
P305+P351+P338
P310
UN号码2920
危险分类8
次要危险性3
包装等级II
WGK2
TSCA
H26857Alfa AesarTrimethylsilyl 2,2-difluoro-2-(fluorosulfonyl)acetate94%1037元/1g;   2334元/5g;   9041元/25g;   展开

应用
Trimethylsilyl 2,2-difluoro-2-(fluorosulfonyl)acetate is an fluoroalkylation agent, reactant for preparation of difluorocyclopropenes, preparation of difluorocarbene reagents.

备注
Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

基本信息

MDL
MFCD02093343

分子式
FSO2CF2CO2Si(CH3)3

分子量
250.27

沸点
156°

闪点
26°(79°F)

密度
1.27

折射率
1.367

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Reacts with water.

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H314-H318
Flammable liquid and vapour.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P210-P260h-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Keep away from heat/sparks/open flames/hot surfaces. - No smoking.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
10-34
Flammable.Causes burns.

安全等级
20-26-36/37/39-45
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

005917FluorochemTrimethylsilyl fluorosulfonyldifluoroacetate90%352元/1g;   836元/5g;   2354元/25g;   展开

基本信息

CAS Number120801-75-4
MDL NumberMFCD02093343
Boiling Point156℃
Density1.27

安全信息

图形或危害标志
危险性说明 H225: Highly flammable liquid and vapour.
H314: Causes severe skin burns and eye damage.
防范说明 P210: Keep away from – No smoking.
P235: Keep cool.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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